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21.
22.
Parise Henry Olufunmilayo Owopetu Demilade Adisa Thao Nguyen Kevin Anthony David Ijoni-Animadu 《Journal of environmental science and health. Part. B》2016,51(8):546-552
The free living nematode Caenorhabditis elegans is a proven model organism for lipid metabolism research. Total lipids of C. elegans were extracted using chloroform and methanol in 2:1 ratio (v/v). Fatty acids composition of the extracted total lipids was converted to their corresponding fatty acids methyl esters (FAMEs) and analyzed by gas chromatography/accurate mass quadrupole time of flight mass spectrometry using both electron ionization and chemical ionization techniques. Twenty-eight fatty acids consisting of 12 to 22 carbon atoms were identified, 65% of them were unsaturated. Fatty acids containing 12 to17 carbons were mostly saturated with stearic acid (18:0) as the major constituent. Several branched-chain fatty acids were identified. Methyl-14-methylhexadecanoate (iso- 17:0) was the major identified branched fatty acid. This is the first report to detect the intact molecular parent ions of the identified fatty acids in C. elegans using chemical ionization compared to electron ionization which produced fragmentations of the FAMEs. 相似文献
23.
Ester Heath Marjeta Česen Noelia Negreira Miren Lopez de Alda Laura Ferrando-Climent Lucie Blahova Tung Viet Nguyen Mohamed Adahchour Achim Ruebel Neville Llewellyn Janez Ščančar Srdjan Novaković Vesna Mislej Marjeta Stražar Damià Barceló Tina Kosjek 《Environmental science and pollution research international》2016,23(15):14692-14704
The results of an inter-laboratory comparison exercise to determine cytostatic anticancer drug residues in surface water, hospital wastewater and wastewater treatment plant effluent are reported. To obtain a critical number of participants, an invitation was sent out to potential laboratories identified to have the necessary knowledge and instrumentation. Nine laboratories worldwide confirmed their participation in the exercise. The compounds selected (based on the extent of use and laboratories capabilities) included cyclophosphamide, ifosfamide, 5-fluorouracil, gemcitabine, etoposide, methotrexate and cisplatinum. Samples of spiked waste (hospital and wastewater treatment plant effluent) and surface water, and additional non-spiked hospital wastewater, were prepared by the organising laboratory (Jo?ef Stefan Institute) and sent out to each participant partner for analysis. All analytical methods included solid phase extraction (SPE) and the use of surrogate/internal standards for quantification. Chemical analysis was performed using either liquid or gas chromatography mass (MS) or tandem mass (MS/MS) spectrometry. Cisplatinum was determined using inductively coupled plasma mass spectrometry (ICP-MS). A required minimum contribution of five laboratories meant that only cyclophosphamide, ifosfamide, methotrexate and etoposide could be included in the statistical evaluation. z-score and Q test revealed 3 and 4 outliers using classical and robust approach, respectively. The smallest absolute differences between the spiked values and the measured values were observed in the surface water matrix. The highest within-laboratory repeatability was observed for methotrexate in all three matrices (CV?≤?12 %). Overall, inter-laboratory reproducibility was poor for all compounds and matrices (CV 27–143 %) with the only exception being methotrexate measured in the spiked hospital wastewater (CV?=?8 %). Random and total errors were identified by means of Youden plots. 相似文献
24.
Impact of temperature on the dynamics of organic matter and on the soil-to-plant transfer of Cd,Zn and Pb in a contaminated agricultural soil 总被引:1,自引:0,他引:1
Jean-Yves Cornu L. Denaix J. Lacoste V. Sappin-Didier C. Nguyen A. Schneider 《Environmental science and pollution research international》2016,23(4):2997-3007
Predicting the soil-to-plant transfer of metals in the context of global warming has become a major issue for food safety. It requires a better understanding of how the temperature alters the bioavailability of metals in cultivated soils. This study focuses on one agricultural soil contaminated by Cd, Zn and Pb. DGT measurements were performed at 10, 20 and 30 °C to assess how the bioavailability of metals was affected by a rise in soil temperature. A lettuce crop was cultivated in the same conditions to determine if the soil-to-plant transfer of metals increased with a rise in soil temperature. A gradual decline in Cd and Zn bioavailability was observed from 10 to 30 °C, which was attributed to more intense complexation of metals in the pore water at higher temperatures. Together with its aromaticity, the affinity of dissolved organic matter (DOM) for metals was indeed suspected to increase with soil temperature. One main output of the present work is a model which satisfactorily explains the thermal-induced changes in the characteristics of DOM reported in Cornu et al. (Geoderma 162:65–70, 2011) by assuming that the mineralization of initial aliphatic compounds followed a first-order reaction, increased with soil temperature according to the Arrhenius law, and due to a priming effect, led to the appearance of aromatic molecules. The soil-to-plant transfer of Cd and Zn was promoted at higher soil temperatures despite a parallel decrease in Cd and Zn bioavailability. This suggests that plant processes affect the soil-to-plant transfer of Cd and Zn the most when the soil temperature rises. 相似文献
25.
