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261.
    
Disposal of discarded chromated copper arsenate (CCA)-treated wood in landfills raises concerns with respect to leaching of preservative compounds. When unweathered CCA-treated wood is leached using the toxicity characteristic leaching procedure (TCLP), arsenic concentrations exceed the toxicity characteristic (TC) limit of 5mg/L in most cases. The majority of discarded CCA-treated wood, however, results from demolition activities, where the wood has typically been subjected to weathering. Since preservatives do migrate from the wood during its normal use, leaching characteristics of weathered and aged CCA-treated wood may differ from unweathered wood. To evaluate this, CCA-treated wood removed from service after various degrees of weathering was collected from multiple sources and leached with the TCLP, the synthetic precipitation leaching procedure (SPLP) and California's waste extraction test (WET). Five to seven individual pieces of wood were analyzed from each source. The average TCLP arsenic concentration for the 14 sources ranged from 3.2 to 13 mg/L. The average TCLP concentrations of the 100 wood pieces tested were 6.4, 5.9 and 3.2 mg/L for arsenic, copper and chromium, respectively. Overall, in 60 out of 100 samples tested by the TCLP, arsenic concentrations exceeded 5 mg/L (the TC regulatory value). SPLP leachate concentrations were similar to TCLP concentrations, although copper leached somewhat more with the TCLP. WET leachate concentrations were approximately a factor of 10 higher than TCLP concentrations. Discarded CCA-treated wood, even after exposure to years of weathering, often exceeds the TC limit for arsenic and without the current regulatory exemption would possibly require management as a TC hazardous waste in the US.  相似文献   
262.
Simultaneous ground-based measurements of ozone and carbon monoxide were performed at Oki, Japan, from January 2001 to September 2002 in order to investigate the O(3) and CO characteristics and their distributions. The observations revealed that O(3) and CO concentrations were maximum in springtime and minimum in the summer. The monthly averaged concentrations of O(3) and CO were 60 and 234 ppb in spring and 23 and 106 ppb in summer, respectively. Based on direction, 5-day isentropic backward trajectory analysis was carried out to determine the transport path of air masses, preceding their arrival at Oki. Comparison between classified results from present work and results from the year 1994-1996 was carried out. The O(3) and CO concentration results of classified air masses in our analysis show similar concentration trends to previous findings; highest in the WNW/W, lowest in N/NE and medium levels in NW. Moreover, O(3) levels are higher and CO levels are lower in the present study in all categories.  相似文献   
263.
The concept of animal welfare refersto the animal's quality of life. The choice ofdefinition always reflects some basicvaluation. This makes a particular conceptionof welfare value-dependent. Also, the animalhusbandry system reflects certain values oraims. The values reflected in the chosenconception of animal welfare ought tocorrespond to values aimed for in the husbandrysystem. The IFOAM Basic Standards and otherwritings dealing with organic animal husbandryshould be taken as a departure point for adiscussion of how to interpret the conceptionof welfare in organic farming systems. Theconception of welfare is related to two corevalues in the organic agriculture movement.These core values should be considered in termsof (1) aim for holistic view and (2) aim forsustainability. A third, implicit core value,based on bio- and ecocentric views: (3) respectfor nature is needed as a supplement to thesetwo core values. There are importantimplications of these core values for an``organic' conception of animal welfare and forconfronting two dilemmas due to conflictinginterests. Comparisons among the three commonlyused welfare definitions will show thesuperiority of the third approach, which canprovide an outline for a conception of animalwelfare more suitable for organic farmingsystems. This outline combines a holisticecocentric approach with respect for theindividual animal, and it can be used as thebasis for a complex definition with emphasis onnatural behavior. Such a systemic approachconsiders welfare in relation to differentsystemic levels. The systemic view also offerspossibilities for resolving the dilemmas in newways.  相似文献   
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265.
    
