全文获取类型
收费全文 | 1838篇 |
免费 | 102篇 |
国内免费 | 605篇 |
专业分类
安全科学 | 133篇 |
废物处理 | 112篇 |
环保管理 | 137篇 |
综合类 | 1061篇 |
基础理论 | 300篇 |
污染及防治 | 579篇 |
评价与监测 | 96篇 |
社会与环境 | 64篇 |
灾害及防治 | 63篇 |
出版年
2024年 | 5篇 |
2023年 | 52篇 |
2022年 | 136篇 |
2021年 | 104篇 |
2020年 | 78篇 |
2019年 | 82篇 |
2018年 | 76篇 |
2017年 | 89篇 |
2016年 | 115篇 |
2015年 | 118篇 |
2014年 | 121篇 |
2013年 | 178篇 |
2012年 | 145篇 |
2011年 | 152篇 |
2010年 | 114篇 |
2009年 | 105篇 |
2008年 | 102篇 |
2007年 | 111篇 |
2006年 | 75篇 |
2005年 | 56篇 |
2004年 | 36篇 |
2003年 | 56篇 |
2002年 | 63篇 |
2001年 | 43篇 |
2000年 | 48篇 |
1999年 | 45篇 |
1998年 | 39篇 |
1997年 | 37篇 |
1996年 | 40篇 |
1995年 | 25篇 |
1994年 | 12篇 |
1993年 | 25篇 |
1992年 | 14篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 3篇 |
1988年 | 10篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1984年 | 3篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1958年 | 1篇 |
1956年 | 2篇 |
排序方式: 共有2545条查询结果,搜索用时 31 毫秒
931.
自然状态下树木排放N2O的研究 总被引:7,自引:3,他引:7
大气中主要温室气体之一N2O的部分来源尚不清楚,以前认为只有土壤微生物过程是N2O的生物源,本文则旨在证明自然状态下植物也是N2O的排放源.采用同步空气样品采集装置和气相色谱仪观测了长白山阔叶红松林内空气N2O的垂直分布特征,发现林冠或其附近处出现高N2O浓度,高N2O浓度比同一时刻其他高度处的正常N2O浓度高3.03%~64.9%,差异显著或极显著.在林冠高度处的高N2O浓度和树干高度处的正常N2O浓度同时存在的现象证明了植物向外排放N2O,即植物自身在自然状态下是N2O的一个排放源. 相似文献
932.
恢复措施对排土场土壤酶活性和微生物量的影响 总被引:3,自引:0,他引:3
以海州露天矿排土场为研究对象,选取工程复垦、人工种植林地(榆树、刺槐和紫穗槐)和天然草地3种恢复措施作为修复地,以荒裸地作为对照,研究恢复措施对土壤酶活性和土壤微生物量的影响,探讨生态恢复措施对排土场土壤质量的改善情况.结果表明,在同一土层中,修复地土壤脲酶、蛋白酶、蔗糖酶、碱性磷酸酶的活性和土壤微生物量显著高于荒裸地(P0.05),人工林地和天然草地在提高上述4种土壤酶活性方面显著高于工程复垦地(P0.05),工程复垦能够显著提高土壤过氧化氢酶活性(P0.05),却不能显著提高土壤微生物量(P0.05).表层土壤中,微生物量C/N比值表现为人工林地和天然草地显著高于其他土壤(P0.05),深层土壤则为荒裸地最高.从垂直分布上看,土壤酶活性和土壤微生物量C、N随着土壤深度的增加而降低.相关分析表明,土壤酶活性和微生物量与土壤养分含量之间密切相关,说明土壤酶活性和微生物量可以作为评价排土场土壤质量的生物学指标.3种恢复措施对土壤质量的改善能力依次为人工林地天然草地工程复垦地,在林种的选择上为乔木灌木. 相似文献
933.
