Fire and explosion risk assessment for large-scale oil export terminal

Now in Russian Federation and other countries large-scale oil terminals (volume of one tank exceeds 100 000 m³, total volume of tanks exceeds 300 000 m³) are designed and constructed. Therefore fire safety of such objects becomes a very important task, solution of which is hardly possible without detail fire risk assessment. This study is aimed to a solution of this problem. Potential, individual and social risks were calculated. The potential risk was defined as a frequency of occurrence of hazardous factors of fires and explosions in a given point of space (the so-called risk contours). The individual risk was defined as a frequency of injuring a given person by hazardous factors of fires and explosions. Time of presence of this person in hazardous zones (near the hazardous installation) is taken into account during calculations of the individual risk. Social risk was defined as a dependence of frequency of injuring a given number of people by hazardous factors of fires and explosions on this number. In practice the social risk is usually determined on injuring not less than 10 people.

The oil terminal under consideration includes the following main parts: crude oil storage consisting of three tanks of volume 100 000 m³ each, input crude oil pipeline of diameter 0.6 m, crude oil pumps, output crude oil pipeline of diameter 0.8 m, auxiliary buildings and facilities. The following main scenarios of tank fires have been considered: rim seal fire, pool fire on a surface of a floating roof, pool fire on a total cross-section surface of the tank, pool fire in a dyke, explosions in closed or semiclosed volumes. Fires and explosions in other parts of the terminal are also taken into account. Effects of escalation of accidents are considered.

Risk contours have been calculated both for the territory of the terminal and for the neighbouring space. The potential risk for the storage zone is near 10⁻⁴–10⁻⁵ year⁻¹, and at a distance 500 m from the terminal the potential risk values do not exceed 10⁻⁶ year⁻¹. The values of the individual risk for various categories of workers are in the range of 10⁻⁵–10⁻⁶ year⁻¹. Because of low number of the workers on the terminal and large distances to towns and villages the social risk value is negligible. These risk values are consistent with practice of the best oil companies, and fire hazard level of the terminal can be accepted as tolerable.     

“Vybuchovy trojuhelnik”: A software tool for evaluation of explosibility of coal mine atmosphere

Rescue operations during mine fires or methane explosions are highly dangerous for rescue workers. The knowledge of the composition of the coal mine atmosphere and the calculations of its explosibility may help to increase the safety of the rescuers. In the Czech Republic, a system called “Mine Gas Laboratory” (DPL) has been used for these purposes. The DPL allows measurement of the composition of the mine atmosphere and transmits the data necessary for evaluation to the surface. Up to now the explosibility evaluation of the coal mine atmosphere has depended either on the rescuers’ experience or on software code calculation. The code called “Vybuchovy trojuhelnik” (explosion triangle) is a graphical computing system intended for fast assessment of explosibility of fuel–air mixture. This article introduces the code and describes two simple methods of explosibility evaluation. The first method is “explosion triangle analysis”—a graphical method based on empirical graphs transformed into equations. The second method uses thermodynamic calculation based on chemical balance dynamics and Gibbs and Helmholtz energy. According to the requirements of the Czech Bureau of Mining (CBU) and Central Mine Rescue Service (HBZS), the code solves the problems of explosion triangle for both standard and non-standard coal mine atmosphere compositions. Unfortunately, the atmosphere composition must be introduced manually due to the unknown format of the data transmitted from the old DPL model. On 1 September 2005, a project started to develop a new system for on-line monitoring and atmosphere explosibility evaluation. The system should be able to measure CO₂, O₂, CH₄, H₂ and CO concentrations as well as the wind speed, temperature and humidity. The “Vybuchovy trojuhelnik” code will be used as a basis for explosibility evaluation, and an on-line connection with the new model of DPL will be established.     

EFFECTS OF SELECTED HERBICIDES ON BACTERIAL POPULATIONS IN NONTREATED AND TREATED WATER1

ABSTRACT: Bacterial populations in nontreated and herbicide-treated waters were subjected to three different herbicides. Diuron, dichlobenil, and diquat were added (100 mg/l) to water samples from two fresh water lakes and two herbicide-treated ponds. Total numbers of bacteria were monitored. Bacterial populations in fresh lake water decreased after herbicide additions; however, final populations were significantly greater than the controls. Similar observations were recorded for bacteria in dichlobenil- and diuron-treated waters. Selective enrichment is probably expressed in these experiments.     

