Role of halogen(I) cation-transfer mechanisms in water chlorination in the presence of bromide ion

Bromide ion is rapidly converted to HOBr via BrCl by reaction with HOCl. The subsequent slow reactions of (HOCl, OCl-)/(HOBr, OBr-) mixtures are monitored directly by multiwavelength UV-vis absorbance methods and simultaneously by ion chromatographic measurement of ClO2-, ClO3-, and BrO3- (p[H+] 5.6-7.6). A first-order loss of HOCl is observed which is catalyzed by trace concentrations of Br- and BrCl. Chlorite ion forms first and is subsequently oxidized to ClO3-. The loss of HOBr is slower and is second-order in HOBr, so that BrO3- formation takes longer than ClO3- formation. Under the conditions of this work, the relative yield of BrO3- increases with increase in pH. The decomposition of HOCI by bromide proceeds primarily by a series of halogen(I) cation-transfer reactions with subsequent halide release. The presence of HOCI increases the BrO3- yield three-fold from HOBr decay alone.     

HEAVY RAINFAL RELATIONS OVER CHICAGO AND NORTHEASTERN ILLINOIS1

ABSTRACT: Detailed studies of rainfall frequency and pattern relations were made over the Chicago urban region and the surrounding six Illinois counties (Cook, DuPage, Kane, Will, Lake, and McHenry). These studies utilized raingage records from an urban network of National Weather Service raingages in the region, primarily for the period 1949 to 1974. Frequency distributions of point rainfall were obtained for periods from 5 minutes to 72 hours and recurrence intervals of 6 months to 50 years. These results indicated a spatial pattern of short-duration heavy rainfall frequencies related to urban-lake effects, particularly in the huge industrial region over the southern portion of Chicago. The time distribution within heavy rainstorms over the urban region was determined, and it was found that the point rainfall relations over the urban region were similar to a 12-year sample of a dense raingage network over a rural area in central Illinois. The characteristics of heavy rainfall over northeast Illinois were also studied through the use of heavy, 1-day storms. A total of 87 storms, capable of producing local flooding, were analyzed to determine 1) the frequency distribution of storm centers, 2) seasonal and diurnal distribution of storms, and 3) orientation and movement of storms.     

Long-term toxicology and carcinogenicity of 2,4,6-trichlorophenol

Carcinogenesis bioassays were conducted by giving 2,4,6-trichlorophenol [2,4,6-TCP] in feed to groups of 50 male and female Fischer rats and male B6C3F1 mice for two years. Dietary concentrations were 0 [20/group], 5000 [0.5%], or 10,000 [1%] ppm. Female mice began with 10,000 and 20,000 ppm but after 38 weeks were lowered due to reduced body weights to 2500 and 5000 ppm for 67 weeks; exposures averaged 5200 and 10,400 ppm. Adverse effects at two years were leukocytosis and monocytosis of peripheral blood and hyperplasia of bone marrow in both sexes of rats. In mice, liver toxicity, including individual liver cell abnormalities, focal areas of cellular alteration, and focal and nodular areas of hyperplasia were commonly present. Regarding carcinogenic activity, TCP caused leukemias/lymphomas in male rats, and possibly in female rats and female mice as well, and induced liver tumors in male and female mice. Using NTP categories of evidence indicates ‘clear evidence of carcinogenicity’ for male rats [hematopoietic system tumors]; ‘equivocal evidence of carcinogenicity’ for female rats [hematopoietic system tumors]; ‘clear evidence of carcinogenicity’ for male and female mice [liver tumors].     