为分析参数不确定性对地下水污染数值模拟模型输出结果的影响,以某钼矿尾矿库地下水污染问题作为研究实例,选取钼离子作为模拟因子,建立该钼矿尾矿库地下水污染数值模拟模型,对输出结果进行不确定性分析.为降低替代模型的维数,运用灵敏度分析法筛选出对模拟模型输出结果影响较大的2个参数作为模型中的随机参数.为减少反复调用数值模拟模型产生的计算负荷,分别运用克里格方法和支持向量机法建立模拟模型的替代模型,并比较二者的精度,选择精度较高的替代模型完成蒙特卡罗随机模拟.最后,对随机模拟的输出结果进行统计分析与区间估计,对地下水污染超标的风险进行评价.结果表明:置信度为80%时,井1,2,3浓度值的置信区间分别为0.71~2.29,0.28~1.02,1.55~3.25mg/L.此外,结合《地下水质量标准》以及污染物浓度分布函数曲线,井1,2,3中水质达到地下水质量标准Ⅴ类的概率分别为99.7%,97.1%,99.6%.本研究可为地下水污染防治提供更科学、全面的参考依据. 相似文献
934.
Variations in the soil/sediment organic matter (SOM)-hydrophobic organic contaminant (HOC) bindings upon microbially mediated redox conditions were examined. While the extractability of pyrene associated with soil declined after its biodegradation began during aerobic incubation, its variations were almost constant (±3.0-4.4%) during anoxic/anaerobic incubations. The dissolved organic matter released from the soil incubated under highly reduced conditions became more humified and aromatic, had a higher average molecular weight, and was more polydispersed compared to that obtained from oxic incubation, similar to the SOM alterations in the early stage of diagenesis (humification). The concentrations of pyrene in the aqueous phase increased significantly during the soil incubations under highly reduced conditions due to its favorable interaction with the altered DOM. Our results suggest that the microbially mediated redox conditions have significant impacts on SOM and should be considered for the transport, fate, bioavailability, and exposure risk of HOCs in the geo-environments. 相似文献
935.
Bush bean (Phaseolus vulgaris L.) lines 'S156' (O3-sensitive)/'R123' (O3-tolerant) and cultivars 'BBL 290' (O3-sensitive)/'BBL 274' (O3-tolerant) were used to study the effects of O3 on stomatal conductance (gs), density, and aperture size on leaf and pod surfaces with the objective of establishing links between the degree of plant sensitivity to O3 and plasticity of stomatal properties in response to O3. Studies in open-top chambers (OTCs) and in continuously stirred tank reactors (CSTRs) established a clear relationship between plant developmental stages, degrees of O3 sensitivity and gs: while 'S156' had higher gs rates than 'R123' earlier in development, similar differences between 'BBL 290' and 'BBL 274' were observed at later stages. Gs rates on the abaxial leaf surfaces of 'S156' and 'BBL 290', accompanied by low leaf temperatures, were significantly higher than their O3-tolerant counterparts. Exposure to O3 in CSTRs had greater and more consistent impacts on both stomatal densities and aperture sizes of O3-sensitive cultivars. Stomatal densities were highest on the abaxial leaf surfaces of 'S156' and 'BBL 290' at higher O3 concentrations (60 ppb), but the largest aperture sizes were recorded on the adaxial leaf surfaces at moderate O3 concentrations (30 ppb). Exposure to O3 eliminated aperture size differences on the adaxial leaf surfaces between sensitive and tolerant cultivars. Regardless of sensitivity to O3 and treatment regimes, the smallest aperture sizes and highest stomatal densities were found on the abaxial leaf surface. Our studies showed that O3 has the potential to affect stomatal plasticity and confirmed the presence of different control mechanisms for stomatal development on each leaf surface. This appeared to be more evident in O3-sensitive cultivars. 相似文献
936.
