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641.
Environmentally Friendly Polyurethane Composites: Preparation, Characterization and Mechanical Properties 总被引:1,自引:0,他引:1
J. L. Zhang D. M. Wu D. Y. Yang F. X. Qiu 《Journal of Polymers and the Environment》2010,18(2):128-134
The waterborne polyurethane (PU) prepolymer was prepared based on isophorone diisocyanate (IPDI), polyester polyol (N220), dimethylol propionic acid (DMPA) and hydroxyethyl methyl acrylate (HEMA). The modified waterborne polyurethane–acrylate (PUA) emulsions were obtained with different proportions of acrylate (butyl acrylate and methyl methacrylate) and initiating agent by in situ dispersion technique. The structures and thermal properties of prepared PU and PUA were analyzed and characterized with FT-IR, UV–Vis spectroscopy and DSC. The PUA hybrid samples had lower glass transition temperature of hard segment and higher decomposition temperatures than PU sample. Performances of the emulsion and film were studied by means of apparent viscidity, particle size and polydispersity, surface tension and mechanical properties. The results indicated that the particle sizes of the PUA dispersions were larger than those of the pure PU and the solvent resistance, mechanical properties of PUA films was improved compare with the unmodified polyurethane film. The film had the biggest hardness and the least water absorption when the BA/MMA mass ratio 5:5 modified PU. The obtained PUA have great potential application such as coatings, leather finishing, adhesives, sealants, plastic coatings and wood finishes. 相似文献
642.
Ben T. Hirsch 《Behavioral ecology and sociobiology》2011,65(2):391-399
A variety of factors can influence an individual’s choice of within-group spatial position. For terrestrial social animals,
predation, feeding success, and social competition are thought to be three of the most important variables. The relative importance
of these three factors was investigated in groups of ring-tailed coatis (Nasua nasua) in Iguazú, Argentina. Different age/sex classes responded differently to these three variables. Coatis were found in close
proximity to their own age/sex class more often than random, and three out of four age/sex classes were found to exhibit within-group
spatial position preferences which differed from random. Juveniles were located more often at the front edge and were rarely
found at the back of the group. Juveniles appeared to choose spatial locations based on feeding success and not predation
avoidance. Since juveniles are the most susceptible to predation and presumably have less prior knowledge of food source location,
these results have important implications in relation to predator-sensitive foraging and models of democratic group leadership.
Subadults were subordinate to adult females, and their relationships were characterized by high levels of aggression. This
aggression was especially common during the first half of the coati year (Nov–April), and subadults were more peripheralized
during this time period. Subadults likely chose spatial positions to avoid aggression and were actively excluded from the
center of the group by adult females. In the Iguazú coati groups, it appeared that food acquisition and social agonism were
the major determinants driving spatial choice, while predation played little or no role. This paper demonstrates that within-group
spatial structure can be a complex process shaped by differences in body size and nutritional requirements, food patch size
and depletion rate, and social dominance status. How and why these factors interact is important to understanding the costs
and benefits of sociality and emergent properties of animal group formation. 相似文献
643.
Patrick L. Hanrahan 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1332-1338
ABSTRACT A previous paper1 discusses the methodology for a new method for deriving the nitrogen dioxide/nitrogen oxide (NO2/NOx) ratio in plumes that originally are composed mainly of (NOx). It is called the Plume Volume Molar Ratio Method (PVMRM). This paper documents its performance against six different data sets. These performance evaluations show that the PVMRM can realistically predict the NO2 fraction at close-in receptors yet still provide conservative estimates so that the air quality standards can be protected. 相似文献
644.
645.
A. P. Altshuller S. L. Kopczynski D. Wilson W. Lonneman F. D. Sutterfield 《Journal of the Air & Waste Management Association (1995)》2013,63(10):791-794
Effects associated with photochemical air pollution were measured during irradiation of n-butane-nitrogen oxide or n-butane-ethane-nitrogen oxide mixtures, with small amounts of propylene or toluene added. The effects measured including nitrogen dioxide and oxidant dosages, yields of formaldehyde and peroxy-acetyl nitrate, and eye irritation response. The results obtained clearly show that beneficial effects result from selective changes in hydrocarbon composition as well as from reduction of total hydrocarbon concenfration. Exclusion of olefins and alkylbenzenes was highly effective in reducing oxidant dosage, formaldehyde and peroxyacetyl nitrate concentrations, and eye irritation response. The only penalty was a modest increase in nitrogen dioxide dosage. A large reduction in nitrogen oxide concentration reduced nitrogen dioxide dosage and eye irritation response, but with the penalty of a large increase in oxidant dosage. The desirability of preferentially reducing olefins and alkylbenzenes rather than paraffinic hydrocarbons, acetylene, and benzene is strongly supported by this study. Research and development efforts should be directed toward preferential hydrocarbon control by mechanical or catalytic control 相似文献
646.
