Dissipation of oxytetracycline, chlortetracycline, tetracycline and doxycycline using HPLC-UV and LC/MS/MS under aquatic semi-field microcosm conditions

A mixture of four tetracyclines; oxytetracycline (OTC), chlortetracycline (CTC), tetracycline (TC), and doxycycline (DC) was applied in fifteen 12000l outdoor microcosms at four treatment levels plus controls each with three replicates (n = 3). The dissipation times of parent compounds were monitored and half-lives (DT50) of 1-4 days, depending on treatment level were recorded. This is in accordance with half-lives from previous findings in bench-top experiments. Parent compound DT50, were determined using HPLC-UV. Furthermore, the samples were analyzed for ten different tetracycline products using LC/MS/MS. Two products were found for chlortetracycline; 4-epi-anh-chlortetracyline and the iso-chlortetracycline. Iso-forms were only found for CTC and only at the highest treatment (300 microg l(-1)). The half-lives, trajectories, and relative amounts of the products were analogous for all four tetracyclines. DT50 for products were less than 1.2 days. Formation of 4-epi-anh-tetracyclines, occurred at neutral to weak alkaline conditions.     

Precipitation of aragonite by calcitic bivalves in Mg-enriched marine waters

To understand the relative importance of biological versus physicochemical control over biomineralization, we have tested if the chemical composition of the medium (i.e., the Mg/Ca ratio) can change the mineralogy of mollusk shells. The shells of mollusks are made of calcite and/or aragonite, which are by far the most common CaCO₃ polymorphs. Several species of bivalves with predominantly calcitic shells have been cultivated in artificial seawater with a Mg/Ca molar ratio within the range of 8.3–9.2, well above the present value for seawater (5.2). Four out of six species used (the scallop Chlamys varia, the oyster Ostrea edulis, the saddle oyster Anomia ephippium and the mussel Mytilus edulis) survived long enough to secrete significant amounts of calcium carbonate. The deposits (sometimes extensive) formed on the interior shell surfaces were predominantly aragonitic. Three individuals of C. varia also increased their length by adding new shell at the margin. Contrary to the internal shell deposits, these margins were high-Mg calcite. This implies that the marginal mantle is able to exert a more strict control on the secreted mineral phase than the mantle facing the internal shell surface. This is the first report on an in vivo experimentally forced switch in bivalve shell mineralogy, from calcite to aragonite due to a change in water chemistry.     

Zyklisierung von Äthoxymethylenmalonester mit 1,8-Diaminonaphthalin zum Perimidin

The Science of Nature -     

活性炭纤维（ACF）电极法处理染料废水的探讨

根据Ａｄｖａｎｃｅｄ Ｃｈｅｍｉｃａｌ Ｏｘｉｄａｔｉｏｎ＾［１］［６］的原理，通过ＡＣＦ电极的引入，使得电化学处理成为一个自由基反应与絮凝反应相结合的过程，对于多种模拟印染废水可以具有良好的处理效果。通过与其他方法的对比实验，表明在色度去除率方面不比Ｆｅｎｔｏｎ试剂法逊色，并明显优于絮凝法。经过单级处理，对于实验范围内的还原染料、酸性染料、活性染料及硫化染料，其脱色率全部大于９０％，大多数为９８     

Environmental degradation and political constraints in ethiopia

The article begins by outlining the extent and origins of environmental degradation in northern Ethiopia. Soil conservation and related environmental rehabilitation measures adopted by the Ministry of Agriculture, with donor assistance, are outlined and shown to be inadequate to reverse the trend of environmental degradation. Their scope and financing are too limited, there are too few immediate production returns for the peasants, and the conventional 'top-down' implementation of the measures means that peasants participate in rehabilitation programmes as paid workers (food-for-work) rather than as responsible landowners. The post-revolutionary government has continued the centralising and state-building policies of its predecessors, substituting the state for feudal lords as the appropriator of peasant production and labour. The wars in Eritrea and Tigray consume the lion's share of the state's resources and development programmes have become increasingly extractive (procurement of grain at low prices, labour campaigns, etc.) and penetrative (relocation of population, collectivisation of agriculture, etc). The problem of land degradation is ultimately a political one: how to find a political formula within which efficient development administration can be combined with power sharing and cultural pluralism.     

