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691.
The occurrence of free and conjugated estrogens was examined in a survey of eleven sewage treatment plants (STPs) and their discharge water in the United Kingdom using grab sampling. The STPs included trickling filter with and without tertiary treatment, and activated sludge with tertiary treatment. For three activated sludge plants both influent and effluent samples were compared. For a further 8 STPs only the effluent was examined. The estrone-3-sulphate, estradiol-3-sulphate and estriol-3-sulphate concentrations (up to 20 ng L−1) were typically 5-fold that of the respective free estrogen concentration in the effluents. This represents a substantial additional ‘potential’ estrogen load arriving in the receiving waters. Estrone-3-glucuronide was found at 9 ng L−1, estradiol-3-glucuronide at 7 ng L−1, and estriol-3-glucuronide at 32 ng L−1 in sewage influent. Except on one occasion, no glucuronide conjugates could be found in the effluent. The results suggest in most cases glucuronide conjugates will be completely transformed in sewage treatment whilst sulphate conjugates will only be partially removed. 相似文献
692.
Beck DA Johnson GR Spolek GA 《Environmental pollution (Barking, Essex : 1987)》2011,159(8-9):2111-2118
Numbers of greenroofs in urban areas continue to grow internationally; so designing greenroof soil to reduce the amount of nutrients in the stormwater runoff from these roofs is becoming essential. This study evaluated changes in extensive greenroof water discharge quality and quantity after adding biochar, a soil amendment promoted for its ability to retain nutrients in soils and increase soil fertility. Prototype greenroof trays with and without biochar were planted with sedum or ryegrass, with barren soil trays used as controls. The greenroof trays were subjected to two sequential 7.4cm/h rainfall events using a rain simulator. Runoff from the rain events was collected and evaluated. Trays containing 7% biochar showed increased water retention and significant decreases in discharge of total nitrogen, total phosphorus, nitrate, phosphate, and organic carbon. The addition of biochar to greenroof soil improves both runoff water quality and retention. 相似文献
693.
Nelson SJ Johnson KB Kahl JS Haines TA Fernandez IJ 《Environmental monitoring and assessment》2007,126(1-3):69-80
Precipitation and streamwater samples were collected from 16 November 1999 to 17 November 2000 in two watersheds at Acadia
National Park, Maine, and analyzed for mercury (Hg) and dissolved inorganic nitrogen (DIN, nitrate plus ammonium). Cadillac
Brook watershed burned in a 1947 fire that destroyed vegetation and soil organic matter. We hypothesized that Hg deposition
would be higher at Hadlock Brook (the reference watershed, 10.2 μg/m2/year) than Cadillac (9.4 μg/m2/year) because of the greater scavenging efficiency of the softwood vegetation in Hadlock. We also hypothesized the Hg and
DIN export from Cadillac Brook would be lower than Hadlock Brook because of elemental volatilization during the fire, along
with subsequently lower rates of atmospheric deposition in a watershed with abundant bare soil and bedrock, and regenerating
vegetation. Consistent with these hypotheses, Hg export was lower from Cadillac Brook watershed (0.4 μg/m2/year) than from Hadlock Brook watershed (1.3 μg/m2/year). DIN export from Cadillac Brook (11.5 eq/ha/year) was lower than Hadlock Brook (92.5 eq/ha/year). These data show that
∼50 years following a wildfire there was lower atmospheric deposition due to changes in forest species composition, lower
soil pools, and greater ecosystem retention for both Hg and DIN. 相似文献
694.
Bednar AJ Medina VF Ulmer-Scholle DS Frey BA Johnson BL Brostoff WN Larson SL 《Chemosphere》2007,70(2):237-247
This work studied interactions of uranium with pure organic compounds, such as glutathione, and more complex mixtures, such as humic acid and aqueous plant extracts. High performance liquid chromatography with UV absorption interfaced to inductively coupled plasma mass spectrometry sequential detection was used to detect organouranium complexes in a variety of soils and plant materials, indicating that nearly 100% of the uranium extracted from certain plant tissues was bound to organic ligands. In addition, soil sorption experiments indicated that humic acid generally decreased uranium sorption to soils and promoted subsequent desorption of uranium because of uranium partitioning to the organic phase. These experiments demonstrate that organic compounds influence the mobility and chemistry of uranium in the environment. 相似文献
695.
