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281.
交联菌丝体吸附剂的制备及其对Cr^3+的吸附特性 总被引:1,自引:0,他引:1
深入研究了交联菌丝体吸附剂的制备工艺及其对Cr^3+的吸附特性。交联菌丝体吸附剂制备工艺简单,但在制备过程中,活化剂NaOH和交联剂的用量对吸附特性影响较大。与纯菌丝体吸附剂相比,交联菌丝体吸附剂表观吸附容量提高48%,达到49.83mg/g(pH=2.53,水溶液中的Cr^3+浓度为600mg/L),同时其机械强度明显增强。交联菌丝体吸附剂对Cr^3+的吸附特点是将沉淀法与吸附法相结合,将沉淀与吸附两过程合二为一,从而简化了处理工艺,降低了处理成本。 相似文献
282.
Electrokinetic remediation of a Cu-Zn contaminated red soil by controlling the voltage and conditioning catholyte pH 总被引:5,自引:0,他引:5
Electrokinetics is an innovative technique for treating heavy metals contaminated soil, especially low pH soils such as the Chinese red soil (Udic Ferrisols). In this paper, a Cu-Zn contaminated red soil is treated by electrokinetics. When the Cu-Zn contaminated red soil was treated without control of catholyte pH during the electrokinetic treatment, the soil pH in the soil sections near cathode after the experiment was high above 6, which resulted in accumulation of large amounts of Cu and Zn in the soil sections with such high pH values. Compared to soil Cu, soil Zn was more efficiently removed from the soil by a controlled electrokinetic method. Application of lactic acid as catholyte pH conditioning solution caused an efficient removal of Cu and Zn from the soil. Increasing the electrolyte strength (salt concentration) of the conditioning solution further increased Cu removal, but did not cause a significant improvement for soil Zn. Soil Cu and Zn fractions after the electrokinetic treatments were analyzed using sequential extraction method, which indicated that Cu and Zn precipitation in the soil section closest to the cathode in the treatments without catholyte pH control limited their removal from the soil column. When the catholyte pH was controlled by lactic acid and CaCl(2), the soil Cu and Zn removal percentage after 554 h running reached 63% and 65%, respectively. Moreover, both the residual soil Cu and Zn concentrations were lower than 100 mg kg(-1), which is adequate and meets the requirement of the Chinese soil environmental quality standards. 相似文献
283.
284.
多级雾化超重力旋转床是一种新型的强化传质设备 ,适合于大流量的废气处理。本文选择NaOH Ca(OH) 2双碱法烟气脱硫工艺进行了实验研究 ,考察了再生液的PH0 值、液气比及气体中的SO2 初始浓度等对脱硫率的影响 相似文献
285.
286.
Min Sun Risheng Yao Yahua You Shengsong Deng Wenxia Gao 《Frontiers of Environmental Science & Engineering》2007,1(1):95-98
This paper reports on the degradation of 4-aminophenol using hydrogen peroxide as oxidizer and the enzyme from Serratia marcescens AB 90027 as catalyst. The effecting factors during degradation and the degrading mechanism were studied. Also, the location of the enzyme in the cell, which could catalyze the degradation of 4-aminophenol, was analyzed. The results showed that to degrade 50 mL of 4-aminophenol whose concentration was 500 mg/L, the optimal conditions were: volume of H2O2 = 3 mL, temperature = 40–60°C and pH = 9–10. In the degradation process, 4-aminophenol was first converted to benzoquinone and NH3, then organic acids including maleic acid, fumaleic acid, and oxalic acid were formed, and then finally CO2 and H2O were generated as final products. The enzyme that could catalyze the degradation of 4-aminophenol was mainly extracellular enzyme. 相似文献
287.
The fractional dispersion model for natural rivers, extended by including a first order reaction term, contains four parameters. In order to estimate these parameters a fractional Laplace transform-based method is developed in this paper. Based on 76 dye test data measured in natural streams, the new parameter estimation method shows that the fractional dispersion operator parameter F is the controlling parameter causing the non-Fickian dispersion and F does not take on an integer constant of 2 but instead varies in the range of 1.4–2.0. The adequacy of the fractional Laplace transform-based parameter estimation method is determined by computing dispersion characteristics of the extended fractional dispersion model and these characteristics are compared with those observed from 12 dye tests conducted on the US rivers, including Mississippi, Red, and Monocacy. The agreement between computed and observed dispersion characteristics is found to be good. When combined with the fractional Laplace transform-based parameter estimation method, the extended fractional dispersion model is capable of accurately simulating the non-Fickian dispersion process in natural streams. 相似文献
288.
289.
The characteristics of vertical and horizontal variations of lead element (Pb) in soil-plant system of vertical zone in Changbai Mountain National Nature Reserve(CNNR)were studied.The results showed that Pb concentrations in soils of vertical zone are all above 25mg/kg,and the average Pb concentration of each soil zone negatively correlates its degree of variation,i.e.brown coniferous forest soil zone has the lowest average Pb concentration of four soil zones,and the highest horizontal variation;however,mountain soddy forest soil has the highest average Pb concentration,and the lowest horizontal variation;the average concentration of plant Pb of each plant zone is lower than the worldwide average level of Pb in plant(Clarke),respectively,and plant Pb content order is consistent with soil Pb content order,but their horizontal variations are different from those in soil zones,the variation of mountain tundra forest zone is highest,but Betula ermanii forest zoner the lowest.Vertical variation of plant Pb is obviously higher than that in soils with variation coefficient of 89.76%;the enrichment capability of plant for Pb is depended on the plant types and the different organs of plant;parent material and parent rock,pH values,soil organic matter and soil particle fraction etc.are the main factors influencing variations of Pb contant in soil-plant system of vertical zone in CNNR. 相似文献
290.
Xu Zhengyong Yang Zhaohui Zeng Guangming Xiao Yong Deng Jiuhua 《Frontiers of Environmental Science & Engineering in China》2007,1(1):43-48
The nitrogen removal mechanism was studied and analyzed when treating the ammonium-rich landfill leachate by a set of sequencing
batch biofilm reactors (SBBRs), which was designed independently. At the liquid temperature of (32 ± 0.4)°C, and after a 58-days
domestication period and a 33-days stabilization period, the efficiency of ammonium removal in the SBBR went up to 95%. Highly
frequent intermittent aeration suppressed the activity of nitratebacteria, and also eliminated the influence on the activity
of anaerobic ammonium oxidation (ANAMMOX) bacteria and nitritebacteria. This influence was caused by the accumulation of nitrous
acid and the undulation of pH. During the aeration stage, the concentration of dissolved oxygen was controlled at 1.2–1.4
mg/L. The nitritebacteria became dominant and nitrite accumulated gradually. During the anoxic stage, along with the concentration
debasement of the dissolved oxygen, ANAMMOX bacteria became dominant; then, the nitrite that was accumulated in the aeration
stage was wiped off with ammonium simultaneously.
Translated from Acta Scientiae Circumstantiae, 2006, 26(1): 55–60 [译自: 环境科学学报] 相似文献