Occurrence, fate and antibiotic resistance of fluoroquinolone antibacterials in hospital wastewaters in Hanoi, Vietnam

Occurrence and behavior of fluoroquinolone antibacterial agents (FQs) were investigated in hospital wastewaters in Hanoi, Vietnam. Hospital wastewater in Hanoi is usually not treated and this untreated wastewater is directly discharged into one of the wastewater channels of the city and eventually reaches the ambient aquatic environment. The concentrations of the FQs, ciprofloxacin (CIP) and norfloxacin (NOR) in six hospital wastewaters ranged from 1.1 to 44 and from 0.9 to 17 micrgl(-1), respectively. Total FQ loads to the city sewage system varied from 0.3 to 14 g d(-1). Additionally, the mass flows of CIP and NOR were investigated in the aqueous compartment in a small wastewater treatment facility of one hospital. The results showed that the FQ removal from the wastewater stream was between 80 and 85%, probably due to sorption on sewage sludge. Simultaneously, the numbers of Escherichia coli (E. coli) were measured and their resistance against CIP and NOR was evaluated by determining the minimum inhibitory concentration. Biological treatment lead to a 100-fold reduction in the number of E. coli but still more than a thousand E. coli colonies per 100ml of wastewater effluent reached the receiving water. The highest resistance was found in E. coli strains of raw wastewater and the lowest in isolates of treated wastewater effluent. Thus, wastewater treatment is an efficient barrier to decrease the residual FQ levels and the number of resistant bacteria entering ambient waters. Due to the lack of municipal wastewater treatment plants, the onsite treatment of hospital wastewater before discharging into municipal sewers should be considered as a viable option and consequently implemented.     

Bioaccessibility of polychlorinated biphenyls in different foods using an in vitro digestion method

Bioaccessibility of organic pollutants in food is important for exposure estimation and risk assessment. An in vitro enzyme digestion experiment was carried out to analyze the bioaccessibility of PCBs in different foods including freshwater fish (bighead carp and oriental weather fish) and vegetables (spinach and cabbage). The results indicated that the bioaccessibility of PCBs in freshwater fish (3%) was much lower than that in leafy vegetables (25%). Based on field survey, the daily exposure TEQ value from these two types of food was 17.9 pg/kg bw/day. However, when bioaccessibility was taken into consideration, the value decreased to 0.61 pg/kg bw/day. Therefore, the forms of PCBs existing in food strongly influenced the bioavailability for humans, which may have important implications on dietary exposure. To our knowledge, this is the first paper to illustrate the bioaccessibility of PCBs in different foods using an in vitro digestion method.     

Energy-efficient HVAC system through chillers’ capacity sizing for a library building

Heating, ventilating, and air-conditioning (HVAC) systems in commercial buildings consume the largest amount of energy. Recent surge in energy cost necessitates constant re-evaluation of HVAC system for most of the buildings. The objective of this study is to present the strategic approach on energy saving analysis of the HVAC system and chiller sizing optimization for a library building. Energy modeling code (eQUEST) for buildings simulation has been applied to verify and predict the long-term energy consumption of HVAC systems. To improve the accuracy of simulation results, the actual performance curves of the chillers and pumps were the inputs of curve fitting data from on-site field measurements data. Energy consumption data acquisition from the building energy management system (BEMS) for one year has been conducted comprehensively to calibrate energy modeling and to quantify energy saving results. The results revealed good agreement between energy modeling and BEMS data with the error of less than 10%. Besides, energy savings through the chillers’ sizing based on cooling load profile could be achieved satisfactorily by utilizing energy modeling by using the actual chiller performance curve. The energy saving for HVAC system can be obtained satisfactorily at the saving of 110,362 kWh per year. It is expected that the study will stimulate a more robust investigation of energy-efficient and cost-effective HVAC system specific for library buildings.     

Integrated process development for the recovery of Europium and Yttrium from waste fluorescent powder

Journal of Material Cycles and Waste Management - Fluorescent powder plays an important role in the modern electronic lighting products. During the production of electronic lighting products, a...     

