不同孔径HZSM-5协同低温等离子体催化降解甲苯性能研究

研究了HZSM-5分子筛孔径对其在等离子体场内催化降解甲苯的影响.采用化学液相沉积法对HZSM-5分子筛进行改性,利用XRD、氮气吸附脱附等方法表征样品的骨架结构和表面性质,并用择形吸附实验对样品孔径进行表征.同时,评价了HZSM-5分子筛体系中降解甲苯的性能,研究了分子筛吸附甲苯性能及臭氧的产量,并采用飞行时间质谱(TOF-MS)和气相色谱-质谱联用仪(GC-MS)分析了反应产生的有机副产物.结果表明:液相沉积法成功调控了HZSM-5孔径,样品孔径随沉积剂用量增加而减小;同时,样品均具有相同的MFI骨架结构,比表面积和孔容相差不大.HZSM-5的孔径尺寸对甲苯去除率影响不大,但对碳平衡有影响,孔径越大,碳平衡越好.孔径较大的HZSM-5分子筛对甲苯具有更大的吸附速率和吸附容量,同时更多臭氧参与反应,生成·OH和O·,促进甲苯深度氧化,减少副产物,提高碳平衡.     

苏鲁边界区域水资源保护与利用的协同机制探讨——以南四湖为例

通过对苏鲁界湖南四湖水源保护与利用状况的详细考察,全面系统分析了湖域水资源现状、存在的关键问题、影响因素等。针对湖域水资源现状,探讨了南四湖流域水资源保护与利用的协同机制,即建立湖域水资源协同规划与管理机制、湖区经济协同发展机制、生态修复与补偿协同机制、群众协同参与与监督机制、水危机协同处置机制和湖域界面冲突协同控制机制等,以促进跨界区域水资源的保护与利用,统筹区域协同发展,增强南四湖湖域的可持续发展能力。     

环境资源保存理论视角下人与机器设备合理操作性研究

人类发展到了工业时代以后,机械极大地提升了人类改变世界的步伐,机械带来便利的同时对环境影响非常巨大,这样便引起了人、环境、机械三者之间的重新定位思考,针对上述问题,提出一种环境资源保存理论视角下的人与设备情感研究.以环境资源保存理论为指导理论建立了情感计算模型,建立的情感模型能够有效的对人、机械、环境三者的关系进行情感趋向的计算,能够有效的通过环境资源保存理论进行环境数据的衡量分析.为了保证环境资源保存理论视角下的人与设备情感的研究方案的正确性,设计了实证调研,通过实证调研的数据分析能够有效的证明研究的环境资源保存理论视角下的人与设备情感关系的正确性.     

Leak location of pipelines based on transient model and PSO-SVM

An improved and integrated approach of support vector machine and particle swarm optimization theory (PSO-SVM) is first used to detect the leak location of pipelines and overcome the problem of multiple leaks. The calibration and predictive ability of improved PSO-SVM is investigated and compared with that of other common method, back-propagation neural network (BPNN). Two conditions are evaluated. One with a leak involves a set of 20 samples, while another with two leaks has 127 samples. Both internal and external validations are performed to validate the performance of the resulting models. The results show that, for the two conditions, the values calculated by improved PSO-SVM are in good agreement with those simulated by transient model, and the performances of improved PSO-SVM models are superior to those of BPNN. This paper provides a new and effective method to inspect the multiple leak locations, and also reveals that improved PSO-SVM can be used as a powerful tool for studying the leak of pipeline.     

安静小区噪声测试技术探讨

随着城市的发展,人口密度不断增加,居住小区的声环境质量呈下降之势.研究表明:低量的噪音污染是“慢性毒药”,是造成大楼综合症、亚健康的罪魁祸首之一.环境噪声已成为当今我国城市环境问题的四大公害之一,全国约有2/3的城市居民生活在噪声超标的环境中,且有逐年上升的趋势.本文就其安静居住小区如何进行噪声测试,对其测试方法、测量仪器、布点技术等展开探讨,提供更为可靠、合理的监测数据,为进一步提升小区居民对环境质量满意率,切实解决噪声扰民问题提供科学依据.     