Sustainable Remediation Considerations for Treatment of 1,4‐Dioxane in Groundwater

1,4‐Dioxane remediation is challenging due to its physiochemical properties and low target treatment levels. As such, applications of traditional remediation technologies have proven ineffective. There are a number of promising remediation technologies that could potentially be scaled for successful application to groundwater restoration. Sustainable remediation is an important consideration in the evaluation of remediation technologies. It is critically important to consider sustainability when new technologies are being applied or new contaminants are being treated with traditional technologies. There are a number of social, economic, and environmental drivers that should be considered when implementing 1,4‐dioxane treatment technologies. This includes evaluating sustainability externalities by considering the cradle‐to‐grave impacts of the chemicals, energy, processes, transportation, and materials used in groundwater treatment. It is not possible to rate technologies as more or less sustainable because each application is context specific. However, by including sustainability thinking into technology evaluations and implementation plans, decisions makers can be more informed and the results of remediation are likely to be more effective and beneficial. There are a number sustainable remediation frameworks, guidance documents, footprint assessment tools, life cycle assessment tools, and best management practices that can be utilized for these purposes. This paper includes an overview describing the importance of sustainability in technology selection, identifies sustainability impacts related to technologies that can be used to treat 1,4‐dioxane, provides an approximating approach to assess sustainability impacts, and summarizes potential sustainability impacts related to promising treatment technologies. ©2016 Wiley Periodicals, Inc.     

Remedial Process Optimization and Ozone Sparging for Petroleum Hydrocarbon‐Impacted Groundwater

A former natural gas processing station is impacted with total petroleum hydrocarbons (TPH) and benzene. Remedial process optimization (RPO) was conducted to evaluate the effectiveness of the historical air sparging/soil vapor extraction (AS/SVE) system and the current groundwater extraction and treatment system. The RPO indicated that both remedial activities offered no further benefit in meeting remediation goals. Instead, an in situ chemical oxidation (ISCO) system was recommended. Ozone was selected, and the results of a bench test indicated that the ozone demand was 8 to 12 mg ozone/mg TPH and that secondary by‐products would include hexavalent chromium and bromate. A capture zone analysis was conducted through groundwater flow modeling (MODFLOW) to ensure containment of the injected oxidant using the existing groundwater extraction system. Results of a pilot study indicated that the optimum frequency of ozone sparging is 60 minutes in order to reach a maximum radius of influence of 20 feet. TPH concentrations within the treatment zone decreased by 97 percent over two months of ozone sparging. Concentrations of hexavalent chromium and bromate increased from nondetect to 44 and 110 mg/L, respectively, during the ozone sparging but attenuated to nondetectable concentrations within three months of system shut down. ©2016 Wiley Periodicals, Inc.     

Implementing pro-poor policies in a decentralized context: the case of the Rural Water Supply and Sanitation Program in Tanzania

This paper examines the challenge of achieving a balance between the implementation of centrally designed pro-poor policies and the decentralization of responsibilities to local governments in many African countries. It analyzes the implementation of the Rural Water Supply and Sanitation Program in Tanzania. Key mechanisms for planning and allocating resources are analyzed at ministry, district, and village levels. Results show that a mixture of policy incoherencies, technical shortcomings and political influence determine that only a small proportion of funds reaches the underserved areas. We argue that a greater connection between the bottom-up and top-down planning mechanisms, and a sharp increase of downwards accountability are needed before decentralized decision-making result in better resources allocation. Meanwhile a bigger intervention from central government is needed.