C. Nguyen A. J. Soulier P. Masson S. Bussière J. Y. Cornu 《Environmental science and pollution research international》2016,23(4):3152-3164
This work focuses on the exposure of maize plants to nanomolar concentrations of Cd, which is relevant for agricultural soils cropped with food and feed plants. Maize plants were cultivated in nutrient solution at 0.8 or 20 nM Cd during the vegetative growth stages. No significant hormesis or toxic effects of Cd were observed on maize growth, but a decrease in the allocation of Cd to shoots between the 0.8 and 20 nM Cd exposures revealed that the plants already responded to these low concentrations of Cd according to a shoot Cd excluder strategy. The Cd, Cu and Zn concentrations in shoots decreased with time as the result of an early decrease in the root/shoot ratio and of a decrease in the coefficient of allocation to aboveground for Zn and Cd at 20 nM. As a consequence, shoots of young plants were richer in micronutrients Cu and Zn but also in toxic Cd. The rate of delivery of Cd, Cu and Zn from xylem sap was successfully used to predict the time course of concentrations of Cd, Cu and Zn in the shoot. However, it overestimated the actual concentrations of Cd in the shoot, presumably because the reallocation of this trace element from shoots back to roots was not taken into account. 相似文献
26.
Robin Warner Mary Kaidonis Olivia Dun Kerrylee Rogers Yubing Shi Thang T. X. Nguyen Colin D. Woodroffe 《Sustainability Science》2016,11(4):661-677
Increasing value is attributed to mangroves due to their considerable capacity to sequester carbon, known as ‘blue carbon’. Assessments of opportunities and challenges associated with estimating the significance of carbon sequestered by mangroves need to consider a range of disciplinary perspectives, including the bio-physical science mangroves, social and economic issues of land use, local and international law, and the role of public and private finance. We undertook an interdisciplinary review based on available literature and fieldwork focused on parts of the Mekong River Delta (MRD). Preliminary estimates indicate mangrove biomass may be 70–150 t ha?1, but considerably larger storage of carbon occurs in sediments beneath mangroves. These natural stores of carbon are compromised when mangroves are removed to accommodate anthropogenic activities. Mangroves are an important resource in the MRD that supplies multiple goods and services, and conservation or re-establishment of mangroves provides many benefits. International law and within-country environmental frameworks offer increasing scope to recognize the role that mangrove forests play through carbon sequestration, in order that these might lead to funding opportunities, both in public and private sectors. Such schemes need to have positive rather than negative impacts on the livelihoods of the many people living within and adjacent to these wetlands. Nevertheless, many challenges remain and it will require further targeted and coordinated scientific research, development of economic and social incentives to protect and restore mangroves, supportive law and policy mechanisms at global and national levels, and establishment of long-term financing for such endeavours. 相似文献
27.
Hoang Huu Nguyen Paul Dargusch Patrick Moss Da Binh Tran 《Regional Environmental Change》2016,16(8):2303-2315
This paper examines the anthropogenic factors that have contributed to wetland loss and degradation in the Mekong Delta, Vietnam from 1816 AD to present. Our analysis is framed over five historical periods and highlights the role that seven drivers of wetland degradation have played in the Mekong Delta, including: resettlement and economic development policies; population growth and urbanization; demand for food and reclaiming wetland for agriculture; construction of canals construction of dykes flood protection systems; expansion of travel systems (waterway and roads); and exploitation of wetland natural resources. Of these, government policies for resettlement and economic development seem to have had the greatest impact on wetland loss and degradation in the Mekong Delta throughout the course of history. As a result of these factors, only 0.068 million hectares of the original 4.0 million hectares of the Mekong Delta currently remains as primary swamp forest ecosystem. History suggests that future management of the Mekong Delta should take a holistic approach that includes a better understanding of the implications of past decisions on wetland loss. 相似文献
28.
