危险与可操作性分析实际运用中的问题

对危险与可操作性分析(HAZOP)方法在实际运用中存在着诸多问题予以分析总结,并对这些问题的解决进行简要的说明.     

基于MM的建筑施工企业现场安全管理量化分析

为有效提高建筑施工企业现场安全管理效率,依据危险源对安全管理影响的重要性,探讨建筑施工现场有效的安全管理方法。结合相关建筑安全法律法规,总结出建筑施工现场常见的危险源;采用格雷厄姆评价法(LECD)进行问卷调查,确定出危险源的风险等级;引入测量模型方程构建路径分析图,并以路径系数对建筑施工现场安全管理的各个阶段进行量化分析。将测量模型应用到实际建筑工程项目安全管理量化分析中,结果表明:危险源与安全管理的相关性较强,建筑施工现场各个阶段危险源的管理侧重点不同;施工现场安全管理各个阶段的风险等级大多为一般危险或显著危险,均不能忽视,其中消防材料管理的风险等级最高,为3.09,与现场实际相符,说明该方面是现场安全管理的最薄弱环节,故应制定相应的措施加强其安全管理。     

基于正态模糊数的区域土壤重金属污染综合评价

针对土壤重金属污染评价的不确定性,采用模糊数对其进行描述.在土壤重金属含量满足正态或对数正态分布检验基础上,构建了基于正态模糊数的区域土壤重金属污染综合评价方法.以江苏省T市为例进行评价方法实证分析,结果表明:除As出现轻度污染外,其他重金属含量均处于清洁水平,其中Hg、Cu、Zn处于局部轻度污染状态,各重金属富集污染程度排序为:As ＞Cu＞ Hg＞ Zn＞ Ni＞ Cr＞ Cd＞ Pb,研究区土壤重金属污染综合评价为清洁水平,As、Hg、Cu 、Zn应该作为相关部门污染控制的重点对象.与传统的三角模糊数方法的评价结果相比,该方法能更为精确的描述不同重金属含量的隶属度大小,评价结果所包含的信息更为全面、准确.     

西成客运专线西安至江油段生态景观评价研究

为了对生态环境质量进行综合评价,运用环境景观格局综合评价方法,对西成客运专线西安至江油段铁路段划分出9个不同的生态环境类型。西城客运专线铁路的修建对沿线的耕地和林地影响较大,对水地和草地的影响较小,是西成客运专线施工和后期生态恢复中主要评价和研究的内容。环境景观综合评价表明,横贯中国南北自然地理分界线秦岭的西城客运专线的修建对沿线景观环境影响程度较轻、铁路与沿线景观较为协调,表明西城客运专线设计比较合理。同时,评价的结果也说明,采取恰当的工程措施可以最大限度地减小对自然生态环境的破坏。     

Studies on catalytic reduction of nitrate in groundwater

Catalytic reduction of nitrate in groundwater by sodium formate over the catalyst was investigated. Pd-Cu/γ-Al₂O₃ catalyst was prepared by impregnation and characterized by brunauer-emmett-teller (BET), inductive coupled plasma (ICP), X-ray diffraction (XRD), transmission electron microscopy (TEM) and energy dispersive X-ray (EDX). It was found that total nitrogen was effectively removed from the nitrate solution (100 mg/L) and the removal efficiency was 87%. The catalytic activity was affected by pH, catalyst amount used, concentration of sodium formate, and initial concentration of nitrate. As sodium formate was used as reductant, precise control in the initial pH was needed. Excessively high or low initial pH (7.0 or 3.0) reduced catalytic activity. At initial pH of 4.5, catalytic activity was enhanced by reducing the amount of catalyst, while concentrations of sodium formate increased with a considerable decrease in N₂ selectivity. In which case, catalytic reduction followed the first order kinetics.     

