Although research regarding antibiotic resistance genes (ARGs) in aquaculture environments has gained increasing scientific interest, further studies are required to understand the abundances and removal mechanisms of ARGs during the entire rearing period of shrimp aquaculture. Thus, in this study, abundances, distributions and removal rates of ARGs in different environmental compartments of intensive shrimp farms in South China were investigated during the entire rearing period. The results indicated that sul1 and cmlA were the predominant ARGs in the water and sediment samples. Additionally, the total abundance of ARGs was higher in shrimp pond water than in the source water and farm effluent. Moreover, sediment samples indicated significantly higher ARG abundances than water samples from the shrimp ponds (P?<?0.05). Environmental factors were found to significantly affect the distribution of ARGs in shrimp rearing environments. Furthermore, stable ponds aided the removal of ARGs from shrimp pond water. This study accounted for temporal variations in ARG abundances as well as removal of ARGs in different environmental compartments during the entire shrimp rearing period. However, additional research is required to optimize the water treatment process for removal of ARGs from the aquaculture. 相似文献
In order to give an effective and rapid analysis of the photochemical pollution and information for emission control strategies, a photochemical box model (PBM) was applied to one moderate summer episode, 11 July 1996, and one typical winter episode, 3 December 1996, in the center of Tokyo, Japan. The box model gave a good prediction of the photochemical pollution with minimal investment. As expected, the peak ozone in summer is higher than in winter. The NOx concentrations in winter are higher than those in summer. In summer, NO and NO2 have one peak in the morning. In winter, NO and NO2 show two peaks during the day. Three model runs including no reactions, a zero ozone boundary condition and dark reactions were conducted to understand the photochemical processes. The effects of emission reduction on the formation of the photochemical pollution in the center of Tokyo have been studied. The results show that the reduction of NMHC emission can decrease the ozone, however, the reduction of NOx emission can increase the ozone. It can be concluded that if the NOx emission are reduced, the reduction of NMHC should be more emphasized in order to decrease the ozone concentration in the center of Tokyo, Japan, especially the reduction of the NMHC from stationary source emission. 相似文献
A kinetic model is developed for de novo synthesis of PCDD/F from carbon in incinerator fly ash. The main mechanistic steps considered in the model are carbon gasification, PCDD/F formation, desorption and degradation. Rate equations are derived which can relate PCDD/F formation with process variables including carbon concentration of fly ash, partial pressure of oxygen, reaction temperature and time. The kinetic model has been verified using laboratory de novo synthesis data reported in the literature. When the model is applied to industrial incinerator conditions, PCDD/F formation levels of 0.1-0.5 microg/N m3 in the gas phase and 0.1-1.2 microg/g in the solid phase are calculated, and both are in good agreement with incinerator measurements. 相似文献
Heavy metal-contaminated sediments posed a serious threat to both human beings and environment. A biosurfactant, rhamnolipid, was employed as the washing agent to remove heavy metals in river sediment. Batch experiments were conducted to test the removal capability. The effects of rhamnolipid concentration, washing time, solution pH, and liquid/solid ratio were investigated. The speciation of heavy metals before and after washing in sediment was also analyzed. Heavy metal washing was favored at high concentration, long washing time, and high pH. In addition, the efficiency of washing was closely related to the original speciation of heavy metals in sediment. Rhamnolipid mainly targeted metals in exchangeable, carbonate-bound or Fe-Mn oxide-bound fractions. Overall, rhamnolipid biosurfactant as a washing agent could effectively remove heavy metals from sediment.
It is well known that the dissolution of goethite plays an important role in catalyzing the oxidation of organic chemicals. Therefore, this study investigates how surface dissolution of goethite affects 2-chlorophenol oxidation in the goethite/H2O2 process. Experimental results indicate that ligand and reductant can enhance the dissolution rate of goethite, which is surface-controlled. Our results further indicate 2-chlorophenol degradation depends on goethite concentration. In addition, the oxidation rate of 2-CP is correlated with reductive dissolution rate at various dosages of goethite. Moreover, the oxidation mechanism of 2-CP is also a surface-controlled reaction. A mechanism proposed herein indicates that, in addition to the contaminant, its intermediate species affect the oxidation rate as well. 相似文献
Plastic waste is a source of organic contaminants such as hexabromocyclododecanes (HBCDs). HBCDs have been found to cause developmental and reproductive toxicity; it is important to investigate the occurrence and metabolization of HBCDs in the soil environments with plastic waste contamination. This work analyzed HBCDs and their metabolites in soil and plant samples collected from Xinle and Dingzhou—the major plastic waste recycling centers in North China. Results showed that total HBCD concentrations in soils followed the order: plastic waste treatment site (11.0–624 ng/g) > roadside (2.96–85.4 ng/g) ≥ farmland (8.69–55.5 ng/g). HBCDs were detected in all the plant samples with total concentrations ranging from 3.47 to 23.4 ng/g. γ-HBCD was the dominant congener in soils, while α-HBCD was preferentially accumulated in plants. Compositions of HBCD isomers in soils and plants were significantly different (P < 0.05) among sampling sites and among plant species. HBCDs in farmland soil and all plant samples exhibited high enantio-selectivity based on the enantiomeric fractions (EFs). Furthermore, metabolites of pentabromocyclododecenes (PBCDEs) were frequently identified in soils, and mono-OH-HBCDs were the most common ones in plants. This study for the first time provides evidences of HBCD contamination in the soil-plant system caused by plastic waste, their stereo-selectivity, and metabolization behavior, improving our understanding of the environmental behavior and fate of HBCDs. 相似文献