Contamination of groundwater and risk assessment for arsenic exposure in Ha Nam province, Vietnam 总被引:2,自引:0,他引:2
The characteristics of arsenic-contaminated groundwater and the potential risks from the groundwater were investigated. Arsenic contamination in groundwater was found in four villages (Vinh Tru, Bo De, Hoa Hau, Nhan Dao) in Ha Nam province in northern Vietnam. Since the groundwater had been used as one of the main drinking water sources in these regions, groundwater and hair samples were collected in the villages. The concentrations of arsenic in the three villages (Vinh Tru, Bo De, Hoa Hau) significantly exceeded the Vietnamese drinking water standard for arsenic (10 microg/L) with average concentrations of 348, 211, and 325 microg/L, respectively. According to the results of the arsenic speciation testing, the predominant arsenic species in the groundwater existed as arsenite [As(III)]. Elevated concentrations of iron, manganese, and ammonium were also found in the groundwater. Although more than 90% of the arsenic was removed by sand filtration systems used in this region, arsenic concentrations of most treated groundwater were still higher than the drinking water standard. A significant positive correlation was found between the arsenic concentrations in the treated groundwater and in female human hair. The risk assessment for arsenic through drinking water pathways shows both potential chronic and carcinogenic risks to the local community. More than 40% of the people consuming treated groundwater are at chronic risk for arsenic exposure. 相似文献
29.
Khoi Nguyen Alexandre Caboussat Donald Dabdub 《Atmospheric environment (Oxford, England : 1994)》2009,43(40):6287-6295
Air quality models compute the transformation of species in the atmosphere undergoing chemical and physical changes. The numerical algorithms used to predict these transformations should obey mass conservation and positive definiteness properties. Among all physical phenomena, the chemical kinetics solver provides the greatest challenge to attain these two properties. In general, most chemical kinetics solvers are mass conservative but not positive definite. In this article, a new numerical algorithm for the computation of chemical kinetics is presented. The integrator is called Split Single Reaction Integrator (SSRI). It is both mass conservative and positive definite. It solves each chemical reaction exactly and uses operator splitting techniques (symmetric split) to combine them into the entire system.The method can be used within a host integrator to fix the negative concentrations while preserving the mass, or it can be used as a standalone integrator that guarantees positive definiteness and mass conservation. Numerical results show that the new integrator, used as a standalone integrator, is second order accurate and stable under large fixed time steps when other conventional integrators are unstable. 相似文献
30.
Spatial distribution and vertical profile of polybrominated diphenyl ethers and hexabromocyclododecanes in sediment core from Tokyo Bay, Japan 总被引:4,自引:0,他引:4
Minh NH Isobe T Ueno D Matsumoto K Mine M Kajiwara N Takahashi S Tanabe S 《Environmental pollution (Barking, Essex : 1987)》2007,148(2):409-417
Brominated flame retardants (BFRs), hexabromocyclododecanes (HBCDs) and polybrominated diethyl ethers (PBDEs) were detected in three sediment cores and six surface sediments of Tokyo Bay, Japan. HBCDs were detected for the first time in this region with concentrations ranging from 0.056 to 2.3 ng/g dry wt, implying their widespread contamination, even though their concentrations were lower than summation operatorPBDEs (di- to nona-BDEs) and BDE-209. Levels of these compounds were higher near to the highly populated industrial area of the bay implicating industrial and human activities as sources of these compounds. Summation operatorPBDEs increased in the sediment layer up to the mid-1990s and decreased afterwards, whereas BDE-209 showed an increasing trend until now, following the usage of different commercial BDE mixtures. HBCDs first appeared in the mid-1970s and increased until today. The annual surficial flux of HBCDs (0.62-2.4 ng/cm2/yr) is equal to summation operatorPBDEs (0.95-2.6 ng/cm2/yr) but lower than that of BDE-209 (17-58 ng/cm2/yr). 相似文献