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101.
Simonsen L Fomsgaard IS Svensmark B Spliid NH 《Journal of environmental science and health. Part. B》2008,43(5):365-375
The fate of glyphosate and its degradation product aminomethylphosphonic acid (AMPA) was studied in soil. Labeled glyphosate was used to be able to distinguish the measured quantities of glyphosate and AMPA from the background values since the soil was sampled in a field where glyphosate had been used formerly. After addition of labeled glyphosate, the disappearance of glyphosate and the formation and disappearance of AMPA were monitored. The resulting curves were fitted according to a new EU guideline. The best fit of the glyphosate degradation data was obtained using a first-order multi compartment (FOMC) model. DT(50) values of 9 days (glyphosate) and 32 days (AMPA) indicated relatively rapid degradation. After an aging period of 6 months, the leaching risk of each residue was determined by treating the soil with pure water or a phosphate solution (pH 6), to simulate rain over a non-fertilized or fertilized field, respectively. Significantly larger (p < 0.05) amounts of aged glyphosate and AMPA were extracted from the soil when phosphate solution was used as an extraction agent, compared with pure water. This indicates that the risk of leaching of aged glyphosate and AMPA residues from soil is greater in fertilized soil. The blank soil, to which 252 g glyphosate/ha was applied 21 months before this study, contained 0.81 ng glyphosate/g dry soil and 10.46 ng AMPA/g dry soil at the start of the study. Blank soil samples were used as controls without glyphosate addition. After incubation of the blank soil samples for 6 months, a significantly larger amount of AMPA was extracted from the soil treated with phosphate solution than from that treated with pure water. To determine the degree of uptake of aged glyphosate residues by crops growing in the soil, (14)C-labeled glyphosate was applied to soil 6.5 months prior to sowing rape and barley seeds. After 41 days, 0.006 +/- 0.002% and 0.005 +/- 0.001% of the applied radioactivity was measured in rape and barley, respectively. 相似文献
102.
Growing concern about airborne particles in indoor environments requires fast source identification in order to apply remedial actions. A methodology for identifying sources emitting particles larger than 0.5 microm was designed and applied. It includes: (1) visual inspection of interior surfaces in order to identify deposited particles and inspection of potential sources (equipment, materials, activities etc.) of airborne particles. (2) Technical measurements of airborne particles at different positions in a building with simultaneous logging of activities. (3) Isolating potential activities/particle sources in a test chamber, initially free from particles, for controlled characterizations of the particles generated. The methodology was applied in a study of three houses in southern Sweden. The results show that source identification is facilitated by knowledge of concentration variations between different rooms, real-time measurements together with activity reports and information on particle characteristics that are comparable with results from laboratory simulations. In the houses to which the methodology was applied, major particle emissions from textile handling were identified, which were likely due to detergent zeolite residues. 相似文献
103.
John D. C. Linnell Henrik Broseth John Odden Erlend Birkeland Nilsen 《Environmental management》2010,45(5):1142-1154
The management of large carnivores in multiuse landscapes is always controversial, and managers need to balance a wide range
of competing interests. Hunter harvest is often used to limit population size and distribution but is proving to be both controversialand
technically challenging. Eurasian lynx (Lynx lynx) are currently managed as a game species in Norway. We describe an adaptive management approach where quota setting is based
on an annual census and chart the population development through the period 1996–2008, as management has become significantly
more sophisticated and better informed by the increased availability of scientific data. During this period the population
has been through a period of high quotas and population decline caused by fragmented management authority and overoptimistic
estimates of lynx reproduction, followed by a period of recovery due to quota reductions. The modern management regime is
placed in the context of shifting policy during the last 160 years, during which management goals have moved from extermination
stimulated by bounties, through a short phase of protection, and now to quota-regulated harvest. Much management authority
has also been delegated from central to local levels. We conclude that adaptive management has the potential to keep the population
within some bounded limits, although there will inevitably be fluctuation. 相似文献
104.
