水-岩作用下砂岩微细观结构变化特性及机理研究

为了较好地分析水-岩作用下库岸边坡消落带岩体的劣化机理,设计进行了考虑库水压力升降变化和浸泡-风干循环的水-岩作用试验。研究结果表明:(1)在水-岩作用过程中,砂岩的单轴抗压强度劣化趋势明显,其中前6期抗压强度劣化趋势较为显著,6次水-岩作用之后,岩样的强度劣化趋势逐渐趋于缓慢。(2)随着水-岩作用周期的增加,岩石内部孔隙、裂隙逐渐发育、汇集,矿物颗粒逐渐软化、分解,使得岩石微观结构逐渐趋于松散。(3)水-岩作用下砂岩劣化的进程中,首先是岩样中胶结物的溶解、溶蚀,然后是失去胶结物包裹的矿物颗粒表面发生水-岩物理化学作用,最后是矿物颗粒本身软化、分解。(4)水-岩作用过程中,岩样内部胶结物的溶解、溶蚀对水-岩作用前期的宏观力学性质影响明显,岩石矿物颗粒本身的软化、分解对水-岩作用后期的力学性质影响明显。相关研究成果可为库岸边坡消落带水-岩作用机理分析提供较好的参考。     

Ozonation of the 5-fluorouracil anticancer drug and its prodrug capecitabine: Reaction kinetics,oxidation mechanisms,and residual toxicity

Specific second-order rate constants were determined for 5-FU and CAP with ozone. Reaction sites were confirmed by kinetics, Fukui analysis, and products. The olefin moiety was the main ozone reaction site for 5-FU and CAP. Carboxylic acids comprised most of the residual TOC for 5-FU. Ozonation removed the toxicity associated with 5-FU and products but not CAP. Anticancer drugs (ADs) have been detected in the environment and represent a risk to aquatic organisms, necessitating AD removal in drinking water and wastewater treatment. In this study, ozonation of the most commonly used antimetabolite ADs, namely 5-fluorouracil (5-FU) and its prodrug capecitabine (CAP), was investigated to determine reaction kinetics, oxidation mechanisms, and residual toxicity. The specific second-order rate constants between aqueous ozone and 5-FU, 5-FU⁻, 5-FU²⁻, CAP, and CAP⁻ were determined to be 7.07(±0.11)×10⁴ M⁻¹·s⁻¹, 1.36(±0.06)×10⁶ M⁻¹·s⁻¹, 2.62(±0.17)×10⁷ M⁻¹·s⁻¹, 9.69(±0.08)×10³ M⁻¹·s⁻¹, and 4.28(±0.07)×10⁵ M⁻¹·s⁻¹, respectively; furthermore, the second-order rate constants for ^•OH reaction with 5-FU and CAP at pH 7 were determined to be 1.85(±0.20)×10⁹ M⁻¹·s⁻¹ and 9.95(±0.26)×10⁹ M⁻¹·s⁻¹, respectively. Density functional theory was used to predict the main ozone reaction sites of 5-FU (olefin) and CAP (olefin and deprotonated secondary amine), and these mechanisms were supported by the identified transformation products. Carboxylic acids constituted a majority of the residual organic matter for 5-FU ozonation; however, carboxylic acids and aldehydes were important components of the residual organic matter generated by CAP. Ozone removed the toxicity of 5-FU to Vibrio fischeri, but the residual toxicity of ozonated CAP solutions exhibited an initial increase before subsequent removal. Ultimately, these results suggest that ozone is a suitable technology for treatment of 5-FU and CAP, although the residual toxicity of transformation products must be carefully considered.     

甘蔗叶活性炭的制备

以H3PO4为活化剂制备甘蔗叶活性炭,采用正交实验对活性炭的制备工艺进行了优化,并研究了活性炭对含铬废水的吸附和再生性能.实验结果表明:在H3PO4体积分数为15％、H2SO4体积分数为6％、HC1体积分数为3％、活化温度为723 K、活化时间为0.58 h的工艺条件下,活性炭得率为35.07％,碘吸附值为1 207 mg/g.活性炭对Cr(Ⅵ)的最大平衡吸附量为30.89 mg/g,HNO3再生后对Cr(Ⅵ)的最大平衡吸附量为39.48 mg/g;再生效率最高达87.41％,经3次再生,活性炭的再生效率仍能维持在80％以上.     

Water pollution and degradation in Pearl River Delta,South China

The Pearl River Delta Economic Zone is the most dynamic economic area in South China. One of the major problems in the region is the sustainable utilization of the water resources. On the basis of analysis of the water environment status and pollution sources, it is suggested that domestic sewage is the primary cause of pollution. Two new concepts "degradation coefficient" and "degradation volume" of water resources, due to pollution, which may be used to assess macroscopically the carrying capacity of the water resources and sustainability of the water environment, are proposed by the authors. The results calculated indicate that the volumes of degraded water resources will be up to 204, 352, and 537 million m3 in 2002, 2010, and 2020. It is suggested that water for daily consumption and domestic sewage must be controlled more effectively and there should be cross-regional coordination in tackling problems of water environment.     

生态条件对离体瘤胃菌丛数量和菌群的影响

本文通过在模拟瘤胃发酵装置内进行动物体外瘤胃菌丛发酵生态条件动态变化对细菌数量和菌群的影响研究，发现温度４０℃、每小时搅动２０分钟是９０５２３－１瘤胃菌丛的最佳生长条件。瘤胃球菌随Ｃ／Ｎ的减小而增加，而Ｃ／Ｎ高的条件下更有利于弧菌的生长。     

不同生境下瘤胃菌丛菌体密度与VFA的关系

在温度，搅动强度和Ｃ／Ｎ经３个生态因素发生梯度变化的情况下，本文在人工瘤胃装置内对瘤胃菌从９５０２３－１进行了连续发酵试验，逐日测定瘤肋细菌数量和ＶＦＡ产量的变化，对两者之间的关系进行了相关和回归分析。     

龙口褐煤对废水中Cr（Ⅵ）的吸附与还原

进行了以龙口褐煤作吸附剂，还原剂净化铬废水的实验，研究了含铬废水ＰＨ、浓度对褐煤吸附，还原Ｃｒ（Ⅵ）效果的影响，确定了龙口褐煤净化含废水的最佳条件。     

胭脂鱼仔幼鱼的摄食习性及其生长

胭脂鱼幼鱼具有明显的昼夜摄食节律.仔鱼以适口的浮游动物为食,并随着口位下移,转而摄食底层生物.文中分别对140日幼鱼的日龄与全长、全长与体重以及全长和全长/体高的关系作了曲线回归方程,反映了幼鱼的生长特点.本工作为增殖该种珍稀鱼类资源提供了基础资料,并对其观赏价值进行了评价.     

中国传统的天人关系理论与可持续发展的伦理学基础

本文认为,中国古代的天人关系论能够为可持续发展提供一种必要的伦理学基础,并在中国传统哲学“天人合一”观念的基础上提出了自然的价值、人在世界中的地位、人对自然的权利和义务的理论观点,这对可持续发展的伦理建设具有重大的理论和实践意义。     

高纯二氧化锆生产过程中污染的防治

对高纯二氧化锆的生产工艺进行了改革,采用了新型反应器及胶凝除硅,直接酸溶重结晶,直接煅烧等技术,降低了原材料消耗及能耗,减少了废液排放量,并将回收的废物加工成副产品白炭黑,实现了在生产过程中防治污染。