A comparison of water solubilities by the flask and micro-column methods

A comparative examination of the two procedures of the OECD Test Guideline: Water Solubility was undertaken using carbazole, fluoranthene, anthracene, hexachlorobenzene, p-nitroaniline and diphenylamine. The flask method was modified to provide for dissolution of the solute from the surface of glass beads. By the proposed flask method, one can accurately measure the water solubility down to the order of 10 μg/L as well as those of the order of %. The micro-column method, which requires a number of concentration determinations to ensure that a saturated solution has been obtained, is recommended for the solubility range of 10 mg/L through 10 μg/L. The flask method using the procedures described in this study, covers the range of solubility above 10 μg/L with only two determinations one being a simple preliminary test and the other a precise measurement.     

Satellite Tracking of White-naped Crane Migration and the Importance of the Korean Demilitarized Zone

Satellite-tracking of 15 White-naped Cranes ( Grus vipio ) from their Japanese wintering grounds through the Korean Peninsula shows that there are four important regions for conserving migrant cranes: the Three Rivers Plain, the People's Republic of China; Lake Khanka, Russia; Kumya, North Korea; and—most importantly—the demilitarized zone of the Korean Peninsula. Two sites along the Korean demilitarized zone, Panmunch'om and Ch'olwon, were the most heavily used stopover sites, and they present complex international conservation challenges. Cranes stopped at these sites for up to 87.1% of their total migration time; cranes migrating to Zhalong Nature Reserve, China, made it their only lengthy stop. We report the migration routes and the importance of the identified stopover sites, and we outline conservation issues at those sites.     

A basic study with feasibility of applying clean development mechanism to the transport projects

In the transport sector, few projects applied Clean Development Mechanism (CDM) or Joint Implementation (JI) projects. This study will examine the feasibility of applying CDM to the transport sector from viewpoints of validation of processes and funding. A number of greenhouse gas emission reduction projects, as well as traffic management project within existing transport infrastructures, can be implemented as CDM projects. New transport infrastructure projects can be validated by transportdemand forecasting and traffic simulation methods, though application of Life Cycle Assessment (LCA) and Intelligent Transport Systems (ITS) technologies. This revised version was published online in August 2006 with corrections to the Cover Date.     

A putative octopamine/tyramine receptor mediating appetite in a hungry fly

In the blowfly Phormia regina, experience of simultaneous feeding with d-limonene exposure inhibits proboscis extension reflex (PER) due to decreased tyramine (TA) titer in the brain. To elucidate the molecular mechanism of TA signaling pathway related to the associated feeding behavior, we cloned cDNA encoding the octopamine/TA receptor (PregOAR/TAR). The deduced protein is composed of 607 amino acid residues and has 7 predicted transmembrane domains. Based on homology and phylogenetic analyses, this protein belongs to the OAR/TAR family. The PregOAR/TAR was mainly expressed in head, with low levels of expression in other tissues at adult stages. Gene expression profile is in agreement with a plethora of functions ascribed to TA in various insect tissues. The immunolabeled cell bodies and processes were localized in the medial protocerebrum, outer layer of lobula, antennal lobe, and subesophageal ganglion. These results suggest that decrease of TA level in the brain likely affects neurons expressing PregOAR/TAR, causing mediation of the sensitivity in the sensillum and/or output of motor neurons for PER.     

Amelioration effect of humic acid extracted from solubilized excess sludge on saline-alkali soil

In this study, the main characteristics and soil amendment effects on the saline–alkali soil of humic acid extracted from solubilized excess sludge (SS-HA) were investigated. The excess sludge was solubilized prior to extraction to improve the humic acid recovery rate. The structural features of SS-HA were characterized by an elemental analysis, Fourier transform infrared spectroscopy, and ¹H-nuclear magnetic resonance spectroscopy, and compared with those of HA extracted from non-solubilized excess sludge (ES-HA). The results showed that extraction efficiency of humic acid was enhanced by using solubilization, although structural properties of humic acid extracted from solubilized excess sludge were almost the same as those of ES-HA. To study a utilization method of SS-HA, the soil amendment effects on saline–alkali soil by mixture of SS-HA were investigated with a model soil-column experiment. SS-HA reduced the pH of the saline–alkali soil, and the effect was immediately observed or faster than the case in which only peat is added. Moreover, the cation exchangeable capacity of the saline–alkali soil was enhanced by addition of SS-HA.     

Photodegradation of the synthetic fragrance OTNE and the bactericide triclosan adsorbed on dried loamy sand--results from models and experiments

Fragrances such as OTNE (marketed as Iso-E-Super®) and bactericides such as triclosan (marketed as Igrasan) are present in waste water and thus finally sorbed to sewage sludge. With that sludge they can reach agricultural fields where they potentially can undergo photodegradation processes. In this study the photodegradation of OTNE and triclosan on dried loamy sand was measured under artificial sunlight conditions in laboratory experiments. These compounds were artificially added with concentrations of 1 μg g⁻¹ on pre-rinsed dried loamy sand. The decrease in concentration with light irradiation was measured for 32 d in comparison to soil samples without light irradiation. The estimated light source intensity was 27 W m⁻². Within the experiment, the apparent half-life was 7 and 17 d for OTNE and triclosan respectively. The decrease did not simply follow first-order kinetics. The apparent rate constant decreased in the latter stage of reaction, suggesting that part of the chemicals were inaccessible for degradation. Two models, i.e., a diffusion-limited model, and a light penetration-limited model, were used in comparison to the measured data to explain the observed degradation limitations in the latter stages of the experiments. Comparing the hereby obtained model parameters with estimated physico-chemical parameters for the soil and the two chemical compounds, the light penetration-limited model, in which the degradation in the soil surface layer is assumed to be limited due to the shading effect of light in the upper thin soil layer, showed to be the most realistic in describing the photodegradation.     

Biogeochemical properties and potential risk of shallow arsenic-rich sediment layers to groundwater quality in Western Bangladesh

Environmental Geochemistry and Health - The arsenic-contaminated groundwater has attracted attention in much south and southeast Asian deltas, however, mainly on the deep aquifers. Here, arsenic...     

Accumulation of Hg and other heavy metals in the Javan mongoose (Herpestes javanicus) captured on Amamioshima Island, Japan

Concentrations of 22 elements (Mg, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, Tl, total Hg (T-Hg), Pb) and organic Hg (O-Hg) were examined in the liver, kidney and brain of the Javan mongoose (Herpestes javanicus) and in liver of the Amami rabbit (Pentalagus furnessi) from Amamioshima Island in Japan. Relatively high levels of T-Hg levels (from 1.75 to 55.5 microg g-1 wet wt.) were found in the Javan mongoose. As for a comparison of hepatic T-Hg concentrations between the two areas, there was no significant difference between the Javan mongoose in Amamioshima and those in the Okinawa islands. In addition, T-Hg levels in the livers of the Amami rabbit were the same as in the livers of other herbivorous mammals. Taken together, it suggested that T-Hg accumulation in the livers of the Javan mongoose was not affected by the environment but by a specific physiological mechanism. The comparison of Hg and other heavy metal accumulations between terrestrial mammals (13 species, 61 individuals) including the Javan mongoose and marine mammals (18 species, 508 individuals) were also discussed.