全文获取类型
收费全文 | 915篇 |
免费 | 76篇 |
国内免费 | 175篇 |
专业分类
安全科学 | 58篇 |
废物处理 | 58篇 |
环保管理 | 78篇 |
综合类 | 415篇 |
基础理论 | 164篇 |
环境理论 | 1篇 |
污染及防治 | 218篇 |
评价与监测 | 77篇 |
社会与环境 | 70篇 |
灾害及防治 | 27篇 |
出版年
2024年 | 4篇 |
2023年 | 16篇 |
2022年 | 41篇 |
2021年 | 40篇 |
2020年 | 40篇 |
2019年 | 22篇 |
2018年 | 34篇 |
2017年 | 28篇 |
2016年 | 36篇 |
2015年 | 44篇 |
2014年 | 57篇 |
2013年 | 75篇 |
2012年 | 67篇 |
2011年 | 58篇 |
2010年 | 63篇 |
2009年 | 52篇 |
2008年 | 52篇 |
2007年 | 56篇 |
2006年 | 51篇 |
2005年 | 37篇 |
2004年 | 46篇 |
2003年 | 46篇 |
2002年 | 48篇 |
2001年 | 45篇 |
2000年 | 19篇 |
1999年 | 10篇 |
1998年 | 13篇 |
1997年 | 15篇 |
1996年 | 13篇 |
1995年 | 12篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1977年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有1166条查询结果,搜索用时 296 毫秒
921.
Cayetano MG Kim YJ Jung JS Batmunkh T Lee KY Kim SY Kim KC Kim DG Lee SJ Kim JS Chang LS 《Journal of the Air & Waste Management Association (1995)》2011,61(11):1192-1203
Deokjeok Island is located off the west coast of the Korean Peninsula and is a suitable place to monitor the long-range transport of air pollutants from the Asian continent. In addition to pollutants, Asian dust particles are also transported to the island during long-range transport events. Episodic transport of dust and secondary particles was observed during intensive measurements in the spring (March 31-April 11) and fall (October 13-26) of 2009. In this study, the chemical characteristics of long-range-transported particles were investigated based on highly time-resolved ionic measurements with a particle-into-liquid system coupled with an online ion chromatograph (PILS-IC) that simultaneously measures concentrations of cations (Li+, Na , NH4+, K+, Ca2+, Mg2+) and anions (F-, C1-, NO3-, SO42-). The aerosol optical thickness (AOT) distribution retrieved by the modified Bremen Aerosol Retrieval (M-BAER) algorithm from moderate resolution imaging spectroradiometer (MODIS) satellite data confirmed the presence of a thick aerosol plume coming from the Asian continent towards the Korean peninsula. Seven distinctive events involving the long-range transport (LRT) of aerosols were identified and studied, the chemical components of which were strongly related to sector sources. Enrichment of acidic secondary aerosols on mineral dust particles, and even of sea-salt components, during transport was observed in this study. Backward trajectory, chemical analyses, and satellite aerosol retrievals identified two distinct events: a distinctively high [Ca2++Mg2]/[Na+] ratio (>2.0), which was indicative of a preprocessed mineral dust transport event, and a low [Ca2++Mg2+]/[Na+] ratio (<2.0), which was indicative of severe aging of sea-salt components on the processed dust particles. Particulate C1- was depleted by up to 85% in spring and 50% in the fall. A consistent fraction of carbonate replacement (FCR) averaged 0.53 in spring and 0.55 in the fall. Supporting evidences of C1- enrichment on the marine boundary layer prior to a dust front were also found. Supplemental materials are available for this article. Go to the publisher's online edition of the Journal of the Air & Waste Management Association for sector and air mass classifications of clean and LRT cases. 相似文献
922.
