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71.
Heavy metals in untreated/treated urban effluent and sludge from a biological wastewater treatment plant 总被引:1,自引:0,他引:1
Oliveira Ada S Bocio A Trevilato TM Takayanagui AM Domingo JL Segura-Muñoz SI 《Environmental science and pollution research international》2007,14(7):483-489
Background, Aim and Scope
The presence of heavy metals in wastewater is one of the main causes of water and soil pollution. The aim of the present study was to investigate the removal of Cd, Cu, Pb, Hg, Mn, Cr and Zn in urban effluent by a biological wastewater treatment, as well as to quantify the levels of As, Be, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sn, Tl, V and Zn in dewatering sludge from the Biological Wastewater Treatment Plant to Ribeirão Preto (RP-BWTP), Brazil.Materials and Methods
Concentrations of Cd, Cr, Cu, Mn and Pb in wastewater and those of Ni in sludge were determined by atomic absorption spectrophotometry with graphite furnace atomization. Mercury concentrations in wastewater were measured by hydride generation atomic spectrophotometry, and Zn levels were determined by atomic absorption spectrophotometry using acetylene flame. In sludge, the levels of As, Be, Cd, Cr, Cu, Fe, Hg, Mn, Pb, Sn, Tl, V and Zn were determined by inductively coupled plasma-mass spectrometry.Results
The percentages of removal efficiency (RE) were the following: Hg 61.5%, Cd 60.0%, Zn 44.9%, Cu 44.2%, PB 39.7%, Cr 16,5% and Mn 10.4%. In turn, the mean concentrations (mg/kg) of metals in dewatering sludge followed this increasing order: Tl (<0.03), Hg (0.31), Be (0.43), As (1.14), Cd (1.34), V (59.2), Pb (132.1), Sn (166.1), Cr (195.0), Mn (208.1), Ni (239.4), Cu (391.7), Zn (864.4) and Fe (20537).Discussion
The relationship between metal levels in untreated wastewater, as well as the removal efficiency are in agreement with previous data from various investigators, It is important to note that metal removal efficiency is not only affected by metal ion species and concentration, but also by other conditions such as operating parameters, physical, chemical, and biological factors.Conclusions
Metal values recorded for treated wastewater and sludge were within the maximum permitted levels established by the Environmental Sanitation Company (CETESB), São Paulo, Brazil.Recommendations
There is an urgent need for the authorities who are responsible for legislation on sludge uses in agriculture of establishing safety levels for As, Be, Hg, Sn, Tl and V.Perspectives
According to the current metal levels, RP-BWTP sludge might be used for agriculture purposes. However, for an environmentally safe use of sewage sludge, further studies including systematic monitoring are recommended. Annual metal concentrations and predicted variations of those elements in the sludge should be monitored.72.
Oil spills due to oil pipelines is a very frequent problem in Mexico. Petroleos Mexicanos (PEMEX), very concerned with the
environmental agenda, has been developing inspection and correction plans for zones around oil pipelines pumping stations
and pipeline right-of-way. These stations are located at regular intervals of kilometres along the pipelines. In this study,
two sections of an oil pipeline and two pipeline pumping stations zones are characterized in terms of the presence of Total
Petroleum Hydrocarbons (TPHs) and Polycyclic Aromatic Hydrocarbons (PAHs). The study comprehends sampling of the areas, delimitation
of contamination in the vertical and horizontal extension, analysis of the sampled soils regarding TPHs content and, in some
cases, the 16 PAHs considered as priority by USEPA, calculation of areas and volumes contaminated (according to Mexican legislation,
specifically NOM-EM-138-ECOL-2002) and, finally, a proposal for the best remediation techniques suitable for the contamination
levels and the localization of contaminants. 相似文献
73.
The Ephemeroptera family Baetidae is one of the most specious families in the Neotropical region and a great effort to improve
the taxonomy of this group has been made over the last 10 years in South America. Such studies now enable the development
of biomonitoring tools at species-level in the region. A total of 2,199 baetids were collected from seven sampling sites,
collected three times (autumn, winter and summer), representing an environmental gradient, draining an area of Atlantic Forest
remnants. We describe the mesohabitat of nine Baetidae species and evaluate their responses to environmental degradation and
water chemistry by means of biological measures (richness and abundance) and multivariate analysis (Canonical Correspondence
Analysis), in order to assess their potential capacity as indicators of these impacts. Most species were found predominantly
associated with stony substrates, but some were associated with pool litter, and one species was found predominantly in riffle
litter substrate. Species distribution was influenced by the environmental gradient. Based on the CCA ordination, we were
able to identify which species were found in pristine versus the most impaired areas, therefore enabling us to establish the sensitivity of each species. 相似文献
74.
