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361.
Kwang V. Lo Winnie W. I. Chan Selina K. Yawson Ping H. Liao 《Journal of environmental science and health. Part. B》2013,48(4):362-367
This study investigated the treatment of dairy manure using the microwave enhanced advanced oxidation process (MW-AOP) at pH 2. An experimental design was developed based on a statistical program using response surface methodology to explore the effects of temperature, hydrogen peroxide dosage and heating time on sugar production, nutrient release and solids destruction. Temperature, hydrogen peroxide dosage and acid concentration were key factors affecting reducing sugar production. The highest reducing sugar yield of 7.4% was obtained at 160°C, 0 mL, 15 min heating time, and no H2O2 addition. Temperature was a dominant factor for an increase of soluble chemical oxygen demand (SCOD) in the treated dairy manure. The important factors for volatile fatty acids (VFA) production were microwave temperature and hydrogen peroxide dosage. Temperature was the most important parameter, and heating time, to a lesser extent affecting orthophosphate release. Heating time, hydrogen peroxide dosage and temperature were significant factors for ammonia release. There was a maximum of 96% and 196% increase in orthophosphate and ammonia concentration, respectively at 160°C, 0.5 mL H2O2 and 15 min heating time. The MW-AOP is an effective method in dairy manure treatment for sugar production, nutrient solubilisation, and solids disintegration. 相似文献
362.
S.H.A.D. Zayed I.M.I. Fakhr Somaia EL‐Magraby 《Journal of environmental science and health. Part. B》2013,48(4-5):467-478
Abstract Cholinesterase activity in the brain, RBC and plasma of Swiss mice was determined following different routes of administration of methamidophos. Continuous feeding with the insecticide caused a progressive inhibition of both plasma‐ and erythrocyte enzymes. The effect of methamidophos was more pronounced when applied in diet than when administered dermally or intraperitoneally. Following a single injection (i.p.) of methamidophos, the brain enzyme showed maximum inhibition 24 hr following treatment. At the appearance of tremors, the plasma and RBC‐enzymes showed considerable inhibition, the former being more inhibited. The plasma enzyme appears to be the most sensitive enzyme and may be taken as a suitable index for exposure to methamidophos. 相似文献
363.
Ralph I. Larsen 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1326-1339
Abstract The Clean Air Act Amendments of 1990 (CAAA-90) list 189 hazardous air pollutants (HAPs) for which “safe” ambient concentrations are to be determined. The primary purpose of this paper is to develop two mathematical models, lognormal and logarithmic, that effectively express excess lung cancer mortality as a function of asbestos concentration for an example set of data and also to suggest using these two models for additional HAPs. The secondary purpose of this paper is to calculate a “safe” asbestos concentration by first assuming a default linear extrapolation (to one excess death per million people, as specified for carcinogenic HAPs). The resulting “safe” concentration is an impossible-to-achieve 1/1000 of present background asbestos concentrations. A letter to the editor and a response in this Journal issue use additional asbestos data that suggest that the “safe” concentration should be about 730 times higher than first calculated here and that a default nonlinear extrapolation should be used instead, with the “safe” concentration proportional to the desired mortality level raised to the 0.39 power. These results suggest that the most important problem in setting a “safe” concentration for each carcinogenic HAP is to determine the correct nonlinear extrapolation to use for each HAP. 相似文献
364.
Chuen-Jinn Tsai Kai-Chung Cheng Shankar G. Aggarwal Tung-Sheng Shih I.-Fu Hung 《Journal of the Air & Waste Management Association (1995)》2013,63(10):1265-1272
Abstract A new triple filter system sampler/model is proposed for the precise and accurate simultaneous sampling and determination of gas- and aerosol-phase 2,4-toluene diisocyanate (TDI). The system consists of two front Teflon filters for sampling aerosol-phase TDI and a final coated glass fiber filter to collect gas-phase TDI. The aerosol-phase TDI is collected on the first Teflon filter, while the second Teflon filter is used to estimate gaseous TDI adsorbed by the first. According to the gas adsorption test of two Teflon filters in series, the TDI gas adsorption fraction of the two filters is almost the same. Results of the evaporation test using pure TDI aerosols collected on the Teflon filter show that significant evaporation of the compound does not occur during sampling. These two findings allow the use of a model to estimate accurate gasand aerosol-phase TDI concentrations. The comparison test with an annular denuder shows that the triple filter system can minimize the TDI sampling bias between the dual filter and the annular denuder systems. 相似文献
365.