区域土地资源优化配置及其可持续利用

从土地利用优化配置入手，介绍了其基本内涵和研究进展，阐述了土地资源可持续利用的途径与目标以及评价方法，建立了区域土地利用持续评价模式。     

白土渣中润滑油回收技术的研究

研究开发了一种回收白土渣中润滑油的新技术--溶剂抽提技术.通过对润滑油回收量的综合比较,确立了实验所用的抽提溶剂及处理工艺的操作条件.结果表明:用石脑油馏分(60～90℃)抽提溶剂,最佳溶剂与白土渣投量比为1:1,抽提次数为2,温度为室温,搅拌时间为15min且回流液质量百分比为5%情况下,润滑油回收率为92%左右,并且可形成稳定的循环操作模式,为溶剂抽提法回收白土渣中润滑油的工业化应用提供了科学依据.     

Indoor particle dynamics in a school office: determination of particle concentrations,deposition rates and penetration factors under naturally ventilated conditions

Recently, the problem of indoor particulate matter pollution has received much attention. An increasing number of epidemiological studies show that the concentration of atmospheric particulate matter has a significant effect on human health, even at very low concentrations. Most of these investigations have relied upon outdoor particle concentrations as surrogates of human exposures. However, considering that the concentration distribution of the indoor particulate matter is largely dependent on the extent to which these particles penetrate the building and on the degree of suspension in the indoor air, human exposures to particles of outdoor origin may not be equal to outdoor particle concentration levels. Therefore, it is critical to understand the relationship between the particle concentrations found outdoors and those found in indoor micro-environments. In this study, experiments were conducted using a naturally ventilated office located in Qingdao, China. The indoor and outdoor particle concentrations were measured at the same time using an optical counter with four size ranges. The particle size distribution ranged from 0.3 to 2.5 μm, and the experimental period was from April to September, 2016. Based on the experimental data, the dynamic and mass balance model based on time was used to estimate the penetration rate and deposition rate at air exchange rates of 0.03–0.25 h^?1. The values of the penetration rate and deposition velocity of indoor particles were determined to range from 0.45 to 0.82 h^?1 and 1.71 to 2.82 m/h, respectively. In addition, the particulate pollution exposure in the indoor environment was analyzed to estimate the exposure hazard from indoor particulate matter pollution, which is important for human exposure to particles and associated health effects. The conclusions from this study can serve to provide a better understanding the dynamics and behaviors of airborne particle entering into buildings. And they will also highlight effective methods to reduce exposure to particles in office buildings.     

SCREENING THE RELOCATION STRATEGIES OF WATER QUALITY MONITORING STATIONS BY COMPROMISE PROGRAMMING1

Water quality monitoring network designs historically have tended to use experience, intuition, and subjective judgment in siting monitoring stations only sporadically. Better design procedures for optimizing monitoring systems with respect to multiple criteria decision analysis had rarely been put into practice up front when the needs for intensive monitoring became critical. This paper describes a systematic relocation strategy that is organized to identify several significant planning objectives and consider a series of inherent constraints simultaneously. The planning objectives considered in this analysis are designed to enhance the detection possibility for lower compliance areas, reflect the emphasis for different attainable water uses at different locations, promote the potential detection for the lower degradation areas of pollutants, increase the protection degree of those areas with higher population density in the proximity of the river system, and strengthen the pre‐warning capability of water quality for water intakes. The constraint set contains the limitations of budget, the equity implication, and the detection sensitivity in the water environment. A case study in the Kao‐Ping River Basin, South Taiwan, demonstrates the application potential of this methodology based on a seamless integration between the optimization and the simulation models. It enables identification of the optimal locational pattern stepwise using the embedded screening and sequencing capacity in a compromise programming model. However, a well calibrated and verified water quality model is an indispensable tool in support of this multiobjective evaluation. Extra sampling procedures become necessary for the sites with sparse environmental information. Comparison of planning outcomes of compromise programming is made against previously achieved analyses by using weighted programming and fuzzy programming.