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991.
Thacker NP Nitnaware VC Das SK Devotta S 《Environmental science and pollution research international》2007,14(4):225-226
Samples of effluents, sludge, pulp, final products (paper) and soil were collected from the identified pulp and paper mills
in India. The samples were analysed for 2,3,7,8-tetrachloro-dibenzo-p-dioxin (2,3,7,8-TCDD) and other dioxin congeners and
precursors. Pulp and paper mills using chlorine for the bleaching process showed the presence of 2,3,7,8-TCDD in effluent
samples. In the effluent and pulp samples from mills where chlorine dioxide was used as a bleaching agent, the 2,3,7,8-TCDD
congener ranged from below the detection limit 0.05 to 0.12 ngL−1/ngg−1. The relative standard deviation of reproducibility and the percent recovery of 2,3,7,8-TCDD were 2.07 and 82.4% in pulp
and 2.8 and 92% in effluent, respectively. The 1,3,6,8-TCDD was the only other major dioxin congener found in the treated
and untreated effluent and sludge samples. However, dichlorobenzene, trichlorophenyl, and hexachlorobiphenyl were detected
in all samples. The formation of dioxins can be minimised by replacing chlorine with chlorine dioxide in bleaching processes
in pulp and paper mills. 相似文献
992.
Chuaybamroong P Cayse K Wu CY Lundgren DA 《Environmental monitoring and assessment》2007,128(1-3):421-430
Ambient aerosols were collected during 2000–2001 in Gainesville, Florida, using a micro-orifice uniform deposit impactor (MOUDI)
to study mass size distribution and carbon composition. A bimodal mass distribution was found in every sample with major peaks
for aerosols ranging from 0.32 to 0.56 μm, and 3.2 to 5.6 μm in diameter. The two distributions represent the fine mode (<2.5 μm)
and the coarse mode (>2.5 μm) of particle size. Averaged over all sites and seasons, coarse particles consisted of 15% carbon
while fine particles consisted of 22% carbon. Considerable variation was noted between winter and summer seasons. Smoke from
fireplaces in winter appeared to be an important factor for the carbon, especially the elemental carbon contribution. In summer,
organic carbon was more abundant. The maximum secondary organic carbon was also found in this season (7.0 μg m−3), and the concentration is between those observed in urban areas (15–20 μg m−3) and in rural areas (4–5 μg m−3). However, unlike in large cities where photochemical activity of anthropogenic emissions are determinants of carbon composition,
biogenic sources were likely the key factor in Gainesville. Other critical factors that affect the distribution, shape and
concentration were precipitation, brushfire and wind. 相似文献
993.
One hundred forty seven samples of bovine milk were collected from 14 districts of Haryana, India during December 1998–February
1999 and analysed for the presence of organochlorine pesticide (OCPs) residues. ∑HCH, ∑DDT, ∑endosulfan and aldrin were detected
in 100%, 97%, 43% and 12% samples and with mean values of 0.0292, 0.0367, 0.0022 and 0.0036 μg/ml, respectively. Eight percent
samples exceeded the maximum residue limit (MRL) of 0.10 mg/kg as recommended by WHO for ∑HCH, 4% samples of 0.05 mg/kg for
α-HCH, 5% samples of 0.01 mg/kg for γ-HCH, 26% samples of 0.02 mg/kg for β-HCH as recommended by PFAA and 24% samples of 0.05 mg/kg
as recommended by FAO for ∑DDT. Concentrations of β-HCH and p,p′-DDE were more as compared to other isomers and metabolites
of HCH and DDT. 相似文献
994.
Almeida CA Quintar S González P Mallea MA 《Environmental monitoring and assessment》2007,133(1-3):459-465
A study of the water quality of the Potrero de los Funes River (San Luis – Argentina) was carried out in order to evaluate
the possible effect of the anthropogenic activities on the river developed in the homonymous town. Samples were collected
during the period March 2000–November 2005 at three selected sampling sites (RP1, RP2 and RP3). Different physicochemical and bacteriological parameters (turbidity, pH, conductivity, suspended solids, alkalinity, potassium,
sodium, calcium, magnesium, chlorides, nitrates, phosphates, sulphates, chemical oxygen demand (COD), 5-day biological oxygen
demand (BOD5), dissolved oxygen, total coliforms, Escherichia coli and total heterotrophic bacteria) were analysed according to the Standard Method for the Examination of Water and Wastewater.