The Wreck of Amtrak's Sunset Limited: News Coverage of a Mass Transport Disaster

Using the 1993 crash of Amtrak's Sunset Limited in Mobile, Alabama, this study examines the safety education provided by seven newspapers. A total of 117 news stories were analysed for five primary themes: overall story category, passenger safety theme, train personnel safety theme, train safety theme and rescue safety. Sixty-three per cent were found to contain at least one safety theme paragraph within the larger story. A total of 631 paragraphs were identified as safety theme paragraphs, 32 per cent of which were passenger safety themes, 8 per cent were train personnel safety, 31 per cent were train safety and 29 per cent were rescue safety themes. As in previous research, safety themes rarely appeared alone; more often than not, a story contained a mixture of all themes. Some safety themes appeared more frequently than others, but overall, the safety themes present a complete view of the safety issues surrounding the crash.
Safety themes are embedded within a story framework which reflects the three stages of disaster news work. Images of normalcy tragically disrupted by the crash abound as do images of passengers escaping and aiding others. Disaster relief personnel and aviation officials are shown working to restore order and solve the mystery of the crash. Within this framework we can learn what to expect when a train crashes and what we might have to do in a similar situation.     

CHARACTERISTICS AND CONTRIBUTING CAUSES OF AN ABNORMAL FREQUENCY OF FLOOD-PRODUCING RAINSTORMS AT CHICAGO1

ABSTRACT: Major hydrometeorological factors pertinent to defining and understanding the hydrologic characteristics of urban and other small-basin storms were investigated using data from a continuous 44-year operation of a recording raingage network in Chicago. Factors included: the frequency distribution of basin mean rainfall and its relation to storm maximum precipitation; the spatial distribution characteristics of each storm, including storm rainfall reduction factors which are widely used in hydrologic design problems; and weather-related causes related to the frequency and intensity of severe rainstorms in the Chicago area in recent years. Results have indicated that urban mean rainfall frequencies were overestimated in earlier studies in which they were derived from point/areal mean rainfall ratios obtained from much shorter records on rural networks. Reduction factors were found to vary between urban and rural storm systems due to urban-related effects. Two factors were found to be potential contributors to the characteristics of severe rainstorm occurrences at Chicago. These include urban-induced rain enhancement and an upward climatic trend in the occurrence of heavy rainfall events during the sampling period. Study results should be generally applicable to other large urban areas in the Midwest and other regions of similar precipitation climate.     

An approach for determining bioassessment performance and comparability

Many organizations in the USA collect aquatic bioassessment data using different sampling and analysis methods, most of which have unknown performance in terms of data quality produced. Thus, the comparability of bioassessments produced by different organizations is often unknown, ultimately affecting our ability to make comprehensive assessments on large spatial scales. We evaluated a pilot approach for determining bioassessment performance using macroinvertebrate data obtained from several states in the Southeastern USA. Performance measures evaluated included precision, sensitivity, and responsiveness to a human disturbance gradient, defined in terms of a land disturbance index value for each site, combined with a value for specific conductance, and instream habitat quality. A key finding of this study is the need to harmonize ecoregional reference conditions among states so as to yield more comparable and consistent bioassessment results. Our approach was also capable of identifying potential areas for refinement such as reevaluation of less precise, sensitive, or responsive metrics that may result in suboptimal index performance. Higher performing bioassessments can yield information beyond “impaired” versus “unimpaired” condition. Acknowledging the limitations of this pilot study, we would recommend that performance evaluations use at least 50 sites, 10 of which are ecoregional reference sites. Efforts should be made to obtain data from the entire human disturbance gradient in an ecoregion to improve statistical confidence in performance measures. Having too few sites will result in an under-representation of certain parts of the disturbance gradient (e.g., too few poor quality sites), which may bias sensitivity and responsiveness estimates.     

Prenatal diagnosis and investigation of a fetus with chondrodysplasia punctata,ichthyosis, and Kallmann syndrome due to an Xp deletion

We report the prenatal diagnosis of a male fetus with X-linked recessive chondrodysplasia punctata (CDPX), steroid sulphatase (STS) deficiency, X-linked Kallmann syndrome (KAL), and a chromosome deletion at Xp22.31. Biochemical analysis of bone from this case indicates that CDPX is not a defect of vitamin K metabolism. Immunocytochemical study of the brain suggests that KAL is a defect in neuronal migration.