Dechlorane Plus as an emerging environmental pollutant in Asia: a review

Environmental Science and Pollution Research - Dechlorane Plus (DP) is an unregulated, highly chlorinated flame retardant. It has been manufactured from past 40 years but its presence in...     

Potential CO2 emission reduction for BF–BOF steelmaking based on optimised use of ferrous burden materials

Currently, the blast furnace (BF) to basic oxygen furnace (BOF) is the dominant steel production route in the steel industry. The direct CO₂ emission in this process system exceeds 1 t of CO₂/t of crude steel produced. Different ferrous burden materials, for instance iron ore and scrap, can be used in various proportions in this steelmaking route. This paper analyses how energy use, conversion costs, and CO₂ emissions can be influenced by the use of different ferrous burden materials when producing crude steel. An optimisation mixed integer linear programming (MILP) model has been applied for analysis. By the use of the optimisation model, it is possible to highlight some issues of special importance, such as best practices to increase production at low conversion cost, or best practices to increase production at low CO₂ emission. It is found out that more benefits will be gained when using the system-oriented analysis to the steelmaking process. Furthermore, a comprehensive view of the trade-offs between the objectives of Cost and CO₂ can provide useful information for decision makers to generate strategies under the future emission trading.     

Attenuation of dissolved metals in neutral mine drainage in the Zambian Copperbelt

Behaviour of metals like Cu and Co was studied in nearly neutral (pH ?? 6.4) mine drainage seepage in a stream downgradient of a tailing dam at Chambishi site in the Copperbelt of Zambia. They are attenuated by precipitation of ferruginous ochres that incorporate significant quantities of metals. Using chemical analysis, X-ray powder diffraction and M?ssbauer spectroscopy, we show that the ochres are composed mostly of amorphous ferric hydroxide. Close to the seepage face, the total Fe content of ochres increases due to precipitation of amorphous ferric hydroxide, but total Fe in sediment decreases further downstream. The stream then flows through wetland (dambo) where the remaining fraction of metals is removed. During rainy periods, increased flow rate may result in re-suspension of ochres, increasing thus the mobility of metals. Major ions like sulphate are conservative at the start of the dry period (May), but gypsum may probably precipitate later at the end of the dry period. Sequential extractions of bulk sediments indicate that Mn behaves differently to Fe, with a trend of increasing Mn with distance from the tailing dam. There is much more Fe than Mn in residual (Aqua Regia) fraction, indicating that amorphous ferric hydroxides are transformed to more crystalline phases deeper in sediment. Environmental impact of mine drainage is relatively limited due to its neutral character.     

Combination of two indication systems in pre-alpine lakes — diatom index and macrophyte index

Since the climax of eutrophication in the early 1980s mainly greater lakes have been investigated and monitored in terms of their nutrient charge. In the future there will still be a need to develop guidelines for monitoring the trophic status of smaller lakes. Four small lakes were investigated by the author in the years 1996 and 1997. In order to define the nutrient charge of those lakes more precisely, special emphasis has been put upon the two criteria diatoms and macrophytes. Eventually an evaluation of the lakes' catchment areas will also be an important component of these studies. Benthic diatoms are the main part of periphyton. As unicellular fast reproducing organisms they are excellent indicators for trophic situations in lakes. The diatom index denotes the trophic status of the littoral zone during the last few weeks before sampling. The macrophytes, however, reflect the nutrient charge over a longer period, i.e. several years. The macrophyte index is based on the fact that some species are most prevalent at certain nutrient loads. The effort to combine these two indication systems carries a high resolution of spatial nutrient changes as well as in temporally changes.     

Deposition monitoring networks: what monitoring is required to give reasonable estimates of ammonia/ammonium?

Deposition is one of the main loss terms for ammonia and ammonium from the atmosphere. It is also the input for ecosystems that can lead to drastic changes and effects. Deposition networks are needed to evaluate the need and the effect of policies to reduce nitrogen emissions, but also for studying deposition parameters and for developing deposition models. As with ambient concentrations of ammonia, deposition, especially dry deposition, varies strongly in space and in time. Furthermore, the bi-directional surface-atmosphere exchange of ammonia makes the combination of ambient concentration measurements with inferential models inadequate. Developing deposition monitoring networks with reasonable accuracy and representativeness is therefore not straightforward. In Europe several projects have addressed deposition monitoring. From these results it is concluded that a monitoring strategy should consist of a network with a limited amount of super sites combined with a larger number of sites where low cost methods are applied, together with models for generalisation.     

Changes in cadmium mobility during composting and after soil application

The effect of twelve weeks of composting on the mobility and bioavailability of cadmium in six composts containing sewage sludge, wood chips and grass was studied, along with the cadmium immobilization capacity of compost. Two different soils were used and Cd accumulation measured in above-ground oat biomass (Avena sativa L.). Increasing pH appears to be an important cause of the observed decreases in available cadmium through the composting process. A pot experiment was performed with two different amounts of compost (9.6 and 28.8 g per kg of soil) added into Fluvisol with total Cd 0.255 mg kg^?1, and contaminated Cambisol with total Cd 6.16 mg kg^?1. Decrease of extractable Cd (0.01 mol l^?1 CaCl₂) was found in both soils after compost application. The higher amount of compost immobilized an exchangeable portion of Cd (0.11 mol l^?1 CH₃COOH extractable) in contaminated Cambisol unlike in light Fluvisol. The addition of a low amount of compost decreased the content of Cd in associated above-ground oat biomass grown in both soils, while a high amount of compost decreased the Cd content in oats only in the Cambisol.     

Land cover dynamics in the Simien Mountains (Ethiopia), half a century after establishment of the National Park

Regional Environmental Change - The Simien Mountains house several endangered and endemic wildlife species and provide important ecosystem services. Despite its regional environmental importance,...     

Participatory ergonomics and an evaluation of a low-cost improvement effect on cleaners' working posture.

Cleaning is a highly physically demanding job with a high frequency of awkward postures and working environments as contributing risk factors. Participatory ergonomics is a method in which end-users take an active role in identifying risk factors and solutions. The aim of this study was to apply the participatory ergonomics method to identify cleaning problems and to evaluate the effect of a low-cost improvement on cleaners' working postures in an office environment. The results show that the cleaning problem was identified, and the low-cost ergonomics solution suggested by the cleaners was implemented. Thus an improved working environment reduced the number of awkward cleaning postures and the Ovako Working Posture Analysis System (OWAS) action category for floor mopping decreased. It can be concluded that working in an improved environment can lead to better working postures which, in turn, leads to the cleaners' better health and better cleaning results.