The adults of the leaf beetle Platyphora kollari (Chrysomelidae) are able to metabolise the oleanane triterpene β-amyrin (1) into the glycoside 3-O-β-d-glucopyranosyl-(1→4)-β-d-glucuronopyranosyl-hederagenin (2) that is stored in their defensive glands. The aim of this study was to test the hypothesis that oleanolic acid (3) is an intermediate in the conversion of 1 into 2 and to check whether the sequestration of pentacyclic triterpenes is selective in favour of β-amyrin (1). To this end, adults of P. kollari were fed with Ipomoea batatas leaf disks painted with a solution of [2,2,3-2H3]oleanolic acid or [2,2,3-2H3]α-amyrin and the secretion of their defensive glands analysed by HPLC–ESIMS. The data presented in this work indicated that
the first step of the transformation of β-amyrin (1) into the sequestered glycoside 2 is its oxidation into oleanolic acid (3) and that this conversion is selective but not specific in favour of β-amyrin (1). 相似文献
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As an important renewable energy source, wind power plays a key role in mitigating climate change and has become one of the fastest growing clean energies globally. In China, wind energy development has been a vital component of national energy transformation strategy. Over the years, the Chinese government has introduced a series of policies to promote the development of wind power and also to regulate this emerging industry. Base on examining all the key policy documents on wind power issued by the Chinese government over the last 30 years, we find that China has built up a comprehensive policy system, and summarized the current framework of Chinese wind power policy systematically. Then, we analyze the policy objectives, policy tools, major measures, their results in each development stage, and the characteristics and trends of China’s wind power policies. Finally, we discuss the limitations of the current policy and put forward corresponding suggestions.