When comparing the values of total coliforms, E. coli, total heterotrophic bacteria, COD, BOD5 and phosphates from the zone without anthropogenic influence (RP1) and the urban zones (RP2 and RP3) an important variation in the parameters was observed. These results indicate that the urban activity produces a serious
and negative effect on the water quality, thus constituting a sanitary risk and may have a major impact on the trophic status
of the Potrero de los Funes dam. As case study, we report on the use of General Quality Index (GQI) to evaluate spatial and
seasonal changes in the water quality of Potrero de los Funes River. Results revealed a significant degradation of the water
quality at RP2 and RP3. 相似文献
995.
Current demand analysis methods do not formally cover the case of chronic deficits in quantity or quality of water and sanitation
services. These services include drinking water supply (DWS), wastewater and sewage treatment (WST), and municipal solid waste
management (MSW). Formal analysis of this case would, at minimum, define the deficit state and evaluate appropriate options
for reducing it. This paper proposes for a formal analytical model for municipal sanitation systems (MSS) that operate with
deficits in at least one of the constituent services of DWS, WST, or MSW. The model introduces definitions and notation for
describing the deficit state for conducting demand analysis on municipal sanitation systems. This model of demand analysis
for systems with chronic deficits will hereinafter be referred to as deficit analysis. A case study for Bacoor, Philippines is presented as an example. 相似文献
996.
Relation of waste generation and composition to socio-economic factors: a case study 总被引:3,自引:0,他引:3
Bandara NJ Hettiaratchi JP Wirasinghe SC Pilapiiya S 《Environmental monitoring and assessment》2007,135(1-3):31-39
To develop an effective waste management strategy for a given region, it is important to know the amount of waste generated
and the composition of the waste stream. Past research has shown that the amount of waste generated is proportional to the
population and the average mean living standards or the average income of the people. In addition, other factors may affect
the amount and composition of waste. These are climate, living habits, level of education, religious and cultural beliefs,
and social and public attitudes. This paper presents the findings of a study carried out in a suburban municipal area in Sri
Lanka to determine the solid waste generation rate and waste composition based on field surveys and to determine the related
socio-economic factors. A database was developed that included information on the quantity and composition of waste generated
in a sample of households in the study area over a time period. The collected data was analysed to relate waste generation
and composition data to various socio-economic factors. Over 400 sample households were selected for the study using a stratified
random sampling methodology based on municipal wards and property values. A technique that considers both the number of households
in a particular income group (property value range) and the standard deviation of property values within a given income group
was used to determine the appropriate sample size for each municipal ward. Through category and regression analyses, the quantities
of waste and waste composition were related to several socio-economic factors. The paper describes the basis for the sample
selection, the methodology adopted for data collection, the socio-economic parameters used for the analysis, and the relationships
developed from the analysis. 相似文献
997.
The potential for airborne emissions to undergo long-range transport or to be removed from the atmosphere is influenced by their physical-chemical properties. When perfluorooctanate (PFO) enters the environment, its physical-chemical properties can vary significantly, depending on whether it exists as an acid, a salt, or a dissociated ion. A summary of the physical-chemical properties of the three most likely environmental states: ammonium perfluorooctanoate (APFO), perfluorooctanoic acid (PFOA) and the dissociated perfluorooctanoate anion (PFO(-)) is presented to illustrate the distinct environmental properties of each. The most volatile species, PFOA, is shown to have a pH-dependent air-water partitioning coefficient (K(aw)). The variability of K(aw) with pH influences the potential for vapor formation from aqueous environments, including rain events. Using the pH-dependent K(aw) and measured rain and air concentrations, it is shown that vapor-phase PFOA is not likely to be present above measurable levels of 0.2 ng m(-3) (12 parts per quadrillion v/v) during a rain event. Because rain concentrations determined in this work are comparable to measurements in other parts of North America, it is unlikely that rain events are a significant source of vapor-phase PFOA for the general North American region. It is shown that PFOA exists primarily in the particle phase in ambient air near direct sources of emissions and is efficiently scavenged by rain droplets, making wet deposition an important removal mechanism for emissions originating as either PFOA or APFO. Washout ratios of particle-associated PFO were determined to range between 1 x 10(5) and 5 x 10(5), in the same range as other semi-volatile compounds for which wet deposition is an important mechanism for atmospheric removal and deposition onto soils and water bodies. 相似文献
998.
