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101.
Identification of sources of elevated concentrations of polycyclic aromatic hydrocarbons in an industrial area in Tianjin, China 总被引:2,自引:0,他引:2
Wentao Jiao Yonglong Lu Jing Li Jingyi Han Tieyu Wang Wei Luo Yajuan Shi Guang Wang 《Environmental monitoring and assessment》2009,158(1-4):581-592
The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined by gas chromatography equipped with a mass spectrometry detector in 105 topsoil samples from an industrial area around Bohai Bay, Tianjin in the North of China. Results demonstrated that concentrations of PAHs in 104 soil samples from this area ranged from 68.7 to 5,590 ng g???1 dry weight with a mean of ∑16PAHs 814 ± 813 ng g???1, which suggests that there exists mid to high levels of PAH contamination. The concentration of ∑16PAHs in one soil sample from Tianjin Port was exceptionally high (48,700 ng g???1). Ninety-three of the 105 soil samples were considered to be contaminated with PAHs (>200 ng g???1), and 25 were heavily polluted (>1,000 ng g???1). The sites with high PAHs concentration are mainly distributed around chemical industry parks and near highways. Two low molecular weight PAHs, naphthalene and phenanthrene, were the dominant components in the soil samples, which accounted for 22.1% and 10.7% of the ∑16PAHs concentration, respectively. According to the observed molecular indices, house heating in winter, straw stalk combustion in open areas after harvest, and petroleum input were common sources of PAHs in this area, while factory discharge and vehicle exhaust were the major sources around chemical industrial parks and near highways. Biological processes were probably another main source of low molecular weight PAHs. 相似文献
102.
Han Qu Hongting Diao Jiajun Han Bin Wang Gang Yu 《Frontiers of Environmental Science & Engineering》2023,17(1):12
Over the past decades, the plastic production has been dramatically increased. Indeed, a category of small plastic particles mainly with the shapes of fragments, fibers, or spheres, called microplastics (particles smaller than 5 mm) and nanoplastics (particles smaller than 1 μm) have attracted particular attention. Because of its wide distribution in the environment and potential adverse effects to animal and human, microplastic pollution has been reported as a serious environment problem receiving increased attention in recent years. As one of the commonly detected emerging contaminants in the environment, recent evidence indicates that the concentration of microplastics show an increasing trend, for the reason that up to 12.7 million metric tons of plastic litter is released into aquatic environment from land-based sources each year. Furthermore, microplastic exposure levels of model organisms in laboratory studies are usually several orders of magnitude higher than those found in environment, and the microplastics exposure conditions are also different with those observed in the environment. Additionally, the detection of microplastics in feces indicates that they can be excreted out of the bodies of animal and human. Hence, great uncertainties might exist in microplastics exposure and health risk assessment based on current studies, which might be exaggerated. Policies reduce microplastic emission sources and hence minimize their environmental risks are determined. To promote the above policies, we must first overcome the technical obstacles of detecting microplastics in various samples. 相似文献
103.
单甲脒农药对土壤微生物种群和土壤酶活性的影响 总被引:9,自引:0,他引:9
研究了单甲脒(N'-2,4-二甲苯基-N-甲基甲脒,简称DMA)对土壤微生物种群和土壤酶活性的影响.田间试验表明,喷洒单甲脒盐酸盐(DMAH)于棉花植株对土壤微生物种群和土壤酶活性无明显影响.实验室试验表明,投加DMAH于土壤对土壤微生物种群有不同的抑制作用;当DMAH在土壤中的浓度为20mg/g时,好氧异养菌总量开始降低,硝化细菌和放线菌、真菌的土壤DMAH抑制浓度分别为0.5mg/g和0.1mg/g.DMAH对土壤酶活性的影响亦不相同,脱氢酶对土壤中DMAH含量为10mg/g时其活性即有明显的减弱,而过氧化氨酶对DMA的耐受性相当高,其活性的抑制浓度达500mg/g.试验还证明了土壤中DMA的微生物降解作用.当DMA在土壤中的浓度为50~500g/g时,其消解速率可从8.75mm·kg-1·d-1提高到48mg·kg-1·d-1. 相似文献
104.
105.
低压离子色谱法测定水和酸雨样品中的Li~+,Na~+,NH_4~+,K~+,Ca~(2+)和Mg~(2+)离子 总被引:3,自引:0,他引:3
本文介绍了低压离子色谱仪测定水样(井水、湖水、矿泉水、自来水)和酸雨中锂、钠、铵、钙、钾和镁离子的方法、欲测阳离子在阳离子交换柱上被分离,分别用1.4mmol·1~(-1)HNO_3和0.6mmol·1~(-1)乙二胺+1.2mmol·1~(-1)HNO_3溶液作流动相,流速为1.6ml·min~(-1).各离子的流分用电导检测.进样量为10μl时,Li~+,Na~+,NH_4~+,K~+,Ca~(2+)和Mg~(2+)离子的检出限(2倍噪音比),分别为0.020,0.050,0.100,0.250,2.5和1.0μg·ml~(-1). 相似文献
106.
