The use of nanoparticles in polymeric and ceramic membrane structures: Review of manufacturing procedures and performance improvement for water treatment

Membrane separations are powerful tools for various applications, including wastewater treatment and the removal of contaminants from drinking water. The performance of membranes is mainly limited by material properties. Recently, successful attempts have been made to add nanoparticles or nanotubes to polymers in membrane synthesis, with particle sizes ranging from 4 nm up to 100 nm. Ceramic membranes have been fabricated with catalytic nanoparticles for synergistic effects on the membrane performance. Breakthrough effects that have been reported in the field of water and wastewater treatment include fouling mitigation, improvement of permeate quality and flux enhancement. Nanomaterials that have been used include titania, alumina, silica, silver and many others. This paper reviews the role of engineered nanomaterials in (pressure driven) membrane technology for water treatment, to be applied in drinking water production and wastewater recycling. Benefits and drawbacks are described, which should be taken into account in further studies on potential risks related to release of nanoparticles into the environment.     

A contribution of brown carbon aerosol to the aerosol light absorption and its radiative forcing in East Asia

Brown carbon aerosols were recently found to be ubiquitous and effectively absorb solar radiation. We use a 3-D global chemical transport model (GEOS-Chem) together with aircraft and ground based observations from the TRACE-P and the ACE-Asia campaigns to examine the contribution of brown carbon aerosol to the aerosol light absorption and its climatic implication over East Asia in spring 2001. We estimated brown carbon aerosol concentrations in the model using the mass ratio of brown carbon to black carbon (BC) aerosols based on measurements in China and Europe. The comparison of simulated versus observed aerosol light absorption showed that the model accounting for brown carbon aerosol resulted in a better agreement with the observations in East Asian-Pacific outflow. We then used the model results to compute the radiative forcing of brown carbon, which amounts up to ?2.4 W m^?2 and 0.24 W m^?2 at the surface and at the top of the atmosphere (TOA), respectively, over East Asia. Mean radiative forcing of brown carbon aerosol is ?0.43 W m^?2 and 0.05 W m^?2 at the surface and at the TOA, accounting for about 15% of total radiative forcing (?2.2 W m^?2 and 0.33 W m^?2) by absorbing aerosols (BC + brown carbon aerosol), having a significant climatic implication in East Asia.     

Seasonal characteristics of haze observed by continuous visibility monitoring in the urban atmosphere of Kwangju, Korea

Continuous visibility monitoring has been carried out inKwangju, Korea since May 1999. The total light extinctioncoefficient b _ext measured by a transmissometer andreveals seasonal trends in urban visual air quality,especially under hazy conditions with a visual range of lessthan 15 km. Seasonal atmospheric visibility under lowrelative humidity during the winter was observed to be betterthan during any other seasons. Summertime visibility wasseverely degraded due to highly increased light scattering byhygroscopic particles under high humidity atmosphericconditions. Visibility during spring and fall was alsomoderate. However, yellow sand in spring caused the lowestvisibility conditions over the measurement area for a fewdays. With continuous monitoring using the transmissometer,the daily average seasonal visual range was measured to be13.1, 9.2, 11.0, and 13.9 km in spring, summer, falland winter, respectively. Under the atmospheric humiditycondition less than 60%, visual range was observed tobe 16.1, 13.9, 15.1, and 16.6 km in spring, summer,fall, and winter, respectively. The mean light extinctionbudget by sulfate and nitrate aerosols was determined to bethe highest value of 63.71% during the summer and thelowest value of 27.08% during spring. During the `yellow sand dust' period, a mean light extinction budget by soil particles was estimated to be at an unusually high value of 44.22%.     

Development of monitoring technology for airborne particulate matter

Particulate matter suspended in the air has adverse effects onhuman health. Its level of concentration is an important parameter in evaluating the degree of hazard it poses to the atmosphere. Conventional methods used in measuring particulatematter are often filter-based, which indicates some disadvantagesbecause such a base requires labor and time. In this study, to achieve real-time measurements, a new electrical method was developed for measuring PM10 and PM2.5 concentrations. The basicprinciple is to electrically charge particles passing through thePM inlet using a corona charger and measure the currents createdby charged particles to obtain the number concentration of particulate matter. A new type inlet based on the particle cupimpactor configuration was designed and its performance was evaluated. A unipolar diffusion charger was developed and thecharger's efficiency was determined experimentally in terms ofPn, which represents the penetration through the charger,P, times the average charge number acquired by a particle,n, for different particle sizes. The correlation was constructed between the PM10 (or the PM2.5) mass concentrationsand the electrical currents due to particles, which were chargedby the diffusion charger.     

