红外热成像技术检测发电机铁心故障的研究

为解决发电机定子铁心片间绝缘的损坏点定位的问题,采用红外热成像检测技术对发电机定子铁心损耗进行缺陷点定位及测试数据分析。结果表明:红外热成像检测技术相比于传统的测温方法更能直观、准确地反映定子铁心存在的局部微小缺陷点,可在缺陷定子铁心的检修试验中广泛使用。     

防闪络绝缘护套对鸟粪闪络防护效果的分析

作为一种新型鸟粪闪络防护措施,防闪络绝缘护套是通过降低绝缘子所承受的电压达到防护效果的,这种方法虽然在理论上可行,但其实际效果却还没有得到有效验证。因此,通过对鸟粪闪络的机理进行分析,建立架空输电线路鸟粪闪络的仿真模型和试验平台,验证防闪络绝缘护套对鸟粪闪络的防护效果。结果表明:只要厚度足够,绝缘护套能有效地阻止鸟粪污染造成的线路闪络事故的发生。     

典型湖库富营养化的模糊综合评价研究

随着氮磷等营养盐类的不断排入湖库中,导致了水体的富营养化,使得水体透明度下降,产生异味,对人们的身体健康造成威胁。通过采用合适的水体富营养化评价模型,可以对水体的污染现状进行评价,得出正确的结论,以便采用适当的处理方式及时处理富营养化状况,减少对水环境和人体健康的危害。采用模糊综合评价法,将评价指标进行层次分析,并根据指标的相互关系,确定了各指标的权重,建立了模糊综合评价的数学模型。最终根据建立的评价指标体系、确定的评价标准和实测的湖库（巢湖、洱海和微山湖等）水质资料,得到了我国典型湖库的富营养化评价结论。评价结果与实际状况相吻合,说明该模型适合广泛应用     

Geosmin degradation by seasonal biofilm from a biological treatment facility

Introduction  

Initial geosmin degradation was closely related to water temperature and natural geosmin concentration of sampling environment. Here, for the first time, we evaluated the biodegradation of geosmin by microorganisms in biofilm from biological treatment unit of actual potable water treatment plant.     

安宁河上游冷渍沟泥石流特征及其发展趋势

冷渍沟是安宁河上游左岸的一级支沟,沟内发育了一大型滑坡 碎屑流,为后续泥石流活动提供充足的松散物质来源。为了研究冷渍沟泥石流的危害特征,在野外调查和实地勘测的基础上,分析了泥石流的形成背景条件及其特征,探讨了泥石流的发展趋势,提出了相应的泥石流防治对策。研究表明,冷渍沟泥石流属于过渡性（亚粘性）高频大规模泥石流,泥石流成灾速度快,危害严重;百年一遇的泥石流容重为21 t/m3,五十年一遇的泥石流容重为20 t/m3,二十年一遇害泥石流容重为19 t/m3,相应的峰值流量分别为12768、8171和3818 m3/s。在常态下,冷渍沟泥石流的发生频率和规模会逐渐减小;但如果近期遭遇强震或者暴雨,一旦滑坡失稳堵塞沟道,将会暴发大规模泥石流,很容易堵断安宁河,对上下游造成严重危害。因此,建议在该流域布设必要的泥石流防治工程;同时加强对沟道两岸和滑坡稳定性监测,做好泥石流发生的监测预警工作     

Removal of Pb2+ from aqueous solution by adsorption on chemically modified muskmelon peel

A cost-effective biosorbent was prepared by a green chemical modification process from muskmelon peel by saponification with alkaline solution of Ca(OH)₂. Its adsorption behavior for lead ions was investigated and found to exhibit excellent adsorption properties. Results showed that the optimal equilibrium pH range for 100 % adsorption is from 4 up to 6.4. Adsorption equilibrium was attained within 10 min. The adsorption process can be described well by Langmuir model and pseudo-second-order kinetics equation, respectively. The maximum adsorption capacity for lead ions was found to be 0.81 mol/kg. Pectic acid contained in the muskmelon peel is the main factor responsible for the uptake of lead ions onto the gel, and the chemical modification process presented in this study can be assumed effective to prepare other similar biomaterials. The large adsorption capacity and the fast adsorption rate indicated that chemically saponified muskmelon peel gel in present study has great potential to be used as a cost-effective adsorbent for the removal of lead ions from the water.     

铜-胺改性ZSM-5吸附剂的制备及其对NOx的净化机理

以ZSM-5分子筛粉体为原料,成型后负载铜盐和有机胺改性,制备出一种高效脱除氮氧化物的吸附剂。通过改变铜盐、有机胺的含量以及铜盐活化温度使吸附剂的性能得到优化,在实验条件下（NO：初浓度1000mg／m^3,气流2．7L／min）床层对NO2动态吸附的透过时间由改性前的3min提高到90min,并使NO气体的释放得到有效减缓。通过动态吸附实验研究了NO释放时间在负载前后的变化,通过X射线光电子能谱（XPS）和红外分析（FTIR）研究了吸附剂表面铜元素、有机基团等在吸附前后的变化规律,提出了可能的净化机理。     