Effects of Subsistence Hunting on Vertebrate Community Structure in Amazonian Forests 总被引:9,自引:0,他引:9
Carlos A. Peres 《Conservation biology》2000,14(1):240-253
Abstract: Subsistence hunting affects vast tracts of tropical wilderness that otherwise remain structurally unaltered, yet distinguishing hunted from nonhunted tropical forests presents a difficult problem because this diffuse form of resource extraction leaves few visible signs of its occurrence. I used a standardized series of line-transect censuses conducted over a 10-year period to examine the effects of subsistence game harvest on the structure of vertebrate communities in 25 Amazonian forest sites subjected to varying levels of hunting pressure. Crude vertebrate biomass, which was highly correlated with hunting pressure, gradually declined from nearly 1200 kg km−2 at nonhunted sites to less than 200 kg km−2 at heavily hunted sites. Hunting had a negative effect on the total biomass and relative abundance of vertebrate species in different size classes at these forest sites, but it did not affect their overall density. In particular, persistent hunting markedly reduced the density of large-bodied game species (>5 kg), which contributed a large proportion of the overall community biomass at nonhunted sites (65–78%) and lightly hunted sites (55–71%). Nutrient-rich floodplain forests contained a consistently greater game biomass than nutrient-poor unflooded forests, once I controlled for the effects of hunting pressure. Conservative estimates of game yields indicate that as many as 23.5 million game vertebrates, equivalent to 89,224 tons of bushmeat with a market value of US$190.7 million, are consumed each year by the rural population of Brazilian Amazonia, which illustrates the enormous socioeconomic value of game resources in the region. My cross-site comparison documents the staggering effect of subsistence hunters on tropical forest vertebrate communities and highlights the importance of considering forest types and forest productivity in game management programs. 相似文献
75.
Justina Catarino João Henriques Anabela Maia 《International Journal of Sustainable Engineering》2016,9(1):35-46
The activities developed within an eco-efficiency project in mineral industries located in the largest area for marble extraction in Portugal, in Alentejo region, in the Estremoz – Borba and Vila Viçosa anticline are presented in this paper. The project was designed to apply the sustainability concept in seven companies of marble extraction and transformation. The adopted strategy used new cleaner production models together with sustainable value (SV) improvement, leading to the rationalization of the industrial process, the involvement of economic agents and the orientation of the management of production processes towards eco-efficiency. The challenge was to have the mineral industry managing efficiently the resources on which the business depends, according to sustainability principles. Different opportunities for improvement, related to the minimization of materials, water and energy use, were identified in the companies. Some proposals mainly related to social improvement and small and medium-sized enterprise competitiveness benefits were also selected and discussed. This approach allows the integration of sustainability at company's and region's levels by combining in the entrepreneurial activity the creation of wealth together with the environment protection and the achieving of social benefits. Highlights: The involvement of different stakeholders in the project (Eco-efficiency in Portuguese companies of marble sector) was positive in the discussion and search of solutions for companies. It is possible to involve marble extraction and processing companies in eco-efficiency improvement towards sustainability. Companies from the marble sector improved environmental and social performance and reduced the costs of their production processes by applying SV methodology. 相似文献
76.
Inara Amoroso da Silva Stella Thomaz de Lima Marcos Rechi Siqueira Márcia Andreia Mesquita Silva da Veiga Valeria Reginatto 《Journal of Material Cycles and Waste Management》2018,20(2):777-786
Fermentation can use renewable raw materials as substrate, which makes it a sustainable method to obtain H2. This study evaluates H2 production by a mixed culture from substrates such as glucose and derivatives from sugarcane processing (sucrose, molasses, and vinasse) combined with landfill leachate. The leachate alone was not a suitable substrate for biohydrogen production. However, leachate blended with glucose, sucrose, molasses, or vinasse increased the H2 production rate by 2.0-, 2.8-, 4.6-, and 0.5-fold, respectively, as compared with the substrates without the leachate. Determination of metals (Cu, Cd, Pb, Hg, Ni, and Fe) at the beginning and at the end of the fermentative assays showed how they were consumed during the fermentation and demonstrated improved H2 production. During fermentation, Cu, Fe, and Cd were the most consumed leachate metals. The best substrate combination to produce H2 was molasses and leachate, which gave high volumetric productivity—469 ml H2/l h. However, addition of the leachate to the substrates stimulated lactic acid formation pathways, which lowered the H2 yield. The use of leachate combined with sugarcane processing derivatives as substrates could add value to the leachate and reduce its polluting power, generating a clean energy source from renewable raw materials. 相似文献
77.
