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131.
Various analyses of physico-chemical characteristics and batch tests were conducted with the sludge obtained from a full-scale electrolysis facility for treating coal mine drainage in order to find the applicability of sludge as a material for removing Zn(II) in an aqueous phase. The physico-chemical analysis results indicated that coal mine drainage sludge (CMDS) had a high specific surface area and also satisfied the standard of toxicity characteristic leaching procedure (TCLP) because the extracted concentrations of certain toxic elements such as Pb, Cu, As, Hg, Zn, and Ni were much less than their regulatory limits. The results of X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) showed that the CMDS mainly consists of goethite (70%) and calcite (30%) as a weight basis. However, the zeta potential analysis represented that the CMDS had a lower isoelectric point of pH (pH(IEP)) than that of goethite or calcite. This might have been caused by the complexation of negatively charged anions, especially sulfate, which usually exists with a high concentration in coal mine drainage. The results of Fourier transform infrared (FT-IR) spectrometry analysis revealed that Zn(II) was dominantly removed as a form of precipitation by calcite, such as smithsonite [ZnCO?] or hydrozincite [Zn?(CO?)?(OH)?]. Recycling sludge, originally a waste material, for the removal process of Zn(II), as well as other heavy metals, could be beneficial due to its high and speedy removal capability and low economic costs. 相似文献
132.
Seung Min LeeJun Su Ha Poong Hyun Seong 《Journal of Loss Prevention in the Process Industries》2011,24(1):90-97
Communication error has been considered a primary cause of many incidents and accidents in the nuclear industry. In order to prevent these accidents, a method for the analysis of such communication errors is proposed here. This paper presents a qualitative and a quantitative method to analyze communication errors. The qualitative method focuses on finding a root cause of the communication error and predicting the type of communication error which could happen in nuclear power plants. We develop context conditions and antecedent-consequent links of influential factors related to communication errors. The quantitative analysis method focuses on estimating the probability of communication errors. To accomplish the quantification of communication errors, the Cognitive Speaking Process (CSP) is defined and a method to estimate the weighting factors and the probability is suggested. Finally, case studies conducted to validate the applicability of the proposed methods are detailed. From the results, we can foresee the effects of given plant conditions on communication errors and reduce the error occurrences. 相似文献
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Ming‐Chun Lu Jong‐Nan Chen Mei‐Fen Tu 《Journal of environmental science and health. Part. B》2013,48(5):859-872
Abstract The photocatalytic oxidation of propoxur, a nitrogen‐containing pesticide, has been investigated using aqueous TiO2 suspensions as catalyst in this study. The operating variables considered in the study were initial pH, temperature, [H2O2] and TiO2 loading. Results showed that 1 g/l of TiO2 was the optimum dosage for oxidizing propoxur in this system. Hydrogen peroxide can increase the oxidation rate with increasing its initial concentration. There was no obvious difference in the rate of propoxur oxidation at the initial pH of 4, 6 and 9, and the final pHs of reaction solutions were around 5.5. However, propoxur degraded slower at initial pH 2, and the pH did not vary during the period of photocatalytic reaction. The photocatalytic oxidation of propoxur using TiO2 suspensions as the photocatalyst was reaction‐controlled as indicated by the activation energy. 相似文献