Gender differences in wayfinding in virtual environments with global or local landmarks

This study assesses gender differences in wayfinding in environments with global or local landmarks by analyzing both overall and fine-grained measures of performance. Both female and male participants were required to locate targets in grid-like virtual environments with local or global landmarks. Interestingly, the results of the two overall measures did not converge: although females spent more time than males in locating targets, both genders were generally equivalent in terms of corrected travel path. Fine-grained measures account for different aspects of wayfinding behavior and provide additional information that explains the divergence in overall measures; females spent less time traveling away from the target location, a higher proportion of time not traversing, and made more rotations when stopping than males did. Rather than unequivocally supporting male superiority in wayfinding tasks, both the overall and fine-grained measures partially indicate that males and females are differentially superior when using global and local landmark information, respectively. To summarize, males moved faster than females but did not necessarily navigate the spatial surroundings more efficiently. Each gender showed different strengths related to wayfinding; these differences require the application of both overall and fine-grained measures for accurate assessment.     

Catalytic Destruction of Dichloromethane Using Perovskite-Type Oxide Catalysts

Abstract

Dichloromethane (DCM, also known as methylene chloride [CH₂Cl₂]) is often present in industrial waste gas and is a valuable chemical product in the chemical industry. This study addresses the oxidation of airstreams that contain CH₂Cl₂ by catalytic oxidation in a tubular fixed-bed reactor over perovskite-type oxide catalysts. This work also considers how the concentration of influent CH₂Cl₂ (C_o = 500-1000 ppm), the space velocity (GHSV = 5000-48,000 1/hr), the relative humidity (RH = 10-70%) and the concentration of oxygen (O₂ = 5-21%) influence the operational stability and capacity for the removal of CH₂Cl_2.

The surface area of lanthanum (La)-cobalt (Co) composite catalyst was the greatest of the five perovskite-type catalysts prepared in various composites of La, strontium, and Co metal oxides. Approximately 99.5% CH₂Cl₂ reduction was achieved by the catalytic oxidation over La-CoO₃-based perovskite catalyst at 600 °C. Furthermore, the effect of the initial concentration and reaction temperature on the removal of CH₂Cl₂ in the gaseous phase was also monitored. This study also provides information that a higher humidity corresponds to a lower conversion. Carbon dioxide and hydrogen chloride were the two main products of the oxidation process at a relative humidity of 70%.     

Determination of the Adsorption Isotherm of Vapor-Phase Mercury Chloride on Powdered Activated Carbon Using Thermogravimetric Analysis

Abstract

This study investigated the use of thermogravimetric analysis (TGA) to determine the adsorptive capacity and adsorption isotherm of vapor-phase mercury chloride on powdered activated carbon (PAC). The technique is commonly applied to remove mercury-containing air pollutants from gas streams emitted from municipal solid waste incinerators. An alternative form of powdered activated carbon derived from a pyrolyzed tire char was prepared for use herein. The capacity of waste tire-derived PAC to adsorb vapor-phase HgCl₂ was successfully measured using a self-designed TGA adsorption system. Experimental results showed that the maximum adsorptive capacities of HgCl₂ were 1.75, 0.688, and 0.230 mg of HgCl₂ per gram of powdered activated carbon derived from carbon black at 30, 70, and 150 °C for 500 µg/m³ of HgCl₂, respectively. Four adsorption isotherms obtained using the Langmuir, Freundlich, Redlich-Peterson, and Brunauer–Emmett–Teller (BET) models were used to simulate the adsorption of HgCl₂. The comparison of experimental data associated with the four adsorption isotherms indicated that BET fit the experimental results better than did the other isotherms at 30 °C, whereas the Freundlich isotherm fit the experimental results better at 70 and 150 °C. Furthermore, the calculations of the parameters associated with Langmuir and Freundlich isotherms revealed that the adsorption of HgCl₂ by PAC-derived carbon black favored adsorption at various HgCl₂ concentrations and temperatures.     

