Pesticide removal from container nursery runoff in constructed wetland cells

The increased use of pesticides by container nurseries demands that practices for removal of these potential contaminants from runoff water be examined. Constructed wetlands may be designed to clean runoff water from agricultural production sites, including container nurseries. This study evaluated 14 constructed wetlands cells (1.2 by 4.9 m or 2.4 by 4.9 m, and 30 or 45 cm deep) that collected pesticide runoff from a 465-m2 gravel bed containerized nursery in Baxter, TN. One-half of the cells were vegetated with bulrush, Scirpus validus. The cells were loaded at three rates or flows of 0.240, 0.120, and 0.060 m3 d(-1). Herbicides-simazine (Princep) [2-chloro-4,6-bis(ethylamino)-s-triazine] and metolachlor (Pennant) [2-chloro-N-(2-ethyl-6-methylphenyl)-N-2-methoxy-1-methylethyl-acetamide] -were applied to the gravel portion of the container nursery at rates of 4.78 and 239 kg ha(-1), respectively, 9 July 1998, and at rates of 2.39 and 1.19 kg ha(-1), respectively, 17 May 1999. Pesticides entering the wetland and wetland cell water samples were analyzed daily to determine pesticide removal. At the slower flow rate, which corresponds to lower mass loading and greater hydraulic retention times (HRTs), a greater percentage of pesticides was removed. During the 2-yr period, cells with plants removed 82.4% metolachlor and 77.1% simazine compared with cells without plants, which removed 63.2% metolachlor and 64.3% simazine. At the lowest flow rate and mass loading, wetland cells removed 90.2% metolachlor and 83% simazine. Gravel subsurface flow constructed wetlands removed most of the pesticides in runoff water with the greatest removal occurring at lower flow rates in vegetated cells.     

Effect of formulation on the behavior of 1,3-dichloropropene in soil

The fumigant 1,3-dichloropropene (1,3-D) has been identified as a partial replacement for methyl bromide (CH3Br) in soil fumigation. 1,3-Dichloropropene is formulated for soil fumigation as Telone II (Dow AgroSciences, Indianapolis, IN) for shank application and as an emulsifiable concentrate (EC) (Telone EC or InLine; Dow AgroSciences) for drip application. This study investigated the effect of formulation on the phase partitioning, transformation rate, and volatilization of 1,3-D isomers. Air-water partitioning coefficients (K(H)) were slightly higher for Telone II than for Telone EC, presumably due to the higher apparent water solubility of the EC formulation. Sorption of 1,3-D isomers in two soils was not affected by formulation. Formulation had no significant effect on the rate of 1,3-D transformation in water or soil. In general, differences in the rate of 1,3-D transformation and phase partitioning due to formulation as Telone II or Telone EC were very small. Thus, the effect of formulation on 1,3-D fate may be ignored in transformation and phase partition of 1,3-D in water and soil. Packed soil columns without plastic tarp indicated that with relatively shallow subsurface (10 cm) drip application of Telone EC, emission of 1,3-D isomers was more rapid and produced greater maximum instantaneous flux than deeper (30 cm) shank injection of Telone II. Both application methods resulted in the same cumulative emissions for both isomers, 45% for (E)-1,3-D and approximately 50% for (Z)-1,3-D. These results suggest that for drip application of fumigants to be effective in reducing emissions, the fumigant must be applied at sufficient depths to prevent rapid volatilization from the soil surface if the water application rate does not sufficiently restrict vapor diffusion.     

Pure-culture and enzymatic assay for starch-polyethylene degradable plastic biodegradation withStreptomyces species

Eleven starch-polyethylene degradable plastic films were prepared from masterbatches from Archer Daniels Midland Inc. (ADM), EcoStar Inc. (SLS), and Fully Compounded Plastic Inc. The biodegradability of initial and 70°C heat-treated materials was determined using a pure-culture assay withStreptomyces badius 252,S. setonii 75Vi2, orS. viridosporus T7A or without bacterial culture (control). Films were treated with 10-foldS. setonii culture concentrates and compared with inactive enzyme controls. Changes in each films mechanical property, molecular weight distribution, and Fourier-transformed infrared spectrum (FT-IR) were determined, and results were evaluated for significant differences by analysis of variance. Cell mass accumulation on each film was quite pronounced. In pure-culture studies, biodegradation was demonstrated for ADM-7 and SLS-2 initial films and for ADM-6 heat-treated films, whereas after 3-week treatment with activeS. setonii culture concentrates (enzyme assay), reductions in mechanical properties and changes in FT-IR spectrum were illustrated by all the films except SLS-2. Thus the absence of biofilm formation on the film surface permitted enzymatic attack of the materials. Furthermore, inhibition of chemical oxidative degradation in the pure-culture assay was demonstrated for ADM-11, SLS-5, and SLS-10 initial materials and for ADM-4, ADM-7, SLS-8, and SLS-10 heat-treated films. These data suggest that biological and chemical degradation were directly affected by the reduction in oxygen tension on the plastic film surface due to cell mass accumulation. This same phenomenon could be the cause for slow degradation rates in nature.Journal Paper No. J-15061 of the Iowa Agriculture and Home Economics Experiment Station, Ames, Iowa. Project Nos. 0178 and 2889.     

