The importance of considering spatial attributes in evaluating estuarine habitat condition: the South Carolina experience

The South Carolina Estuarine and Coastal Assessment Program (SCECAP) was initiated in 1999 to assess the condition of the state's coastal habitats using multiple measures of water quality, sediment quality, and biological condition. Sampling was subsequently expanded to include components required for the National Coastal Assessment (Coastal 2000) Program. Habitats are classified as either tidal creeks (<#60; 100 meters in width) or larger open water bodies. Approximately 30 sites are sampled within each habitat during the summer months using a probability-based random sampling design. Results obtained from the first two years of sampling documented significant differences in several water quality parameters (DO, salinity, pH, turbidity, fecal coliform bacteria, total nitrogen, TKN, total phosphorus) and biological measures (chlorophyll-a, finfish and crustacean abundance and biomass and a number of benthic species) between the tidal creek and open water habitats. These differences highlight the value of partitioning shallow water habitats separately from the larger open water bodies traditionally sampled in estuarine monitoring programs, especially since tidal creeks serve as critical nursery areas for many species. Based on the differences observed, there is a clear need to identify different physical and biological thresholds for evaluating the condition of each habitat type.     

Uranium speciation in moorland river water samples: a comparison of experimental results and computer model predictions

An on-line method has been developed for separating inorganic and organic bound uranium species present in river water samples. The method utilised a small chelating resin (Hyphan) column incorporated into the sample introduction manifold of an ICP-MS instrument. The method was evaluated for samples from rivers on Dartmoor (Devon, UK), an area of granite overlain with peat bogs. The results indicate that organic-uranium species form a major proportion (80%) of the total dissolved uranium present. Further work with synthetic water samples indicated that the level of dissolved organic carbon played a greater role in determining the level of organic-uranium species than did sample pH. Computer models for the water samples were constructed using the WHAM program (incorporating uranium data from the Nuclear Energy Agency Thermochemical Database project) in order to predict the levels of organic-uranium species that would form. By varying the proportion of humic and fulvic acids used in the humic component, predictions within 10% of the experimental results were obtained. The program did exhibit a low bias at higher pH values (7.5) and low organic carbon concentrations (0.5 microg ml(-1)), but under the natural conditions prevalent in the Dartmoor water samples, the model predictions were successful.     

The consequences of alternative environmental management goals: A non-linear programming analysis of nuclear weapons legacy clean-up at Oak Ridge National Laboratory

Prioritization of projects within the U.S. Department of Energy's (DOE) Weapons Complex Clean-up Program, exemplified with data from the Oak Ridge National Laboratory, is quite sensitive to overall goals. Non-linear programming analysis of three alternative goals - mortgage reduction, terminal-period risk minimization, and current-period risk minimization - shows substantial differences in waste treated, risk reduced, and cost over a ten-year period. This revised version was published online in July 2006 with corrections to the Cover Date.     

Water Use Efficiency and Storage Capacity in South Asia by 2050

More than one billion South Asians are affected by water scarcity. Pressure on water resources is likely to grow as a result of population growth, urban expansion, and climate change. This paper assesses the impacts of these effects on the historical hydrological baseline, with particular focus on irrigation. A geospatial water balance model was developed for this purpose based on geo‐referenced information available in scientific public domain databases. Annual water supply and demand for a baseline period 1950–2000 were calculated and projected to 2050 using (1) outputs from 19 Global Circulation Models from the Coupled Model Intercomparison Project Phase 5 for a Representative Concentration Pathway 4.5; (2) population projections to 2050; and (3) historical land‐use patterns at the country level. Improvements in water use efficiency and storage capacity were analyzed using the Modified Water Scarcity Index of the baseline and the projected water balance in 2050 at the watershed scale.     

GROUNDWATER MANAGEMENT ON THE TEXAS HIGH PLAINS1

ABSTRACT The effects of major water management practices on the pumping requirement from the Ogallala aquifer are discussed. Demand on the aquifer may be reduced as much as 15 percent by recycling irrigation runoff, 25 percent by recycling irrigation runoff and irrigating with water from playas, and 29 percent by recycling irrigation water in combination with irrigation from playas and artificial recharge of playa water to the aquifer. Other practices that can result in more efficient use of precipitation and groundwater are limited irrigation, land forming, soil profile modification, and improved irrigation systems, thereby reducing the pumping demand on the Ogallala. Additional water supplies can possibly be obtained by water harvesting, weather modification, and water importation. Conclusions reached were that the overdraft on the aquifer can be reduced by the application of sound water management practices on an area-wide basis.     

Application of the ERICA Integrated Approach to the Drigg coastal sand dunes

The EC-funded project 'Environmental Risks from Ionising Contaminants: Assessment and Management' (ERICA) developed an 'Integrated Approach' for assessing the impact of ionising radiation on ecosystems. This paper presents the application of the ERICA Integrated Approach, supported by a software programme (the ERICA Tool) and guidance documentation, to an assessment of the Drigg coastal sand dunes (Cumbria, UK). Targeted sampling provided site-specific data for sand dune biota, including amphibians and reptiles. Radionuclides reported included (90)Sr, (99)Tc, (137)Cs, (238)Pu, (239+240)Pu and (241)Am. Site-specific data were compared to predictions derived using the ERICA Tool. Some under- and over-predictions of biota activity concentrations were identified but can be explained by the specific ecological characteristics and contamination mechanism of the dunes. Overall, the results indicated no significant impact of ionising radiation on the sand dune biota and the Integrated Approach was found to be a flexible and effective means of conducting a radiation impact assessment.     

Measurement and Interpretation of Concentrations of Urban Atmospheric Organic Compounds

The presence of volatile organic compounds (VOCs) from traffic and other sources in urban areas is a cause for concern about public health. Canister, chemical derivatisation, particulate sampling and adsorption sampling techniques were used to measure VOC concentrations of a wide range of compounds (C6-C40) during a four day campaign in south London with subsequent laboratory analysis of the samples. Compounds quantified included alkanes, mono- and poly-nuclear aromatic hydrocarbons. Also the first sequential measurements of carbonyl compounds (C1-C8) in a UK urban area are presented. Results from canister and adsorption sampling methods are compared. A comparison of the results with other urban data is presented and the temporal variations in VOC concentrations were interpreted with reference to the prevalent wind speeds and directions. The CALINE4 line source dispersion model was generally successful in reproducing the daytime 12 hour average concentrations of selected VOCs.