The aim of our article is to follow how global policy models affect local policy making. Each city has unique local challenges in promoting development, e.g. economic growth, but also needs to find a balance between these targets and demands for sustainable city solutions. In our empirical study, we follow how ideas of waterfront development – to attract new inhabitants and promote economic growth – and global demands of carbon control were used interactively in a strategic spatial planning process in the city of Tampere, Finland. During the six-year planning process, these two policy targets became interdependent, created a new policy-making domain, and led to a combinatorial development of sustainability elements arising from this domain. These findings demonstrate the serial use of global policy models in the creation of a local urban ‘sustainability fix’. To conclude, the intertwinement of diverse global policy models in a city planning process creates easily a recursive cycle that redefines urban sustainability within cities and intercity networks. This perspective makes local policy narratives and strategic planning highly important in urban sustainability research as promoting urban sustainability becomes an inherently ambivalent practice.  相似文献   
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267.
Defining Chlorophyll-a Reference Conditions in European Lakes   总被引:2,自引:0,他引:2  
The concept of “reference conditions” describes the benchmark against which current conditions are compared when assessing the status of water bodies. In this paper we focus on the establishment of reference conditions for European lakes according to a phytoplankton biomass indicator—the concentration of chlorophyll-a. A mostly spatial approach (selection of existing lakes with no or minor human impact) was used to set the reference conditions for chlorophyll-a values, supplemented by historical data, paleolimnological investigations and modelling. The work resulted in definition of reference conditions and the boundary between “high” and “good” status for 15 main lake types and five ecoregions of Europe: Alpine, Atlantic, Central/Baltic, Mediterranean, and Northern. Additionally, empirical models were developed for estimating site-specific reference chlorophyll-a concentrations from a set of potential predictor variables. The results were recently formulated into the EU legislation, marking the first attempt in international water policy to move from chemical quality standards to ecological quality targets.  相似文献   
268.
The aim of this study was to determine how the potential to rely on arbuscular mycorrhiza (AM) for plant nutrition differs between a conventional and a low-input cropping system in the long term. The roles of fertilisation rate, composting of recycled plant residues and stage of the rotations in the overall impact of the cropping systems on soil quality and AM were also identified. The conventional cropping system with a non-leguminous crop rotation (barley–barley–rye–oat–potato–oat) was fertilised at either full or half the recommended rate. In the low-input cropping system, one year with barley was replaced by clover, and oat was cultivated mixed with pea. Straw and clover were returned to the soil either with or without composting. In the low-input system, biotite and rock phosphate were used to compensate for K and P in the harvested yield, while animal manure was applied at the start only. After 15 years, crop growth and nutrition, AMF colonisation and soil quality were assessed in the field, while the AM contribution to growth and nutrient uptake were determined in a bioassay in a growth chamber. AM functioning made a higher contribution to soil quality in terms of crop performance and environmental benefits in the low-input cropping system than at either fertilisation rate in the conventional system. Halving fertilisation in the conventional system prevented some costs and enhanced some of the benefits of AM in comparison with full fertilisation. However, only the low-input system with composting conclusively favoured AM in comparison with the conventional system. It resulted in the highest percentage colonisation and, in a bioassay with flax and clover, gave a relative average contribution to growth of 27% and to P uptake of 68% in comparison with 4 and 36%, respectively, for the conventional cropping system with full fertilisation. Rye yield was in the low-input system without composting similar to that in the conventional system with full fertilisation, and with composting 87% of the latter one. Incorporation of clover green manure without composting inhibited AM functioning, leading to a temporary loss of AM contribution to crop performance. This effect draws attention to the impact of the form of recycled organic matter on supporting ecosystem services such as nutrient cycling.  相似文献   
269.
    
Protected-area systems should conserve intraspecific genetic diversity. Because genetic data require resources to obtain, several approaches have been proposed for generating plans for protected-area systems (prioritizations) when genetic data are not available. Yet such surrogate-based approaches remain poorly tested. We evaluated the effectiveness of potential surrogate-based approaches based on microsatellite genetic data collected across the Iberian Peninsula for 7 amphibian and 3 reptilian species. Long-term environmental suitability did not effectively represent sites containing high genetic diversity (allelic richness). Prioritizations based on long-term environmental suitability had similar performance to random prioritizations. Geographic distances and resistance distances based on contemporary environmental suitability were not always effective surrogates for identification of combinations of sites that contain individuals with different genetic compositions. Our results demonstrate that population genetic data based on commonly used neutral markers can inform prioritizations, and we could not find an adequate substitute. Conservation planners need to weigh the potential benefits of genetic data against their acquisition costs.  相似文献   
270.
A comprehensive surveillance program was conducted to determine the occurrence of three cyclic volatile methylsiloxanes (cVMS) octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) in environmental compartments impacted by wastewater effluent discharges. Eleven wastewater treatment plants (WWTPs), representative of those found in Southern Ontario and Southern Quebec, Canada, were investigated to determine levels of cVMS in their influents and effluents. In addition, receiving water and sediment impacted by WWTP effluents, and biosolid-amended soil from agricultural fields were also analyzed for a preliminary evaluation of the environmental exposure of cVMS in media impacted by wastewater effluent and solids. A newly-developed large volume injection (septumless head adapter and cooled injection system) gas chromatography – mass spectrometry method was used to avoid contamination originating from instrumental analysis. Concentrations of D4, D5, and D6 in influents to the 11 WWTPs were in the range 0.282–6.69 μg L−1, 7.75–135 μg L−1, and 1.53–26.9 μg L−1, respectively. In general, wastewater treatment showed cVMS removal rates of greater than 92%, regardless of treatment type. The D4, D5, and D6 concentration ranges in effluent were <0.009–0.045 μg L−1, <0.027–1.56 μg L−1, and <0.022–0.093 μg L−1, respectively. The concentrations in receiving water influenced by effluent, were lower compared to those in effluent in most cases, with the ranges <0.009–0.023 μg L−1, <0.027–1.48 μg L−1, and <0.022–0.151 μg L−1 for D4, D5, and D6, respectively. Sediment concentrations ranged from <0.003–0.049 μg g−1 dw, 0.011–5.84 μg g−1 dw, and 0.004–0.371 μg g−1 dw for D4, D5, and D6, respectively. The concentrations in biosolid-amended soil, having values of <0.008–0.017 μg g−1 dw, <0.007–0.221 μg g−1 dw, and <0.009–0.711 μg g−1 dw for D4, D5, and D6, respectively, were lower than those in sediment impacted by wastewater effluent in most cases. In comparison with the no-observed-effected concentrations (NOEC) and IC50 (concentration that causes 50% inhibition of the response) values, the potential risks to aquatic, sediment-dwelling, and terrestrial organisms from these reported concentrations are low.  相似文献   
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