Perchloroethylene (PCE) saturations determined from GPR surveys were used as observations for inversion of multiphase flow simulations of a PCE injection experiment (Borden 9 m cell), allowing for the estimation of optimal bulk intrinsic permeability values. The resulting fit statistics and analysis of residuals (observed minus simulated PCE saturations) were used to improve the conceptual model. These improvements included adjustment of the elevation of a permeability contrast, use of the van Genuchten versus Brooks-Corey capillary pressure-saturation curve, and a weighting scheme to account for greater measurement error with larger saturation values. A limitation in determining PCE saturations through one-dimensional GPR modeling is non-uniqueness when multiple GPR parameters are unknown (i.e., permittivity, depth, and gain function). Site knowledge, fixing the gain function, and multiphase flow simulations assisted in evaluating non-unique conceptual models of PCE saturation, where depth and layering were reinterpreted to provide alternate conceptual models. Remaining bias in the residuals is attributed to the violation of assumptions in the one-dimensional GPR interpretation (which assumes flat, infinite, horizontal layering) resulting from multidimensional influences that were not included in the conceptual model. While the limitations and errors in using GPR data as observations for inverse multiphase flow simulations are frustrating and difficult to quantify, simulation results indicate that the error and bias in the PCE saturation values are small enough to still provide reasonable optimal permeability values. The effort to improve model fit and reduce residual bias decreases simulation error even for an inversion based on biased observations and provides insight into alternate GPR data interpretations. Thus, this effort is warranted and provides information on bias in the observation data when this bias is otherwise difficult to assess. 相似文献
696.
Peckenham JM Kahl JS Nelson SJ Johnson KB Haines TA 《Environmental monitoring and assessment》2007,126(1-3):97-104
Fall and spring streamwater samples were analyzed for total mercury (Hg) and major ions from 47 locations on Mount Desert
Island in Maine. Samples were collected in zones that were burned in a major wildfire in 1947 and in zones that were not burned.
We hypothesized that Hg concentrations in streamwater would be higher from unburned sites than burned watersheds, because
fire would volatilize stored Hg. The Hg concentrations, based on burn history, were not statistically distinct. However, significant
statistical associations were noted between Hg and the amount of wetlands in the drainage systems and with streamwater dissolved
organic carbon (DOC). An unexpected result was that wetlands mobilized more Hg by generating more DOC in total, but upland DOC was more efficient at transporting Hg because it transports more Hg per unit DOC. Mercury concentrations were higher in samples collected at lower elevations. Mercury was positively correlated with relative
discharge, although this effect was not distinguished from the DOC association. In this research, sample site elevation and
the presence of upstream wetlands and their associated DOC affected Hg concentrations more strongly than burn history. 相似文献
697.
The use of porous framework materials in waste management applications has the potential to be a powerful tool in toxic metal remediation. The properties that these materials possess, including high surface area and ion-exchange capacity, are theoretically valuable. Furthermore, the flexibility of many of these frameworks allows the potential for immobilisation of waste materials with the framework of the material, in addition to the traditional capture in the pore structure. However, for either of these routes to be useful for waste management purposes, these structures must also be stable in any proposed storage media. This study examines the stability of a range of porous materials whose frameworks are made out of zinc and arsenic, both considered toxic minesite wastes, when exposed to aqueous media. The three frameworks examined (sodalite analogue Na(6)(H(2)O)(8)(ZnAsO(4))(6), open framework K(3)Zn(4)O(AsO(4))(3).3.5H(2)O, and an ABW type framework NH(4)ZnAsO(4)) all have similar hydrothermal synthetic routes and bulk framework compositions, but differ in counter ion used, pore size and complexity of structure. The phases were examined before and after storage in an aqueous environment, and their crystallinity and leaching were determined. All phases prepared were found to be extremely unstable outside their original synthetic environment, and very soluble when exposed to water, calling into question their practical use in any environment. 相似文献
698.