采用升流式厌氧污泥床(UASB)反应器,对增大进水浓度和增大进水流量过程中,颗粒污泥对丙酸和丁酸冲击负荷变化响应进行了研究。实验表明,进水浓度从2 000 mg COD/L提高到5 000 mg COD/L,丙酸去除率骤降,而丁酸降解相对稳定;在保持进水浓度为3 000 mg COD/L的条件下,增大进水流量,负荷从7.5 kg COD/(m3.d)升高到15 kg COD/(m3.d)时,丙酸降解率骤降,丁酸降解率仍然相对稳定。实验结果符合降解热力学理论和传统抑制动力学的未解离挥发性脂肪酸理论,并发现改变反应器运行条件能够加剧未解离酸的抑制作用。同时提出了探讨厌氧过程中丙酸积累导致厌氧反应器运行失败的基础理论原因。 相似文献
923.
924.
925.
Occurrence of perfluorooctanoate and perfluorooctanesulfonate in the Korean water system: implication to water intake exposure 总被引:1,自引:0,他引:1
Kim SK Kho YL Shoeib M Kim KS Kim KR Park JE Shin YS 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1167-1173
Perfluorinated compounds (PFCs) measured in surface running waters indicated the existence of different emission sources in eight main city basins. The tap water reflected the contamination pattern and levels in their corresponding source water basins. The daily intakes through tap water consumption ranged from <0.01 to 0.73 ng kg−1 d−1 for perfluorooctanoate (PFOA) and <0.01 to 0.08 ng kg−1 d−1 for perfluorooctanesulfonate (PFOS). Tap water intake-derived exposure accounted for 8.6%-101% (for PFOA) and while <10% (for PFOS) of total daily exposure, which was estimated from Korean serum concentrations using a pharmacokinetic model. Our findings indicate that tap water intake could be an important contributor to PFOA exposure in Korean populations; accordingly, additional efforts are necessary to improve the removal efficiency of perfluorinated compounds (PFCs) in the water purification process. However, more fundamentally the aim would be to reduce the discharge of PFCs from potential sources within the basin. 相似文献
926.
选择青藏高原多年冻土区工程迹地的人工恢复植物和紫花针茅草原的优势植物以及对应的土壤样品进行对照,利用原子吸收法分析了它们的矿质元素含量特征。结果表明:多年冻土区工程迹地人工恢复区植物的元素含量:>1 000 μg/g的元素有Ca、P和Na,100~1 000 μg/g的元素有Mn、K、Fe、Mg和Al;而对照紫花针茅草原优势植物的元素含量:>1 000 μg/g的元素有Ca和Na,100~1 000 μg/g的元素有P、Mn、K、Fe、Mg和Al。人工恢复区土壤元素含量:>1 000 μg/g的元素有Ca、Fe和Mn,100~1000 μg/g的元素有Mg、K、Al、P和Na;对照紫花针茅草原土壤元素含量:>1 000 μg/g的元素有Ca、Fe,100~1 000 μg/g的元素有Mn、Mg、Al、K、P和Na。该区域植物和土壤元素含量都属于Ca > K 型。人工恢复植物和对照的紫花针茅草原植物对土壤元素的吸收能力具有较高的相似性。K和Al元素的累积与其他元素没有显著的相关关系,其他元素之间为正相关关系,元素之间的吸收累积属于协同作用,无明显的撷抗作用 相似文献
927.
Catalytic removal of bisphenol A from aqueous solution with hemoglobin immobilized on amino-modified magnetic nanoparticles as an enzyme catalyst was reported. The amino-modified magnetite nanoparticles were firstly prepared by the coprecipitation of Fe2+ and Fe3+ with NH3·H2O and then modified by 3-aminopropyltriethoxysilane. The immobilization process was optimized by examining enzyme concentration, glutaraldehyde concentration, cross-link time, and immobilization time. The optimum conditions for the removal of bisphenol A with immobilized hemoglobin were also investigated. Under the optimality conditions, the removal efficiency of bisphenol A was about 80.3%. The immobilization had a beneficial effect on the stability of hemoglobin and conversions of bisphenol A. According to the proposed breakdown pathway and the intermediates, the enzyme-catalytic removal of bisphenol A by the immobilized hemoglobin is considered to be an effective method. 相似文献
928.
