A roadmap to a green chemical industry in Australia

A ‘roadmap’ has been devised for a progressive greening of the Australian chemical industry over the next two decades. The roadmap is based on a set of interactive principles broadly termed ‘economic’, ‘social’, ‘technological’, ‘environmental’ and ‘political’, which collectively form the ‘drivers of change’ in chemical industry strategy/business/policy planning—leading to greater efficiency and economic sustainability of this industry. The proposed roadmap pre-supposes that real economic, societal and environmental benefits can be obtained through greater use of existing and emerging green chemical technology. It can play an important role in developing a sustainable chemical industry in Australia. Primarily, the proposed roadmap involves a paradigm shift of the business operating plan and a significant mindset change of management.     

Couples experiences of receiving uncertain results following prenatal microarray or exome sequencing: A mixed-methods systematic review

Background

Tests in pregnancy such as chromosomal microarray analysis and exome sequencing are increasing diagnostic yield for fetal structural anomalies, but have greater potential to result in uncertain findings. This systematic review investigated the experiences of prospective parents about receiving uncertain results from these tests.

Methods

A systematic search of three electronic databases was conducted. Data extraction was performed for studies that met the eligibility and quality criteria. Results were synthesised following the principles of thematic analysis.

Results

Fourteen studies (10 qualitative, 4 quantitative) were included. Findings were grouped into three overarching themes. Sources of uncertainty included the testing procedure, the diagnosis and prognosis, and health professionals' own uncertainty. The clinical impact of the uncertainty included parents struggling to make clinical decisions with the information available, the emotional impact included decisional-regret, shock, worry and feeling overwhelmed. To manage the uncertainty, parents sought support from healthcare professionals, friends, family, the internet and other parents as well as remaining hopeful.

Conclusions

Prospective parents experience a myriad of uncertainties in the prenatal setting, which must be handled sensitively. Future research should explore optimal ways of managing uncertainty to minimise harm. Recommendations are made for discussing uncertainty during pre- and post-test counseling.     

A COMPUTERIZED DATA BASE FOR FLOOD PREDICTION MODELING1

ABSTRACT: A computerized geographic information system (GIS) was created in support of data requirements by a hydrologic model designed to predict the runoff hydrograph from ungaged basins. Some geomorphologic characteristics (i.e., channel lengths) were manually measured from topographic maps, while other parameters such as drainage area and number of channels of a specified order, land use, and soil type were digitized and manipulated through use of the GIS. The model required the generation of an integrated Soil Conservation Service (SCS) curve number for the entire basin. To this end, soil associations and land use (generated from analysis of Landsat satellite data) were merged in the GIS to acquire a map representing SCS runoff curve numbers. The volume of runoff obtained from the Watershed Hydrology Simulation (WAHS) Model using this map was compared to the volume computed by hydrograph separation and found to be accurate within 19 percent error. To quantify the effect of changing land use on basin hydrology, the GIS was used to vary percentages from the drainage area from forest to bare soil. By changing the basin runoff curve numbers, significant changes in peak discharge were noted; however, the time to peak discharge remained essentially independent of change in area of land use. The GIS capability eliminated many of the more traditional manual phases of data input arid manipulation, thereby allowing researchers to concentrate on the development and calibration of the model and the interpretation of presumably more accurate results.     

Phosphogypsum stabilization of bauxite residue: Conversion of its alkaline characteristics

Reduction of the high alkalinity of bauxite residue is a key problem to solve to make it suitable for plant growth and comprehensive utilization. In this study, phosphogypsum, a waste product from the phosphate fertilizer industry, was used to drive the alkaline transformation of the bauxite residue. Under optimal water washing conditions(liquid/solid ratio of 2 mL/g, 30°C, 24 hr), the impact of quantity added, reaction time and reaction mechanism during phosphogypsum application were investigated. Phosphogypsum addition effectively lowered p H levels and reduced the soluble alkalinity by 92.2%. It was found that the concentration of soluble Na and Ca ions in the supernatant increased gradually, whilst the exchangeable Na+and Ca~(2+)in solid phase changed 112 mg/kg and 259 mg/kg, respectively. Ca~(2+)became the dominant element in the solid phase(phosphogypsum addition of 2%, liquid/solid ratio of 2 mL/g, 30°C, 12 hr). X-ray diffraction data indicated that cancrinite and hydrogarnet were the primary alkaline minerals. SEM images suggested that phosphogypsum could promote the formation of stable macroaggregates, whilst the content of Ca~(2+)increased from 5.6% to 18.2% and Na reduced from 6.8% to 2.4%. Treatment with phosphogypsum could significantly promote the transformation of alkalinity cations by neutralization, precipitation and replacement reactions.This research provided a feasible method to promote soil formation of bauxite residue by phosphogypsum amendment.     

Rapid methods to determine potentially mineralizable nitrogen in broiler litter

Although broiler (chicken, Gallus gallus domesticus) litter has long been used as a fertilizer, estimating the rate required to supply a desired amount of plant-available N is still hampered by the lack of rapid methods to estimate potentially mineralizable nitrogen (PMN). Previous research has suggested that near infrared reflectance spectroscopy (NIRS) and certain poultry litter characteristics, such as water-soluble organic nitrogen (WSON), may be useful for estimating PMN. The objectives of this study were to evaluate NIRS and WSON as tools to estimate PMN in broiler litter. Sixty sieved (2 mm) and freeze-dried broiler litter samples were mixed with Cowarts sandy loam soil (fine-loamy, kaolinitic, thermic Typic Kanhapludult) and incubated at 25 degrees C for 112 d. Cumulative net N mineralized with time was fitted to a single-pool exponential model to determine PMN for each broiler litter sample. The PMN values obtained were regressed against NIRS (780 to 2500 nm) and WSON measurements. We found strong relationships between measured- and NIRS-predicted PMN (R2 = 0.82), and between measured PMN and WSON (R2 = 0.87). These results demonstrate the feasibility of using either of these two methods to estimate PMN in broiler litter. Future work should further test both methods for their ability to estimate mineralizable N in whole, moist broiler litter under field conditions.