Chowdhury Z Edwards RD Johnson M Naumoff Shields K Allen T Canuz E Smith KR 《Journal of environmental monitoring : JEM》2007,9(10):1099-1106
We have developed a small, light, passive, inexpensive, datalogging particle monitor called the "UCB" (University of California Berkeley particle monitor). Following previously published laboratory assessments, we present here results of tests of its performance in field settings at high particle concentrations. We demonstrate the mass sensitivity of the UCB in relation to gravimetric filter-based PM(2.5) mass estimates as well as commercial light-scattering instruments co-located in field chamber tests and in kitchens of wood-burning households. The coefficient of variation of the unadjusted UCB mass response in relation to gravimetric estimates was 15%. Although requiring adjustment for differences in sensitivity, inter-monitor performance was consistently high (r(2) > 0.99). Moreover, the UCB can consistently estimate PM(2.5) mass concentrations in wood-burning kitchens (Pearson r(2) = 0.89; N = 99), with good agreement between duplicate measures (Pearson r(2) = 0.94; N = 88). In addition, with appropriate cleaning of the sensing chamber, UCB mass sensitivity does not decrease with time when used intensively in open woodfire kitchens, demonstrating the significant potential of this monitor. 相似文献
699.
Little EE Calfee RD Theodorakos P Brown ZA Johnson CA 《Environmental science and pollution research international》2007,14(5):333-337
Background Cobalt cyanide complexes often result when ore is treated with cyanide solutions to extract gold and other metals. These have
recently been discovered in low but significant concentrations in effluents from gold leach operations. This study was conducted
to determine the potential toxicity of cobalt-cyanide complexes to freshwater organisms and the extent to which ultraviolet
radiation (UV) potentiates this toxicity. Tests were also conducted to determine if humic acids or if adaptation to UV influenced
sensitivity to the cyanide complexes.
Methods Rainbow trout (Oncorhynchus mykiss), Daphnia magna, and Ceriodaphnia dubia were exposed to potassium hexacyanocobaltate in the presence and absence of UV radiation, in the presence and absence of
humic acids. Cyano-cobalt exposures were also conducted with C. dubia from cultures adapted to elevated UV.
Results With an LC50 concentration of 0.38 mg/L, cyanocobalt was over a 1000 times more toxic to rainbow trout in the presence of
UV at a low, environmentally relevant irradiance level (4 μW/cm2 as UVB) than exposure to this compound in the absence of UV with an LC50 of 112.9 mg/L. Toxicity was immediately apparent,
with mortality occurring within an hour of the onset of exposure at the highest concentration. Fish were unaffected by exposure
to UV alone. Weak-acid dissociable cyanide concentrations were observed in irradiated aqueous solutions of cyanocobaltate
within hours of UV exposure and persisted in the presence of UV for at least 96 hours, whereas negligible concentrations were
observed in the absence of UV. The presence of humic acids significantly diminished cyanocobalt toxicity to D. magna and reduced mortality from UV exposure. Humic acids did not significantly influence survival among C. dubia. C. dubia from UV-adapted populations were less sensitive to metallocyanide compounds than organisms from unadapted populations.
Conclusions The results indicate that metallocyanide complexes may pose a hazard to aquatic life through photochemically induced processes.
Factors that decrease UV exposure such as dissolved organic carbon or increased pigmentation would diminish toxicity. 相似文献
700.
Johnson KB Haines TA Kahl JS Norton SA Amirbahman A Sheehan KD 《Environmental monitoring and assessment》2007,126(1-3):55-67
Throughfall and bulk precipitation samples were collected for two watersheds at Acadia National Park, Maine, from 3 May to
16 November 2000, to determine which landscape factors affected mercury (Hg) deposition. One of these watersheds, Cadillac
Brook, burned in 1947, providing a natural experimental design to study the effects of forest type on deposition to forested
watersheds. Sites that face southwest received the highest Hg deposition, which may be due to the interception of cross-continental
movement of contaminated air masses. Sites covered with softwood vegetation also received higher Hg deposition than other
vegetation types because of the higher scavenging efficiency of the canopy structure. Methyl mercury (MeHg) deposition was
not affected by these factors. Hg deposition, as bulk precipitation and throughfall was lower in Cadillac Brook watershed
(burned) than in Hadlock Brook watershed (unburned) because of vegetation type and watershed aspect. Hg and MeHg inputs were
weighted by season and vegetation type because these two factors had the most influence on deposition. Hg volatilization was
not determined. The total Hg deposition via throughfall and bulk precipitation was 9.4 μg/m2/year in Cadillac Brook watershed and 10.2 μg/m2/year in Hadlock Brook watershed. The total MeHg deposition via throughfall and bulk precipitation was 0.05 μg/m2/year in Cadillac Brook watershed and 0.10 μg/m2/year in Hadlock Brook watershed. 相似文献