Influence of calcium chloride on the thermal behavior of heavy and alkali metals in sewage sludge incineration 总被引:2,自引:0,他引:2
In order to separate and reuse heavy and alkali metals from flue gas during sewage sludge incineration, experiments were carried out in a pilot incinerator. The experimental results show that most of the heavy and alkali metals form condensed phase at temperature above 600 degrees C. With the addition of 5% calcium chloride into sewage sludge, the gas/solid transformation temperature of part of the metals (As, Cu, Mg and Na) is evidently decreased due to the formation of chloride, while calcium chloride seems to have no significant influence on Zn and P. Moreover, the mass fractions of some heavy and alkali metals in the collected fly ash are relatively high. For example, the mass fractions for Pb and Cu in the fly ash collected by the filter are 1.19% and 19.7%, respectively, which are well above those in lead and copper ores. In the case of adding 5% calcium chloride, the heavy and alkali metals can be divided into three groups based on their conversion temperature: Group A that includes Na, Zn, K, Mg and P, which are converted into condensed phase above 600 degrees C; Group B that includes Pb and Cu which solidify when the temperature is above 400 degrees C; and Group C that includes As, whose condensation temperature is as low as 300 degrees C. 相似文献
107.
108.
利用造纸黑液制备水煤浆添加剂 总被引:5,自引:0,他引:5
利用造纸黑液中有效成分,经过适当处理制备水煤浆添加剂,并且对添加剂的性能进行了测试。结果表明,依照该工艺生产的添加剂,性能优良,能够满足工业生产需要。 相似文献
109.
Sang Soo Lee Samy A.M. Abd El-Azeem Jung Eun Lim Anushka Upamali Rajapaksha Kwon-Rae Kim Young Han Lee 《Chemistry and Ecology》2013,29(6):501-510
Addition of plant residue into soils improves soil physiochemical properties and its fertility. Rapeseed residue is an emerging N source to paddy soils via rice-rape double-cropping practice. The objective of this study was to evaluate the effects of rapeseed residue and eggshell waste on chemical changes and enzyme activity in the rice paddy soil. The powdered eggshells at 0, 1, 3, and 5% were applied once to 7.0 kg paddy repacked soils in each pot treated with the rapeseed residue or the conventional N, P, and K fertilisers. Eight rice seedlings (Oriza sativa L. cv. Ilmibyeo) (40 days after sowing) were transplanted to the treated each pot. The contents of total C (TC) and N (TN), and organic matter (OM) were significantly increased in soils treated with the rapeseed residue compared to the N, P, and K fertilisers. With the addition of eggshell containing ~92% CaCO3, a considerable increase of soil pH was observed in soils treated with the rapeseed residue and the N, P, and K fertilisers, compared to the untreated soil. Activities of β-glucosidase, urease, and arylsulfatase enzymes were higher in soils treated with the rapeseed residue than soils treated with the N, P, and K fertilisers. The eggshell additions at 1, 3, and 5% into soils treated with the rapeseed residue increased enzyme activity mainly resulting from N mineralisation, whereas no change in enzyme activity was observed in the soils treated with the NPK fertiliser. The combined use of the rapeseed residue and the eggshells can be beneficial to improve soil environment. 相似文献
110.
以纹缟虾虎鱼为受试生物,分别进行了Cu~(2+)、Cd~(2+)和氨氮为环境因子的急性毒性实验和氨氮慢性暴露实验,结合文献数据分析纹缟虾虎鱼对3种污染物的敏感性。结果表明,Cu~(2+)、Cd~(2+)和氨氮对纹缟虾虎鱼的EC50分别为4.527、40.408和63.182mg·L~(-1)。组织切片结果显示,氨氮暴露能够引起纹缟虾虎鱼肝组织结构退化,组织细胞畸变,其损伤程度随着氨氮浓度的升高而加剧。氨氮暴露对肠管未见明显影响。敏感性分析结果表明,纹缟虾虎鱼对Cu~(2+)、Cd~(2+)和氨氮的累积概率分别为83.33%、96.27%和90.48%,均表现为不敏感。在Cu~(2+)、Cd~(2+)和氨氮对海洋生物的敏感性排名中,纹缟虾虎鱼分别在第31/35、32/32和19/20位。在8~12种海洋鱼类中,纹缟虾虎鱼对上述3种污染物的敏感性都处在较低水平。 相似文献