Filling and cleaning of pesticide sprayers presents a potential risk of pollution of soil and water. Three different solutions for handling sprayers have been suggested: Filling and cleaning in the field, filling and cleaning on hard surfaces with collection of the waste water, and filling and cleaning on a biobed, which is an excavation lined with clay and filled with a mixture of chopped straw, sphagnum and soil with turf on top, and with increased sorption capacity and microbial activity for degradation of the pesticides. In the present study the degradation and leaching of 21 pesticides (5 g of each) was followed in an established full-scale model biobed. Percolate was collected and analysed for pesticide residues, and the biobed material was sampled at three different depths and analysed by liquid chromatography double mass spectrometry (LC-MSMS). During the total study period of 563 days, no traces of 10 out of 21 applied pesticides were detected in the percolate (detection limits between 0.02 and 0.9 μg l−1) and three pesticides were only detected once and at concentrations below 2 μg l−1. During the first 198 days before second application, 14% of the applied herbicide bentazone was detected in the leachate with maximum and mean concentrations of 445 and 172 μg l−1, respectively. About 2% of the initial mecoprop and fluazifop dose was detected in the percolate, with mean concentrations of 23 μg l−1, while MCPA and dimethoate had mean concentrations of 3.5 and 4.7 μg l−1, respectively. Leachate concentrations for the remaining pesticides were generally below the detection limit (0.02–0.9 μg l−1, below 1% of applied). Sorption studies of five pesticides showed that compounds with a low Kd value appeared in the leachate. After 169 days, all pesticides in the biobed profile were degraded to a level below 50% of the calculated initial dose. Pesticides with Koc values above 100 were primarily found in the uppermost 10 cm and degraded slowest due to the low bioavailability. The 11 most degradable pesticides were all degraded such that less than 3% remained in the biobed after 169 days.
Following second pesticide application of the biobed, leachate was sampled 215 and 365 days after the treatment. This showed the same pesticides to be leached out and at concentrations comparable to those of the first treatment. The same pesticides as after the first treatment were retained in the biobed. 相似文献
105.
106.
Peter Sandberg Mikael Larsson Jan Dahl Mats Söderström Henrik Vourinen 《International Journal of Green Energy》2013,10(2):159-170
It is crucial for a steel making production system to operate at the lowest possible production cost, while satisfying stability and reliability conditions. To plan future production strategies, it is therefore important to be able to model the system behaviour when internal and external parameters are changed. In this study the sensitivity and stability of an optimised solution, of an integrated steel plant, have been investigated. The solution’s sensitivity has been analysed taking both internal process changes and external price variations into account, through applying both simulation and optimisation. The analysis also includes both costs and environmental issues such as carbon dioxide and sulphur emissions. Based on the methodology suggested, it is possible to determine the stability of the system solution, including both economic and environmental performance. 相似文献
107.
108.
This study presents a detailed characterization of Shredder residues (SR) generated and deposited in Denmark from 1990 to 2010. It represents approximately 85% of total Danish SR. A comprehensive sampling, size fractionation and chemical analysis was carried out on entire samples as well as on each individual size fraction. All significant elemental contents except oxygen were analyzed. The unexplained “balance” was subsequently explained by oxygen content in metal oxides, carbonates, sulphates and in organics, mainly cellulose. Using mass and calorific balance approaches, it was possible to balance the composition and, thereby, estimate the degree of oxidation of elements including metals. This revealed that larger fractions (>10 mm, 10–4 mm, 4–1 mm) contain significant amount of valuable free metals for recovery. The fractionation revealed that the >10 mm coarse fraction was the largest amount of SR being 35–40% (w/w) with a metal content constituting about 4–9% of the total SR by weight and the <1 mm fine fraction constituted 27–37% (w/w) of the total weight. The lower heat value (LHV) of SR samples over different time periods (1990–2010) was between 7 and 17 MJ/kg, declining with decreasing particle size. The SR composition is greatly dependent on the applied shredding and post shredding processes at the shredding plants causing some variations. There are uncertainties related to sampling and preparation of samples for analyses due to its heterogeneous nature and uncertainties in the chemical analyses results (≈15–25%). This exhaustive characterization is believed to constitute hitherto the best data platform for assessing potential value and feasibility of further resource recovery from SR. 相似文献
109.
Su Y Hung H Stern G Sverko E Lao R Barresi E Rosenberg B Fellin P Li H Xiao H 《Journal of environmental monitoring : JEM》2011,13(11):3111-3118
Initiated in 1992, air monitoring of organic pollutants in the Canadian Arctic provided spatial and temporal trends in support of Canada's participation in the Stockholm Convention of Persistent Organic Pollutants. The specific analytical laboratory charged with this task was changed in 2002 while field sampling protocols remained unchanged. Three rounds of intensive comparison studies were conducted in 2004, 2005, and 2008 to assess data comparability between the two laboratories. Analysis was compared for organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) in standards, blind samples of mixed standards and extracts of real air samples. Good measurement accuracy was achieved for both laboratories when standards were analyzed. Variation of measurement accuracy over time was found for some OCPs and PCBs in standards on a random and non-systematic manner. Relatively low accuracy in analyzing blind samples was likely related to the process of sample purification. Inter-laboratory measurement differences for standards (<30%) and samples (<70%) were generally less than or comparable to those reported in a previous inter-laboratory study with 21 participating laboratories. Regression analysis showed inconsistent data comparability between the two laboratories during the initial stages of the study. These inter-laboratory differences can complicate abilities to discern long-term trends of pollutants in a given sampling site. It is advisable to maintain long-term measurements with minimal changes in sample analysis. 相似文献
110.