Site-specific water quality guidelines: 2. Development of a water quality regulation framework for pulse exposures of mine water discharges at a uranium mine in northern Australia

The Ranger Uranium Mine, in northern Australia, is monitored by the Supervising Scientist Division (SSD) of the Australian Government to ensure that it does not impact on the highly valued aquatic ecosystems of Kakadu National Park. In 2010, the SSD adopted the continuous monitoring of electrical conductivity (EC) and turbidity, in combination with event-triggered automated grab samples, as its primary water quality monitoring method. The continuous monitoring of EC has shown that mine discharges typically occur over short-term ‘pulse’ durations of minutes to hours. Given that magnesium (Mg) is the most likely mine-derived solute to approach or exceed the applicable water quality limit value, the focus has been on developing a pulse exposure assessment framework for Mg, as represented by its proxy EC, which is tracked by the continuous monitoring system. This study presents a possible ecotoxicologically derived Mg pulse exposure limit and trigger regulation framework for Magela and Gulungul Creeks and an assessment of historic continuous monitoring EC data from these creeks. This framework demonstrates potential to supersede the current EC guideline and associated trigger levels, which are statistically derived from historic grab sample data.     

Water quality guidelines for chemicals: learning lessons to deliver meaningful environmental metrics

Many jurisdictions around the globe have well-developed regulatory frameworks for the derivation and implementation of water quality guidelines (WQGs) or their equivalent (e.g. environmental quality standards, criteria, objectives or limits). However, a great many more still do not have such frameworks and are looking to introduce practical methods to manage chemical exposures in aquatic ecosystems. There is a potential opportunity for learning and sharing of data and information between experts from different jurisdictions in order to deliver efficient and effective methods to manage potential aquatic risks, including the considerable reduction in the need for aquatic toxicity testing and the rapid identification of common challenges. This paper reports the outputs of an international workshop with representatives from 14 countries held in Hong Kong in December 2011. The aim of the workshop and this paper was to identify ‘good practice’ in the development of WQGs to deliver to a range of environmental management goals. However, it is important to broaden this consideration to cover often overlooked facets of implementable WQGs, such as demonstrable field validation (i.e. does the WQG protect what it is supposed to?), fit for purpose of monitoring frameworks (often an on-going cost) and finally how are these monitoring data used to support management decisions in a manner that is transparent and understandable to stakeholders. It is clear that regulators and the regulated community have numerous pressures and constraints on their resources. Therefore, the final section of this paper addresses potential areas of collaboration and harmonisation. Such approaches could deliver a consistent foundation from which to assess potential chemical aquatic risks, including, for example, the adoption of bioavailability-based approaches for metals, whilst reducing administrative and technical burdens in jurisdictions.     

Exposure assessment of lead to workers and children in the battery recycling craft village,Dong Mai,Vietnam

Human exposure to lead (Pb) due to uncontrolled Pb-acid battery recycling has been an environmental health issue in newly developed industrial regions. We conducted a human monitoring survey in Dong Mai, a battery recycling village in Vietnam, to assess exposure status to Pb. Lead level was measured in hair, blood and urine samples of residents in Dong Mai and two reference sites during 4 years spanning 2007–2011. In Dong Mai, Pb levels in three matrixes were significantly higher than those in reference sites. Blood Pb levels of all adults and children exceeded 10 μg/dL, the Centers for Disease Control and Prevention definition of an elevated blood Pb level. Clear increase of urinary δ-aminolevulinic acid (ALA) level with increasing blood Pb level indicated disruption of heme synthesis. One adult exceeded 100 μg/dL of blood Pb, where encephalopathy is of concern. The blood Pb levels achieved various toxic effect threshold values, and elevated blood Pb was not limited to recycling workers, but was also in children and women of reproductive age. Serious pollution status of Dong Mai village suggests an importance of further monitoring surveys in various developing Asian countries.