中国南方山地“砂石化”及控制对策—以云南小江流域为例

“砂石化”是我国南方山地河谷区在崩塌、滑坡、泥石流发生发展过程中所伴生的一种灾变现象，视其地理景观，酷似我国西北地区的戈壁荒漠。作者以云南小江流域为例，通过多年的实地考察研究，从理论与实践的结合上，就“砂石化”的形成过程、类型特征和控制对策等进行剖析，以期引起人们对此类灾变现象的关注。     

产业转型对中国资源型城市增长与收缩演变轨迹的影响机制

中国正进入高质量发展阶段,资源型城市的增长与收缩面临着内外部条件的系统性重构,资源型城市在转型发展过程中如何摆脱“矿竭城衰”的历史宿命,实现城市人口的正增长,目前尚缺乏经验证据。本文采用2010—2020年116个资源型城市的截面与面板数据,定量刻画了资源型城市增长与收缩的演变轨迹,并实证考察了产业结构转型对人口增减变化的相关影响机制。研究发现：中国六成以上的资源型城市在研究期内表现为收缩状态,呈现出“一带两片”的空间分布格局;产业结构合理化和高级化在短期内均对资源型城市的人口增长表现为挤出效应,长期来看,产业结构合理化的影响转为正向,产业结构高级化的补偿效应暂未显现;产业结构多样化在短期内可促进资源型城市人口的增长,但长期来看并不显著。基于此,资源型城市的转型发展需要以提高产业结构合理化水平为重要突破口,以产业结构高级化为长期主线,基于地方比较优势实施产业延伸与产业更新并行战略,构建多元化的产业体系,不同类型、不同发展阶段资源型城市的产业结构转型应强调战略差异化。     

Application of powdered activated carbon coating to fabrics in a hybrid filter to enhance mercury removal

Elemental mercury(Hg0) is predominant constituent of flue gas emitted from coal-fired power plants. Adsorption has been considered the best available technology for removal of Hg0 from flue gas. However, adsorbent injection increases the amount of ash generated. In the present study, powdered activated carbon(PAC) was coated on polytetrafluoroethylene/glass fiber filters to increase Hg0 removal while concurrently reducing the amount of ash generated. The optimal PAC coating rate was determined in laboratory experiments to ensure better Hg0 removal with low pressure drop. When PAC of particle size less than 45 μm was used, and the areal density was 50 g/m2, the pressure drop remained under 30 Pa while the Hg0 removal efficiency increased to 15.8% from4.3%. The Hg0 removal efficiency also increased with decrease in filtration velocity. The optimal PAC coating rate was applied on a hybrid filter(HF), which was combined with a bag filter and an electrostatic precipitator in a single chamber. Originally designed to remove fine particulates matter, it was retrofitted to the flue gas control device for simultaneous Hg0 removal. By employing the PAC coating, the Hg removal efficiency of the HF increased to 79.79% from 66.35%. Also, a temporary reduction in Hg removal was seen but this was resolved following a cleaning cycle in which the dust layer was removed.     

The key role of inoculated sludge in fast start-up of sequencing batch reactor for the domestication of aerobic granular sludge

Two types of inoculated sludges, granular sludge that had been stored at-20°C and activated sludge, were investigated for the domestication of aerobic granular sludges(AGSs in sequencing batch reactors(SBRs). The results showed that using the stored granular sludge as inoculation sludge could effectively shorten the domestication time of AGS and yielded mature granular sludge after 22 days of operation. The AGS domesticated by stored granular sludge had better biomass and sedimentation properties; its MLSS and SVI reached8.55 g/L and 35.27 mL/g, respectively. The removal efficiencies for chemical oxygen demand(COD), ammonium nitrogen(NH_4~+-N) and total phosphorus(TP) reached 90.76%, 97.39% and 96.40%, respectively. By contrast, 54 days were needed to obtain mature granules using activated sludge. The microbial community structure was probed by using scanning electron microscopy(SEM) and high-throughput sequencing. The results showed that the diversity of the microbial community in mature granules was reduced when stored granular sludge rather than activated sludge was employed as inoculation sludge, and the dominant microbes were changed. The dominant species in mature granules domesticated using stored granular sludge were Zoogloea, Acidovorax and Tolumonas at the genus classification level, while the dominant species were Zoogloea and TM7-genera in granules developed from activated sludge.