The uptake of hydrogen fluoride by a forest

A mathematical model of hydrogen fluoride (HF) deposition and accumulation of fluoride in a Eucalyptus rostrata forest has been developed. The model is based on tree physiology and meteorological principles. The data base for the model was derived from a literature survey of the physiological characteristics of E. rostrata and similar eucalyptus species and from current knowledge of meteorological processes in plant canopies.Comparison of the mathematical simulations with measurements in the vicinity of a source of HF (an aluminium reduction plant) shows that (1) the pattern of seasonal fluoride accumulation in leaves agrees with that seen in the field, and (2) the vertical pattern of accumulation inside tree leaves agrees with field observations. The simulations indicate that 50% of the released HF was deposited within 81 km of the source and that the concentration of HF in the air 81 km from the source was reduced to 2% of the concentration 1 km from the source. However, a very large forest area (20 600 km²) was required to achieve these reductions.     

Field Exposure Study of Polylactic Acid (PLA) Plastic Films in the Banana Fields of Costa Rica

For use by the banana industry of Costa Rica, polylactic acid (PLA) plastic ropes and banana finger shrouds must remain operational for 14 to 16 weeks, and they also must be able to break down in the soil after serving their purposes. The banana field at La Rebusca Farm (Costa Rica) and the experiment station at University of Costa Rica were selected for a field exposure study of Cargill EcoPla Generation II (GII) and Cargill EcoPla monolayer (Ca-I) PLA films. The average monthly temperature, relative humidity, and cumulative rainfall of the La Rebusca Farm and the University of Costa Rica site were 26 and 22°C, 92 and 84%, and 352 and 177 in., respectively. The PLA plastic films at the La Rebusca Farm lost their mechanical properties earlier than at the University of Costa Rica site because of the higher temperature and relative humidity of the banana farm. The Ca-I film meets the 14-week operational time frame and it is recommended for further studies as ropes and banana shrouds.     

Trace metal residues in tissues of two crustacean species from the Bahia Blanca Estuary,Argentina

Trace metals (total mercury, cadmium and zinc) were studied in several tissues of the edible shrimps Pleoticus muelleri and Artemesia longinaris from the Bahía Blanca estuary, Argentina. The digestive gland was shown to be the main organ in which metals accumulate, followed by the stomach-alimentary canal and abdominal muscle.The metal contents found in the present study largely exceeded those of the same species caught from the Argentine Sea. Mercury concentrations increased proportionally to the total length of the shrimps studied. Only little variation in metal concentrations among individuals seemed to exist.Finally, the usefulness of these species as bioindicators of trace metal pollution in the Bahía Blanca estuary is discussed.     

Distribution of Heavy Metals in Surface Sediments from an Antarctic Marine Ecosystem

The concentrations of lead, cadmium, copper,chromium, iron, manganese and zinc in surfacesediments collected from Potter Cove, in the 25de Mayo Island (King George Island), Antarctica, andits drainage basin, were measured by atomic absorptionspectroscopy. The obtained results were use todetermine the areal and vertical distribution of themetals of in the Cove and potential sources of thesemetals to this environment. The geochemical datasuggest that most of the metals found in Potter Coveconstitute a redistribution of autochthonous materialswithin the ecosystem. Therefore, the metalconcentrations can be considered to be present atnatural background levels in surface sediments.     

Mercury bioaccumulation in organisms from three Puerto Rican estuaries

We analyzed mercury levels in shrimp (Palaemonetes sp.), Blue Crabs (Callinectes sp.), fish (Tarpon Megalops atlantica and Tilapia Tilapia mossambica), lizards (Ameiva exsul), Cattle Egret (Bubulcus ibis) and Moorhen (Gallinula chloropus) in three estuaries in Puerto Rico in 1988. There were no quantifiable concentrations greater than the method detection limit of mercury in shrimp, crabs and lizards from any site. Mercury levels were also below detection limits in Tilapia, except for specimens collected at Frontera Creek, allegedly contaminated with mercury. However, mercury levels ranged from 92–238 g/kg (wet weight) in Tarpon, a predaceous fish that feeds on smaller fish. Few of the birds had detectable levels of mercury. Our results indicate relatively low concentrations of mercury in biota collected in all of the three estuaries at most trophic levels, although 10 of 12 Tarpon fillet samples from Frontera had detectable mercury compared to 3 of 12 fillet samples for the other two lagoons.This project was partially funded by an EPA consent decree (Dynamac, Inc.) and NIEHS grant (ESO 5022) to EOSHI.     

Physical and chemical characterisation of metal finishing industrial wastes

In EU countries approximately 150,000 tons/year of galvanic sludges are generated by 4000 industrial units from the corresponding wastewater treatment plants. These sludges are generally classified as hazardous (European Waste Catalogue as adopted in Council Decision 2000/532/CE and as amended by Decisions 2001/118/EC, 2001/119/EC and 2001/573/CE), basically due to the presence of heavy metals. This work attempts to better understand the physical and chemical characteristics of these sludges, by studying 39 samples collected in different Portuguese industries that should represent all kinds of similar wastes independent of their place of generation. Chemical composition and leaching characteristics are given, together with density, grain size distribution, and specific surface area values. Statistical analysis was used for grouping the wastes according to chemical parameters, which might be useful to predict potential reuse as raw materials for different applications.     

Operational change as a profitable cleaner production tool for a brewery

The development and implementation of new procedures and operational changes in the production processes constitutes a powerful tool for the practical application of Cleaner Production in industries. In this work an operational change (new procedure) was developed for the elaboration of a type of beer which uses sugar as malt adjunct. The change consists in processing separately the three main components of the beer wort: malt extract, sugar and water, and use them properly in a different sequence than that used up to date in the traditional process. The new procedure was successfully assayed on industrial scale in Tínima brewery, located in Camagüey, Cuba, obtaining a good quality beer, technological and economical advantages with benefits for the environment, registering significant savings in energy (49%), sugar (4%), water (7%) and caustic soda (3%) consumption; and diminishing the surplus hot water (74%), waste generation (11%) and greenhouse gases emission (21%). Beer production capacity is increased also almost three times. With the application of the new technology to the Cuban beer type of 8 °P, it was achieved a total saving of US$ 481.83/1000 hL of beer produced.     

Water security as a challenge for the sustainability of La Serena-Coquimbo conurbation in northern Chile: global perspectives and adaptation

The aim of this study is to address the problem of balance between water scarcity and sustainability, which are the key components of water security of cities located in arid lands, particularly those under constant expansion and population growth. In this paper, we have highlighted the problem of water security for the sustainability of the La Serena-Coquimbo conurbation (LSCC). The coastal LSCC is located at the outlet of the Elqui River basin, in the southern edge of the Chilean Atacama Desert. We have analyzed the available information including drinking water production and consumption data, groundwater levels, precipitation data and population data. Between the years 2009 and 2013 the total water consumption for the area has significantly increased. On the other hand, there has been a significant decrease trend in the precipitations and the groundwater levels show a decrease of about 30 m between the years 1995 and 2014. In a few years, this urban area could face a general water scarcity problem if the drought conditions remain unchanged and if the water demand trend for the agricultural, mining and drinking water continues its increasing. The cities located in the arid lands are particularly vulnerable to water scarcity because their populations are highly concentrated and requires reliable supplies of water to make possible human and economic activities. We discuss how adaptation of the arid land urban areas to water scarcity requires a range of solutions, including economic incentives, regulatory measures, and technology.