N. Said T. Bishara A. García-Maraver M. Zamorano 《Waste management (New York, N.Y.)》2013,33(11):2250-2256
Rice straw can be used as a renewable fuel for heat and power generation. It is a viable mean of replacing fossil fuels and preventing pollution caused by open burning, especially in the areas where this residual biomass is generated. Nevertheless, the thermal conversion of rice straw can cause some operating problems such as slag formation, which negatively affects thermal conversion systems. So, the main objective of this research is studying the combustion behavior of rice straw samples collected from various regions by applying thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). In addition, the thermal behavior of ashes from rice straw was also analyzed in order to detect their melting points, and ash sintering was detected at different temperatures within the range between 550 and 1000 °C. Since washing rice straw with water could reduce the content of undesirable inorganic compounds related to the ash fusibility, samples of washed rice straw were analyzed under combustion conditions to investigate its differences regarding the thermal behavior of rice straw. The results showed that rice straw washing led to a significant improvement in its thermal behavior, since it reduced the ash contents and sintering formation. 相似文献
647.
648.
R.D. Fleming J.R. Allsup T.R. French D.E. Eccleston 《Journal of the Air & Waste Management Association (1995)》2013,63(6):451-458
Air pollutants in exhaust gas produced from LP-gas (propane) were studied using both laboratory engines and vehicles. The objective of the study was both to evaluate propane as a low-pollution fuel and to provide information on adjustment of engine parameters for advantageous use of propane as a low-pollution fuel. Variables in the study were air-fuel ratio (A/F), ignition timing schedule, and ambient temperature. Data comparable to that for propane relating A/F and ambient temperature to emissions are shown for natural gas and for gasoline. 相似文献
649.
Effectiveness of Scat‐Detection Dogs in Determining Species Presence in a Tropical Savanna Landscape
CARLY VYNNE JOHN R. SKALSKI RICARDO B. MACHADO MARTHA J. GROOM ANAH T. A. JÁCOMO JADER MARINHO‐FILHO MARIO B. RAMOS NETO CRISTINA POMILLA LEANDRO SILVEIRA HEATH SMITH SAMUEL K. WASSER 《Conservation biology》2011,25(1):154-162
Abstract: Most protected areas are too small to sustain populations of wide‐ranging mammals; thus, identification and conservation of high‐quality habitat for those animals outside parks is often a high priority, particularly for regions where extensive land conversion is occurring. This is the case in the vicinity of Emas National Park, a small protected area in the Brazilian Cerrado. Over the last 40 years the native vegetation surrounding the park has been converted to agriculture, but the region still supports virtually all of the animals native to the area. We determined the effectiveness of scat‐detection dogs in detecting presence of five species of mammals threatened with extinction by habitat loss: maned wolf (Chrysocyon brachyurus), puma (Puma concolor), jaguar (Panthera onca), giant anteater (Myrmecophaga tridactyla), and giant armadillo (Priodontes maximus). The probability of scat detection varied among the five species and among survey quadrats of different size, but was consistent across team, season, and year. The probability of occurrence, determined from the presence of scat, in a randomly selected site within the study area ranged from 0.14 for jaguars, which occur primarily in the forested areas of the park, to 0.91 for maned wolves, the most widely distributed species in our study area. Most occurrences of giant armadillos in the park were in open grasslands, but in the agricultural matrix they tended to occur in riparian woodlands. At least one target species occurred in every survey quadrat, and giant armadillos, jaguars, and maned wolves were more likely to be present in quadrats located inside than outside the park. The effort required for detection of scats was highest for the two felids. We were able to detect the presence for each of five wide‐ranging species inside and outside the park and to assign occurrence probabilities to specific survey sites. Thus, scat dogs provide an effective survey tool for rare species even when accurate detection likelihoods are required. We believe the way we used scat‐detection dogs to determine the presence of species can be applied to the detection of other mammalian species in other ecosystems. 相似文献
650.
REED F. NOSS ERICA FLEISHMAN† DOMINICK A. DELLASALA‡ JOHN M. FITZGERALD§ MART R. GROSS MARTIN B. MAIN†† FIONA NAGLE‡‡ STACEY L. O'MALLEY JON ROSALES§§ 《Conservation biology》2009,23(4):825-833
Abstract: The Society for Conservation Biology (SCB) can enhance conservation of biodiversity in North America by increasing its engagement in public policy. Toward this end, the North America Section of SCB is establishing partnerships with other professional organizations in order to speak more powerfully to decision makers and taking other actions—such as increasing interaction with chapters—geared to engage members more substantively in science-policy issues. Additionally, the section is developing a North American Biodiversity Blueprint, which spans the continental United States and Canada and is informed by natural and social science. This blueprint is intended to clarify the policy challenges for protecting continental biodiversity, to foster bilateral collaboration to resolve common problems, and to suggest rational alternative policies and practices that are more likely than current practices to sustain North America's natural heritage. Conservation scientists and practitioners can play a key role by drawing policy makers' attention to ultimate, as well as proximate, causes of biodiversity decline and to the ecological and economic consequences of not addressing these threats. 相似文献