A MULTIOBJECTIVE MODEL FOR REGIONAL WATER QUALITY MANAGEMENT1

ABSTRACT: Linear programming is the simplest of all the optimization techniques used in regional water quality management studies; but the technique can optimize only one goal. When there are multiple goals with the same or different priorities, goal programming is a useful decisionmaking tool. This paper illustrates the application of goal programming to a regional water quality management problem where the following two goals are considered: (1) minimize the total cost of waste treatment, and (2) maintain the water quality goals (dissolved oxygen) close to the minimum level stated in the stream standards.     

LEAST COST SOLUTIONS TO THE PROBLEM OF EFFLUENT ABATEMENT IN URBAN SYSTEMS1

ABSTRACT: There is a significant misallocation of resources in the construction and operation of municipal sewage treatment systems in North America. Central to this misallocation is the inadequate evaluation of alternative treatment technologies, alternative distributions of responsibility for waste treatment, and alternative mechanisms for inducing compliance with treatment system requirements. Perverse incentives in the current institutional structure limit the scope of alternatives examined by decisionmakers. Determination of the least cost solution to the problem of urban effluent abatement requires mathematical modeling for the delineation of optimal treatment strategies on a system wide basis. The adoption of modern methods of systems analysis can identify significant opportunities for the reduction of economic waste in the treatment of municipal sewage.     

THE APPLICATION OF HYDROLOGIC MODELS TO SMALL WATERSHEDS HAVING MILD TOPOGRAPHY1

ABSTRACT: The application of hydrologic models to small watersheds of mild topography is not well documented. This study evaluates the applicability of hydrologic models described by Huggins and the Soil Conservation Service to small watersheds by comparing the simulated and actual hydrograph for both gaged and ungaged situations. The annual maximum rainfall events plus storms exceeding 2.5 inches from 25 years of rainfall and runoff data for two small watersheds were selected for the model evaluations. These storms had a variety of patterns and occurred on many different watershed conditions. Simulated and actual hydrographs were compared using a parameter which contained volume, peak, and shape factors. One-half of the selected storms were used to calibrate the models. For both models, there were no significant differences between the simulated and actual runoff volumes and peak runoff rates. Parameters obtained during the calibration process and relationships developed to estimate antecedent moisture and to modify tabulated runoff curve numbers were used to simulate the runoff hydrograph from the remaining storms. These remaining storms or test storms were simulated only once in order to imitate an ungaged situation. In general, both the Huggins and SCS model performed similarly on the test storms, but the level of model performance was lower than that for the calibration storms. For both models, the two-day antecedent rainfall was more important than the five-day in determining antecedent moisture and modifying tabulated curve numbers. The time of concentration which resulted in good hydrograph simulations was about three times larger than that estimated using published empirical relationships.     

STORM WATER MANAGEMENT: THE CONCEPT AND ITS APPLICATION1

ABSTRACT: Storm water management is a concept being applied in many urban areas to deal with the increasing problems of storm runoff control and flood damage prevention. This paper introduces the concept and describes the recently completed storm water management program in Columbus, Georgia. Columbus has spent five years and over $200,000 in the development of their problem which includes several basic elements: soils inventory and analysis, hydrologic data collection, sediment and erosion control ordinance, storm water management handbook, urban flood simulation model, interdepartment coordination study, drainage problem categorization study, and a pilot basin study. The results of the pilot basin study are presented including example output from the urban simulation model. The computer output illustrates both the hydrologic-hydraulic and economic capabilities of the model.     

Cumulative silvicultural impacts on watersheds: A hydrologic and regulatory dilemma

Because of the nature of watersheds, the hydrologic and erosional impacts of logging and related road-building activities may move offsite, affecting areas downslope and downstream from the operation. The degree to which this occurs depends on the interaction of many variables, including soils, bedrock geology, vegetation, the timing and size of storm events, logging technology, and operator performance. In parts of northwestern California, these variables combine to produce significant water quality degradation, with resulting damage to anadromous fish habitat.Examination of recent aerial photographs, combined with a review of public records, shows that many timber harvest operations were concentrated in a single 83 km² watershed in the lower Klamath River Basin within the past decade. The resulting soil disturbance in this case seems likely to result in cumulative off-site water quality degradation in the lower portion of the Basin.In California, both state and federal laws require consideration of possible cumulative effects of multiple timber harvest operations. In spite of recent reforms that have given the state a larger role in regulating forest practices on private land, each timber harvest plan is still evaluated in isolation from other plans in the same watershed. A process of collaborative state-private watershed planning with increased input of geologic information offers the best long-term approach to the problem of assessing cumulative effects of multiple timber harvest operations. Such a reform could ultimately emerge from the ongoing water quality planning process under Section 208 of the amended Federal Water Pollution Control Act.