The use of underwater gaseous sensors has increased rapidly in the last 10 years. The majority of such sensors employ a thin membrane through which the gas diffuses. These sensors are potentiometric gas-sensing probes and essentially they are ion-selective electrodes. The deployment time of these membranes is curtailed by the formation of biofouling on the membrane leading to erroneous results. The physical properties of a variety of commonly used membranes were investigated using SEM and AFM. This showed that there were differences in topography between the PTFE membranes, such as pore sizes and surface roughness, which may be attributed to the manner in which they are manufactured. The pore size of the PTFE membranes varied greatly, ranging from circular pores with a diameter of 500 nm to elongated pores measuring 1 x 22 microm. The contact angle of each membrane showed that they were all hydrophobic. The amount of fouling on each was also observed and its affect on oxygen diffusion was monitored. Fouling slowed down the response of the instrument and caused reduced diffusion through the membranes. The amount of fouling varied between the membranes with the YSI membrane fouling least. Some of the membranes tested did foul less than others and there could be lifetime advantages of choosing a membrane with a smoother surface and a small pore size. 相似文献
999.
Wen-Cheng Liu Jan-Tai Kuo Chih-Chieh Young Ming-Ching Wu 《Environmental Modeling and Assessment》2007,12(3):201-211
Numerical models are often used to evaluate the potential impact of human alternation of natural water bodies and to help
the design of the alternation to mitigate its impacts. In the past decade, three-dimensional hydrodynamic and reactive transport
modeling has matured from a research subject to a practical analysis technology. This paper presents a practical study in
which a three-dimensional hydrodynamic and water quality model [hydrodynamic eutrophication model (HEM-3D)] was applied to
determine the optimal location for treated wastewater discharged from marine outfall system in the Keelung harbor and the
adjacent coastal sea. First, model validation was conducted with respect to surface elevation, current, and water quality
variables measured in the Keelung harbor station and its coastal sea. The overall performance of the model was in qualitative
agreement with the available field data. The model was then used to evaluate several scenarios of the locations from marine
outfall system. Based on model simulation results, a location at the northeast of Ho-Ping Island was recommended for adoption
because the environmental impact is smaller than any other alternative.
相似文献
Wen-Cheng LiuEmail: |
1000.
Organic pollutants in compost and digestate. Part 1. Polychlorinated biphenyls, polycyclic aromatic hydrocarbons and molecular markers 总被引:1,自引:0,他引:1
Brändli RC Bucheli TD Kupper T Furrer R Stahel WA Stadelmann FX Tarradellas J 《Journal of environmental monitoring : JEM》2007,9(5):456-464
In Europe, 9.3 x 10(6) t(dry weight (dw)) of compost and digestate are produced per year. Most of this is applied to agricultural land, which can lead to considerable inputs of organic pollutants, such as polychlorinated biphenyls (PCB) and polycyclic aromatic hydrocarbons (PAH) to soil. This paper presents an inventory of the pollutant situation in source-separated composts, digestates and presswater in Switzerland by a detailed analysis of over 70 samples. PCB concentrations ( summation PCB 28, 52, 101, 118, 138, 153, 180) were significantly higher in urban (median: 30 microg kg(-1)dw, n = 52) than in rural samples (median: 14 microg kg(-1)dw, n = 16). Together with low concentrations in general, this points to aerial deposition on compost input material as the major contamination pathway. Enantiomeric fractions of atropisometric PCB were close to racemic. Median PAH concentration was 3010 microg kg(-1)dw( summation 15PAH, n = 69), and one quarter of the samples exhibited concentrations above the relevant Swiss guide value for compost (4000 microg kg(-1)dw). The levels were influenced by the treatment process (digestate > compost), the season of input material collection (spring-summer > winter > autumn), the particle size (coarse-grained > fine-grained), and maturity (mature > less mature). The main source of PAH in compost was pyrogenic, probably influenced mainly by liquid fossil fuel combustion and some asphalt abrasion, as suggested by multiple linear regression. This study, together with a companion paper reporting on other organic contaminates including emerging compound classes, provides a starting point for a better risk-benefit estimation of the application of compost and digestate to agricultural soil in Switzerland. 相似文献