Boron sorption from aqueous solution by hydrotalcite and its preliminary application in geothermal water deboronation

Hydrotalcite and its calcination product were used to treat pure water spiked with various concentrations of boron and geothermal water containing boron as a major undesirable element. The kinetics process of boron sorption by uncalcined hydrotalcite is controlled by the diffusion of boron from bulk solution to sorbent-solution boundary film and its exchange with interlayer chloride of hydrotalcite, whereas the removal rate of boron by calcined hydrotalcite rests with the restoration process of its layered structure. The results of isotherm sorption experiments reveal that calcined hydrotalcite generally has much stronger ability to lower solution boron concentration than uncalcined hydrotalcite. The combination of adsorption of boron on the residue of MgO–Al₂O₃ solid solution and intercalation of boron into the reconstructed hydrotalcite structure due to “structural memory effect” is the basic mechanism based on which the greater boron removal by calcined hydrotalcite was achieved. As 15 geothermal water samples were used to test the deboronation ability of calcined hydrotalcite at 65 °C, much lower boron removal efficiencies were observed. The competitive sorption of the other anions in geothermal water, such as HCO₃ ^?, SO₄ ^2?, and F^?, is the reason why calcined hydrotalcite could not remove boron from geothermal water as effectively as from pure boron solution. However, boron removal percents ranging from 89.3 to 99.0 % could be obtained if 50 times of sorbent were added to the geothermal water samples. Calcined hydrotalcite is a good candidate for deboronation of geothermal water.     

Removal of Cu, Zn, and Cd from aqueous solutions by the dairy manure-derived biochar

Purpose

Biochar derived from waste biomass is now gaining much attention for its function as a biosorbent for environmental remediation. The objective of this study was to determine the effectiveness of biochar as a sorbent in removing Cd, Cu, and Zn from aqueous solutions.

Methods

Biochar was produced from dairy manure (DM) at two temperatures: 200°C and 350°C, referred to as DM200 and DM350, respectively. The obtained biochars were then equilibrated with 0–5 mM Cu, Zn or Cd in 0.01 M NaNO₃ solution for 10 h. The changes in solution metal concentrations after sorption were evaluated for sorption capacity using isotherm modeling and chemical speciation Visual MINTEQ modeling, while the solid was collected for species characterization using infrared spectroscopy and X-ray elemental dot mapping techniques.

Results

The isotherms of Cu, Zn, and Cd sorption by DM200 were better fitted to Langmuir model, whereas Freundlich model well described the sorption of the three metals by DM350. The DM350 were more effective in sorbing all three metals than DM200 with both biochars had the highest affinity for Cu, followed by Zn and Cd. The maximum sorption capacities of Cu, Zn, and Cd by DM200 were 48.4, 31.6, and 31.9 mg g^?1, respectively, and those of Cu, Zn, and Cd by DM350 were 54.4, 32.8, and 51.4 mg g^?1, respectively. Sorption of the metals by the biochar was mainly attributed to their precipitation with PO ₄ ^3? or CO ₃ ^2? originating in biochar, with less to the surface complexation through –OH groups or delocalized π electrons. At the initial metal concentration of 5 mM, 80–100 % of Cu, Zn, and Cd retention by DM200 resulted from the precipitation, with less than 20 % from surface adsorption through phenonic –OH complexation. Among the precipitation, 20–30 % of the precipitation occurred as metal phosphate and 70–80 % as metal carbonate. For DM350, 75–100 % of Cu, Zn, and Cd retention were due to the precipitation, with less than 25 % to surface adsorption through complexation of heavy metal by phenonic –OH site or delocalized π electrons. Among the precipitation, only less than 10 % of the precipitation was present as metal phosphate and more than 90 % as metal carbonate.

Conclusions

Results indicated that dairy manure waste can be converted into value-added biochar as a sorbent for sorption of heavy metals, and the mineral components originated in the biochar play an important role in the biochar's high sorption capacity.     

Comparative and competitive adsorption of Cr(VI), As(III), and Ni(II) onto coconut charcoal

This study evaluates the behavior of coconut charcoal (AC) to adsorb Cr(VI), As(III), and Ni(II) in mono- and multicomponent (binary and ternary) systems. Batch experiments were carried out for mono- and multicomponent systems with varying metal ion concentrations to investigate the competitive adsorption characteristics. The adsorption kinetics followed the mechanism of the pseudo-second-order equation in both single and binary systems, indicating chemical sorption as the rate-limiting step of adsorption mechanism. Equilibrium studies showed that the adsorption of Cr(VI), As(III), and Ni(II) followed the Langmuir model and maximum adsorption capacities were found to be 5.257, 0.042, and 1.748 mg/g, respectively. In multicomponent system, As(III) and Ni(II) adsorption competed intensely, while Cr(VI) adsorption was much less affected by competition than As(III) and Ni(II). With the presence of Cr(VI), the adsorption capacities of As(III) and Ni(II) on AC were higher than those in single system and the metal sorption followed the order of Ni(II)?>?As(III)?>?Cr(VI). The results from the sequential adsorption–desorption cycles showed that AC adsorbent held good desorption and reusability.