Cultured human-cell-based bioassay for environmental risk management

Among bioassays for evaluating various impacts of chemicalson humans and ecosystems, those based on culturedmammalian-cells can best predict acute lethal toxicity to humans. Weexpect them to be employed in the future in environmentalrisk management alongside mutagenicity tests and endocrine-disrupting activity tests. We recently developed adisposable bioassay device that immobilizes humanhepatocarcinoma cells in a small micropipette tip. Thisenables very quick (within 2 h) evaluation of acute lethaltoxicity to humans. For bioassay-based environmentalmanagement, 2 promising approaches have been demonstrated bythe US-EPA: toxicity identification evaluation (TIE) andtoxicity reduction evaluation (TRE). The Japanese Ministryof Environment has been supporting a multi-center validationproject, aimed at assembling a bioassay database. To makefull use of these resources, we present a numerical modelthat describes contribution of individual chemical toobserved toxicity. This will allow the selection of the mosteffective countermeasure to reduce the toxicity. Bioassay-based environmental risk management works retrospectively,whereas impact assessment using substance flow models andtoxicity databases works prospective. We expect that these 2approaches will exchange information, act complementarily,and work effectively in keeping our environment healthy inthe 21st century.     

Urban development and landscape change in the Yangtze River Delta region in China

The impact of large-scale urban development on land resources has long been debated by urban planners and designers. This study investigated the extent to which different urban characteristics are associated with land-cover change. The Yangtze River Delta region in China, forming one of the largest sprawling urban landscapes among the regions around the world, was chosen for the study area. Spatial analysis and multiple regression methods were applied to empirically investigate the pattern of resource sites lost to urban development in the area between the 1950s and 2017. The results showed that contrary to the widespread notion that large-sized cities are predominantly responsible for a region’s environmental degradation, city size was not a significant factor in determining the rate of resource loss. Large-sized cities gained their populations with far lesser impacts on land than small-sized cities and towns if normalized to the same number of populations. One explanation for the diminishing effect of city size on land-cover change relates to the degree of spatial dispersion of urban development and local differences in social valuation of diversified lands by cities.     

Compositional data analysis and geochemical modeling of CO2–water–rock interactions in three provinces of Korea

Environmental Geochemistry and Health - The CO2-rich spring water (CSW) occurring naturally in three provinces, Kangwon (KW), Chungbuk (CB), and Gyeongbuk (GB) of South Korea was classified based...     

Reductive dissolution and sequestration of arsenic by microbial iron and thiosulfate reduction

Environmental Geochemistry and Health - Iron oxide and oxy-hydroxide are commonly used for remediation and rehabilitation of arsenic (As)-contaminated soil and water. However, the stability of As...     

Colloid mobilization and heavy metal transport in the sampling of soil solution from Duckum soil in South Korea

Environmental Geochemistry and Health - Colloid mobilization is a significant process governing colloid-associated transport of heavy metals in subsurface environments. It has been studied for the...     

Comparison of Computer Simulations of Total Lung Deposition to Human Subject Data in Healthy Test Subjects

ABSTRACT

A mathematical model was used to predict the deposition fractions (DF) of PM within human lungs. Simulations using this computer model were previously validated with human subject data and were used as a control case. Human intersubject variation was accounted for by scaling the base lung morphology dimensions based on measured functional residual capacity (FRC) values. Simulations were performed for both controlled breathing (tidal volumes [V_T] of 500 and 1000 mL, respiratory times [T] from 2 to 8 sec) and spontaneous breathing conditions. Particle sizes ranged from 1 to 5 um. The deposition predicted from the computer model compared favorably with the experimental data. For example, when V_T = 1000 mL and T = 2 sec, the error was 1.5%. The errors were slightly higher for smaller tidal volumes. Because the computer model is deterministic (i.e., derived from first principles of physics), the model can be used to predict deposition fractions for a range of situations (i.e., for different ventilatory parameters and particle sizes) for which data are not available. Now that the model has been validated, it may be applied to risk assessment efforts to estimate the inhalation hazards of airborne pollutants.