Richard R. Anderson Donald V. Martello Leonard J. Lucas Cliff I. Davidson William K. Modey 《Journal of the Air & Waste Management Association (1995)》2013,63(9):1301-1319
Abstract Apportionment of primary and secondary pollutants during the summer 2001 Pittsburgh Air Quality Study (PAQS) is reported. Several sites were included in PAQS, with the main site (the supersite) adjacent to the Carnegie Mellon University campus in Schenley Park. One of the additional sampling sites was located at the National Energy Technology Laboratory, located ~18 km southeast of downtown Pittsburgh. Fine particulate matter (PM2.5) mass, gas-phase volatile organic material (VOM), particulate semivolatile and nonvolatile organic material (NVOM), and ammonium sulfate were apportioned at the two sites into their primary and secondary contributions using the U.S. Environmental Protection Agency UNMIX 2.3 multivariate receptor modeling and analysis software. A portion of each of these species was identified as originating from gasoline and diesel primary mobile sources. Some of the organic material was formed from local secondary transformation processes, whereas the great majority of the secondary sulfate was associated with regional transformation contributions. The results indicated that the diurnal patterns of secondary gas-phase VOM and particulate semivolatile and NVOM were not correlated with secondary ammonium sulfate contributions but were associated with separate formation pathways. These findings are consistent with the bulk of the secondary ammonium sulfate in the Pittsburgh area being the result of contributions from distant transport and, thus, decoupled from local activity involving organic pollutants in the metropolitan area. 相似文献
366.
Samantha Abraham Scott Joslyn I.H. Suffet 《Journal of the Air & Waste Management Association (1995)》2013,63(10):1217-1228
Biofilters are becoming an increasingly popular treatment device for odors and other volatiles found at wastewater treatment plants. A seashell media based biofilter was installed in April 2011 at Lake Wildwood Wastewater Treatment Plant located in Penn Valley, California. It was sampled seasonally to examine its ability to treat odorous compounds found in the air above the anaerobic equalization basin at the front end of the plant and to examine the properties of the biofilter and its recirculating water system. The odor profile method sensory panels found mainly sulfide odors (rotten eggs and rotten vegetable) and some fecal odors. This proved to be a useful guidance tool for selecting the required types of chemical sampling. The predominant odorous compounds found were hydrogen sulfide, methyl mercaptan and dimethyl sulfide. These compounds were effectively removed by the biofilter at greater than 99% removal efficiency therein reducing the chemical concentrations to below their odor thresholds. Aldehydes found in the biofilter were below odor thresholds but served as indicators of biological activity. Gas chromatography with mass spectrometry and gas chromatography with sensory detection showed the presence of dimethyl disulfide and dimethyl trisulfide as well, but barely above their respective odor thresholds. The neutrality of the pH of the recirculating water was variable depending on conditions in the biofilter, but a local neutral pH was found in the shells themselves. Other measurements of the recirculating water indicated that the majority of the bio-activity takes place in the first stage of the biofilter. All measurements performed suggest that this seashell biofilter is successful at removing odors found at Lake Wildwood. This study is an initial examination into the mechanism of the removal of odorous compounds in a seashell biofilter.Implications:?This paper presents a thorough examination of a seashell media biofilter, a sustainable treatment technology used to remove reduced sulfide compounds. The durable performance of the seashell biofilter ensures that odors will be adequately controlled, preventing odor nuisance to surrounding residences, which is an emerging problem faced by waste management facilities. The odor profile method technique used in this study can be applied in many situations by waste management facilities and regulatory air management organizations for source tracking in relation to prevention and management of odor complaints, respectively. 相似文献
367.
Although the high sensitivity of the Na/K pump in cell membrane to ionizing radiation is well known in literature, the individual
role of different isoforms of pump in determination of its radio-sensitivity is not clear yet. This is the subject of the
present investigation. Using isotope, electro-physiological and enzymological methods, the effect of γ-ionizing radiation
on cell membrane voltage-current characteristics, acetylcholine-induced membrane current, 22Na+ and 45Ca2+ exchange between cells and bathing solution, Na+K+-ATPase activity, dose-dependent ouabain binding with cell membrane, intracellular cAMP and membrane phosphorylation in snail
neurons were studied. The changes in neurons as a result of 30-min γ-radiation exposure of snails to 5.16 Ci/kg at the end
of the first 30 min of post-radiation period were as follows: the increase in membrane ionic conductance reversed the ouabain
sensitivity of acetylcholine-induced currents, stimulation of 22Na+ and 45Ca2+ uptakes, inhibition of Na/K pump, activation Na/Ca exchange in reversed mode, increase in ouabain binding with high-affinity
α3 and decrease with α2 middle-affinity receptors, decrease in intracellular cAMP content and membrane dephosphorylation. On the basis of the obtained
data, it is suggested that both α3 and α2 catalytic subunits of Na++K+-ATPase serve primary membrane sensors through the activation of which the biological effect of γ-radiation on neurons is
realized. The IR has activation effects on α3-dependent Na+/Ca2+ exchange in forward and its inactivation on α2-dependent reverse modes. 相似文献
368.