In the Ag(II)/Ag(I) based mediated electrochemical oxidation (MEO) process, the spent waste from the electrochemical cell, which is integrated with the scrubber columns, contains high concentrations of precious silver as dissolved ions in both the anolyte and the catholyte. This work presents an electrochemical developmental study for the recovery of silver from simulated waste water from Ag(II)/Ag(I) based MEO process. Galvanostatic method of silver deposition on Ti cathode in an undivided cell was used, and the silver recovery rate kinetics of silver deposition was followed. Various experimental parameters, which have a direct bearing on the metal recovery efficiency, were optimized. These included studies with the nitric acid concentration (0.75-6M), the solution stirring rate (0-1400 rpm), the inter-electrode distance between the anode and the cathode (2-8 cm), the applied current density (29.4-88.2 mA cm(-2)), and the initial Ag(I) ion concentration (0.01-0.2M). The silver recovered by the present electrodeposition method was re-dissolved in 6M nitric acid and subjected to electrooxidation of Ag(I) to Ag(II) to ascertain its activity towards Ag(II) electrogeneration from Ag(I), which is a key factor for the efficient working of MEO process. Our studies showed that the silver metal recovered by the present electrochemical deposition method could be reused repeatedly for MEO process with no loss in its electrochemical activity. Some work on silver deposition from sulfuric acid solution of different concentrations was also done because of its promising features as the catholyte in the Ag(II) generating electrochemical cell used in MEO process, which include: (i) complete elimination of poisonous NO(x) gas liberation in the cathode compartment, (ii) reduced Ag(+) ion migration across Nafion membrane from anolyte to catholyte thereby diminished catholyte contamination, and (iii) lower cell voltage and hence lesser power consumption. 相似文献
929.
Effects of anions on the kinetics and reactivity of nanoscale Pd/Fe in trichlorobenzene dechlorination 总被引:1,自引:0,他引:1
Influences of anionic co-solutes on dechlorination of 1,2,4-trichlorobenzene (124TCB) by the nanoscale Pd/Fe particles were investigated in batch experiments in the presence of an anionic solute such as nitrate, nitrite, perchlorate, phosphate, carbonate, silica, sulfate, sulfite, or sulfide. Based on the extent of inhibitory effects on the 124TCB dechlorination, the anions can be ranked in the order of: control≈sulfate≈silica相似文献
930.
Thinh An Nguyen Dung Anh Vu Phai Van Vu Thanh Ngoc Nguyen Tam Minh Pham Hang Thi Thuy Nguyen Hai Trinh Le Thanh Viet Nguyen Lich Khac Hoang Thanh Duc Vu Tung Song Nguyen Tuyen Thi Luong Ngoc Phuong Trinh Luc Hens 《Environment, Development and Sustainability》2017,19(2):745-767
Vietnam is prone to tropical storms. Climate change effects contribute to sea level rise, floods, progression of the low water line and coastal erosion. This paper inventories the perception of local people, assesses and values main aspects of the livelihood damage caused by the tropical storms of the period 2008–2013 in three coastal communes of the Ky Anh District of the Ha Tinh Province in Central Vietnam. The communes were selected because the location of their coastal line is perpendicular to the storm itself, which made them prone to damage. The effects of increasingly extreme weather conditions on three communities in an area most affected by storms and floods on the local residents and their responses to these changing environmental conditions are analyzed and assessed. The results of questionnaires completed by randomly selected local inhabitants of these communes show that storms and related hazards such as flood, sea level rise and heavy rain are perceived as the most impacting climate change intensified phenomena on agriculture and aquaculture, livestock, household property and income. Opinions and measured data provided by the commune and district authorities allow estimating the total direct cost of the tropical storm at 1.56 million $US (The used conversion rate VND/$US is 21,730 when the research was conducted in 2014) during the period 2008–2013. The long-term costs of adaptation and social impact measures will be significantly higher. Details of the monetary figures allow identifying the physical and natural capital of the area as being most affected by the storm. Trend and cost analysis show that the total financial support for hazard prevention and management during 2014–2019 is estimated at 1.19 up to 1.32 million $US. Local stakeholders indicate that climate change adaptation should not be limited to technical measures such as strengthening dikes, but also should target planting protection forests and mangroves and land use planning. Financial support for the relocation policy, stakeholder involvement and integrating climate change adaptation in both the socioeconomic development master plan and local land use planning are also of importance. 相似文献