CLASSIFICATION OF ENVIRONMENTAL HYDROLOGIC BEHAVIORS IN THE NORTHEASTERN UNITED STATES1

ABSTRACT: Environmental response to acidic deposition results from movement of water through the ecosystem. As a part of the environmental studies for acidic deposition sponsored by the U.S. Environmental Protection Agency (EPA), hydrologic classification based on regional baseflow properties was done. To obtain the amount of baseflow, a flow separation method was developed based on the division of streamflows into “baseflow” and “other” runoff sources. Because of the differences in the flow paths and exposure duration, the two components were assumed to be associated with distinct geo-chemical responses. Individual annual hydrographs were analyzed using 31 separation slopes to determine the amount of baseflow. A total of 1575 streamflow stations in the Northeastern U.S. were analyzed through the access of a long-term daily stream-flow data base. An interactive computer program was developed to obtain baseflow properties and other hydrologic characteristics of each station. The output from this analysis was used to perform cluster analysis to classify streamflow behaviors. The clustering output showed different regional boundaries than those currently used by the EPA for water quality studies.     

OPTIMIZATION OF THE HYDROMETRIC NETWORK OPERATION BY A HEURISTIC TRAVELING SALESMAN ALGORITHM1

ABSTRACT: The problem of determining the optimal route to operate a network of hydrometric gauges within a given area is formulated and solved by an original heuristic traveling salesman algorithm. The algorithm used for solving the problem takes into account the variation of station service time, the eight-hour maximum working day, existence of more than one home base, and the budget constraint. The traveling salesman algorithm is used to solve the optima! assignment problem within a one-day time limit, locating a starting base, stations to visit, and the closest home base. The ending base for the previous day becomes the starting base for the next day, and the assignment procedure is repeated. The computation proceeds from day to day, until all the stations in the considered region are serviced. The solution obtained presents the optimal route to operate a network of hydrometric gauges. The optimization procedure has been applied to the Dauphin hydrometric field area in Manitoba.     

Prospects of DLC coating as environment friendly surface treatment process

After first commercialization in 90's, the applications of diamond-like carbon (DLC) have been significantly expanded to tool, automobile parts, machineries and moulds to enhance wear and friction properties. Although DLC has many advantages like high hardness, low friction electrical insulating and chemical stability and has the possible market, its application in the field is still very limited due to the gaps of understanding between end-user and developer of its advantage of costing. Recently, one of the most popular issues in the surface modification is providing the long lasting super-hydrophilic or -hydrophobic properties on the material surface for the outdoor usage. A lot of material loss is caused due to water corrosion which has to do with the flow and contacts of water like fuel cell separator and air conditioner parts. The consequence of development of functional surface based on the hydrophilic or hydrophobic design for the important parts would be really helpful for materials to be cleaner and more energy effective. Here, we first reviewed the DLC technology and then examined the kind of surface modification as well as its merits and disadvantage. We also looked at how we can improve super-hydrophilic and super hydrophobic for the DLC coating layer as well as current status of technology and arts of DLC. In the end, we would like to suggest it as one of the environmental friendly industrial technology.     

改善微电网电能质量的分层控制策略研究

微电网技术具有许多优点,但分布式电源的不稳定性将导致微电网不易运行控制,对微电网的电能质量产生不利影响。针对此问题,提出了分层控制策略,以改善和提高微电网的电能质量。分层控制包含上下 2 层,通过上层将控制信息发送到下层实现。其中,初级控制采用下垂控制方法,提出了基于电压外环、电流内环和功率环的反馈控制器。二级控制(secondarycontrol)通过向初级控制(primary control)反馈二级控制后控制逆变器的输出电压幅值和频率,使之重新达到平衡,实现系统运行的稳定性。利用 Matlab/simulink 仿真结果表明:该分层控制策略对改善微电网电能质量是有效的。     

Robust Prioritization of Climate Change Adaptation Strategies Using the VIKOR Method with Objective Weights

This study proposes a robust prioritization framework for climate change adaptation strategies under uncertain climate change scenarios, using the VIseKriterijumska Optimizacija I Kompromisno Resenje (VIKOR) method, a multi‐criteria decision‐making approach, together with the Shannon entropy‐based weights. The VIKOR method allows us to find a compromise solution between two decision strategies of maximizing group utility and minimizing individual regret, and the Shannon entropy is used to determine objective weights among multiple climate change scenarios. The proposed methodology was applied to the problem of selecting locations of subwatersheds for reusing treated wastewater (TWW) in a Korean urban watershed. Selected based on the sustainability concept, hydro‐environmental and socioeconomic indicators were used to evaluate the sustainability of TWW reuse under multiple climate change scenarios, using the hydrologic simulation model results and statistical data. Finally, sustainability scores under multiple scenarios were aggregated using the VIKOR together with the Shannon entropy‐based weights for the robust prioritization of adaptation strategies. According to the different levels of regret aversion or affinity, our results for water quality showed different sets of adaptation strategies as the best options, suggesting that our framework would help stakeholders seeking the robust options considering both the utility and regret.