Microbial structure and chemical components of aerosols caused by rotating brushes in a wastewater treatment plant 总被引:1,自引:0,他引:1
Yunping Han Lin Li Junxin Liu Mengzhu Zhang 《Environmental science and pollution research international》2012,19(9):4097-4108
Purpose
Bacterial community structure and the chemical components in aerosols caused by rotating brushes in an Orbal oxidation ditch were assessed in a Beijing municipal wastewater treatment plant.Methods
Air samples were collected at different distances from the aerosol-generating rotating brushes. Molecular culture-independent methods were used to characterize the community structure of the airborne bacteria in each sample regardless of cell culturability. A clone library of 16S rDNA directly amplified from air DNA of each sample was constructed and sequenced to analyze the community composition and diversity. Insoluble particles and water-soluble ions emitted with microorganisms in aerosols were analysis by a scanning electron microscope together with energy dispersive X-ray spectroscopy and ion chromatogram analyzer.Results
In total, most of the identified bacteria were Proteobacteria. The majority of sequences near the rotating brushes (the main source of the bioaerosols) were Proteobacteria (62.97 %) with ??-(18.52 %) and ??-(44.45?%) subgroups and Bacteroidetes (29.63 %). Complex patterns were observed for each sampling location, suggesting a highly diverse community structure, comparable to that found in water in the Orbal oxidation ditch. Accompany with microorganisms, 46.36???g/m3 of SO 4 2? , 29.35???g/m3 of Cl?, 21.51???g/m3 of NO 3 ? , 19.76???g/m3 of NH 4 + , 11.42???g/m3 of PO 4 3? , 6.18???g/m3 of NO 2 ? , and elements of Mg, Cl, K, Na, Fe, S, and P were detected from the air near the aerosols source.Conclusions
Differences in the structure of the bacterial communities and chemical components in the aerosols observed between sampling sites indicated important site-related variability. The composition of microorganisms in water was one of the most important sources of bacterial communities in bioaerosols. Chemical components in bioaerosols may provide a media for airborne microorganism attachment, as well as a suitable microenvironment for their growth and survival in the air. This study will be benefit for the formulation of pollution standards, especially for aerosols, that take into account plant workers?? health. 相似文献937.
938.
油田含油污泥超声脱油的研究 总被引:2,自引:2,他引:2
在油田含油污泥的热洗处理中引入超声辐照处理技术,研究考察了超声脱油技术中超声强度,超声辐照时间,含油污泥预热温度,清洗液用量和清洗液回用4个试验操作条件对污泥脱油的影响,认为在优化条件(超声发生器输出电压175 V,辐照时间15 min,预热温度55 ℃,清洗液和含油污泥以质量比8∶1)下,超声脱油技术可以把污泥的干基油含量由0.35 g/g降低到0.14 g/g,同时也证明清洗液可以反复使用。根据简单的经济核算,处理1 t含油污泥可以产出66元的效益。研究表明,使用超声处理可以有效地提高含油污泥的污油脱除效率,明显降低污泥清洗的操作温度。 相似文献
939.
940.
掌握装配式综合管廊的螺栓节点在土体回填、加载、卸载等工况中所承受的应力变化,对于准确评价管廊施工和运营期的稳定性有着重要的作用。针对常规的监测手段难以满足综合管廊在施工及运营期间安全监测要求的瓶颈,基于开发的光纤光栅(FBG)智能螺栓应力计,对南京江北新区某综合管廊的建设过程进行原型试验研究。 现场监测结果表明:FBG 螺栓应力计监测数据与管廊的连接位置、施工工况、堆载大小及位置等有关。在管廊上部堆载从 0 增加至 4 000 kN 的过程中,FBG 螺栓应力计测试数据处于安全阈值,表明其具有足够的螺栓预紧度;根据相关规范,螺栓所受的最大应力满足设计使用要求,保证了管廊结构的承载力处于安全范围。本研究充分验证了光纤传感技术在装配式综合管廊受力变形监测中的有效性,未来值得推广应用。 相似文献