Bellmore JR Baxter CV Ray AM Denny L Tardy K Galloway E 《Environmental management》2012,49(3):734-750
Pre-restoration studies typically focus on physical habitat, rather than the food-base that supports aquatic species. However,
both food and habitat are necessary to support the species that habitat restoration is frequently aimed at recovering. Here
we evaluate if and how the productivity of the food-base that supports fish production is impaired in a dredge-mined floodplain
within the Yankee Fork Salmon River (YFSR), Idaho (USA); a site where past restoration has occurred and where more has been
proposed to help recover anadromous salmonids. Utilizing an ecosystem approach, we found that the dredged segment had comparable
terrestrial leaf and invertebrate inputs, aquatic primary producer biomass, and production of aquatic invertebrates relative
to five reference floodplains. Thus, the food-base in the dredged segment did not necessarily appear impaired. On the other
hand, we observed that off-channel aquatic habitats were frequently important to productivity in reference floodplains, and
the connection of these habitats in the dredged segment via previous restoration increased invertebrate productivity by 58%.
However, using a simple bioenergetic model, we estimated that the invertebrate food-base was at least 4× larger than present
demand for food by fish in dredged and reference segments. In the context of salmon recovery efforts, this observation questions
whether additional food-base productivity provided by further habitat restoration would be warranted in the YFSR. Together,
our findings highlight the importance of studies that assess the aquatic food-base, and emphasize the need for more robust
ecosystem models that evaluate factors potentially limiting fish populations that are the target of restoration. 相似文献
369.
Estimating the Cumulative Ecological Effect of Local Scale Landscape Changes in South Florida 总被引:1,自引:0,他引:1
Hogan DM Labiosa W Pearlstine L Hallac D Strong D Hearn P Bernknopf R 《Environmental management》2012,49(2):502-515
Ecosystem restoration in south Florida is a state and national priority centered on the Everglades wetlands. However, urban
development pressures affect the restoration potential and remaining habitat functions of the natural undeveloped areas. Land
use (LU) planning often focuses at the local level, but a better understanding of the cumulative effects of small projects
at the landscape level is needed to support ecosystem restoration and preservation. The South Florida Ecosystem Portfolio
Model (SFL EPM) is a regional LU planning tool developed to help stakeholders visualize LU scenario evaluation and improve
communication about regional effects of LU decisions. One component of the SFL EPM is ecological value (EV), which is evaluated
through modeled ecological criteria related to ecosystem services using metrics for (1) biodiversity potential, (2) threatened
and endangered species, (3) rare and unique habitats, (4) landscape pattern and fragmentation, (5) water quality buffer potential,
and (6) ecological restoration potential. In this article, we demonstrate the calculation of EV using two case studies: (1)
assessing altered EV in the Biscayne Gateway area by comparing 2004 LU to potential LU in 2025 and 2050, and (2) the cumulative
impact of adding limestone mines south of Miami. Our analyses spatially convey changing regional EV resulting from conversion
of local natural and agricultural areas to urban, industrial, or extractive use. Different simulated local LU scenarios may
result in different alterations in calculated regional EV. These case studies demonstrate methods that may facilitate evaluation
of potential future LU patterns and incorporate EV into decision making. 相似文献
370.
Santoro R Jucker T Prisco I Carboni M Battisti C Acosta AT 《Environmental management》2012,49(3):534-542
Sandy coastlines are sensitive ecosystems where human activities can have considerable negative impacts. In particular, trampling
by beach visitors is a disturbance that affects dune vegetation both at the species and community level. In this study we
assess the effects of the limitation of human trampling on dune vegetation in a coastal protected area of Central Italy. We
compare plant species diversity in two recently fenced sectors with that of an unfenced area (and therefore subject to human
trampling) using rarefaction curves and a diversity/dominance approach during a two year study period. Our results indicate
that limiting human trampling seems to be a key factor in driving changes in the plant diversity of dune systems. In 2007
the regression lines of species abundance as a function of rank showed steep slopes and high Y-intercept values in all sectors, indicating a comparable level of stress and dominance across the entire study site. On the
contrary, in 2009 the regression lines of the two fenced sectors clearly diverge from that of the open sector, showing less
steep slopes. This change in the slopes of the tendency lines, evidenced by the diversity/dominance diagrams and related to
an increase in species diversity, suggests the recovery of plant communities in the two fences between 2007 and 2009. In general,
plant communities subject to trampling tended to be poorer in species and less structured, since only dominant and tolerant
plant species persisted. Furthermore, limiting trampling appears to have produced positive changes in the dune vegetation
assemblage after a period of only two years. These results are encouraging for the management of coastal dune systems. They
highlight how a simple and cost-effective management strategy, based on passive recovery conservation measures (i.e., fence
building), can be a quick (1–2 years) and effective method for improving and safeguarding the diversity of dune plant communities. 相似文献