Rui Galhano dos Santos Noemi F. Acero Sandro Matos Ricardo Carvalho Mário Vale Ana C. Marques João C. Bordado Maria M. Mateus 《Journal of Polymers and the Environment》2018,26(1):91-100
The use of petroleum-derived products should be avoided regarding the principles of green and sustainable chemistry. The work reported herein, is aimed at the liquefaction of pine shavings for the production of an environmentally-friendly polyol suitable to be used in the formulations of sprayable polyurethane foams. The biopolyols were obtained in high yield and were used to replace those derived from fossil sources, to produce more “greener” polyurethane foams and therefore, less dependent on petroleum sources, since the polyol component was substituted by products resulting from biomass liquefaction. The partial and fully exchange of the polyols was accomplished, and the results compared with a reference foam. The foams were afterward, chemical, physical, morphological, and mechanically characterized. The complete replacement of polyether polyol and polyol polyester has presented some similar characteristics as that used as a reference, validating that the path chosen for the development of more sustainable materials is on the right track for the contribution to a cleaner world. 相似文献
78.
79.
M. J. Patiño Ropero N. Rodríguez Fariñas R. Mateo J. J. Berzas Nevado R. C. Rodríguez Martín-Doimeadios 《Environmental science and pollution research international》2016,23(7):6074-6081
The impact of mercury (Hg) pollution in the terrestrial environments and the terrestrial food chains including the impact on human food consumption is still greatly under-investigated. In particular, studies including Hg speciation and detoxification strategies in terrestrial animals are almost non-existing, but these are key information with important implications for human beings. Therefore, in this work, we report on Hg species (inorganic mercury, iHg, and monomethylmercury, MeHg) distribution among terrestrial animal tissues obtained from a real-world Hg exposure scenario (Almadén mining district, Spain). Thus, we studied Hg species (iHg and MeHg) and total selenium (Se) content in liver and kidney of red deer (Cervus elaphus; n?=?41) and wild boar (Sus scrofa; n?=?16). Similar mercury species distribution was found for both red deer and wild boar. Major differences were found between tissues; thus, in kidney, iHg was clearly the predominant species (more than 81 %), while in liver, the species distribution was less homogeneous with a percentage of MeHg up to 46 % in some cases. Therefore, Hg accumulation and MeHg transfer were evident in terrestrial ecosystems. The interaction between total Se and Hg species has been evaluated by tissue and by animal species. Similar relationships were found in kidney for both Hg species in red deer and wild boar. However, in liver, there were differences between animals. The possible underlying mechanisms are discussed. 相似文献
80.
M.?Antonia?Lopez-AntonEmail author Nuria?Fernández-Miranda M.?Rosa?Martínez-Tarazona 《Environmental science and pollution research international》2016,23(24):24495-24503
Mercury is a well-known toxic element, and flue gas streams emitted from coal-fired utilities are one of the largest anthropogenic sources of this element. This study briefly reviews the proposed technologies for reducing mercury emissions from coal combustion, focusing on an emerging process which involves the use of regenerable sorbents and especially those loaded with noble metals. Among the mercury species formed during coal combustion, elemental mercury is the most difficult to remove from the flue gases due to its low reactivity and insolubility in water. The widespread interest in using regenerable sorbents with metals is due to their ability to retain elemental mercury. With this technology, not only can efficiencies of 100 % be reached in the retention of elemental mercury but also a way to avoid the generation of new wastes loaded with mercury. This study considers the main aspects that must be taken into account when developing effective regenerable sorbents for mercury capture, with special attention to sorbents containing noble metals. The characteristics of this process are compared with those of other processes in a more advanced state of development. 相似文献