小型区域形状规整性对环境噪声测量误差的影响分析

本文通过对小型区规整性与环境噪声抽样测量误差的讨论,提出了区域形状的改变对抽样测量误差的影响状况。     

LnSrCoO4对CO和C3H8的氧化性能

采用聚乙二醇凝胶法制备LnSrCoO4(Ln=La,Sm)复合氧化物,考察了其对CO和C3H8的氧化反应活性,并运用XRD,BET,TEM和TPD等方法对其进行了表征．结果表明：该类复合氧化物具有四方K2NiF。结构,对CO和C3H8的氧化反应具有不同的催化活性,而LaSrCo04催化活性更好．     

一种新型湿地公园在水环境修复中的应用

近年来,利用人工湿地技术修复水环境,进而建设湿地公园成为一大热点,但人工湿地工艺存在不容忽视的缺陷。成都市凤凰河二沟湿地公园创新性的采用人工快渗+表面流人工湿地组合工艺修复水环境,两者互为补充,互为强化,COD、BOD5、氨氮、TP去除率分别达85%～95%、85%～95%、95%～98%、70%～80%,即使低温环境污染物降解效果也很稳定。     

Degradation of metronidazole by dielectric barrier discharge in an aqueous solution

The discharge characteristics during the degradation of MNZ by DBD were investigated. Increasing the discharge frequency can promote the degradation of MNZ. MNZ removal reaches 99.1% at the initial concentration of 40 ppm within 120 min. Coexisting organic matter inhibits the degradation of MNZ. The energy efficiency of DBD for MNZ removal is higher than other technologies. Degradation of metronidazole (MNZ) which is a representative and stable antibiotic by dielectric barrier discharge (DBD) in an aqueous solution has been studied. Effects of initial MNZ concentration, solution pH and coexisting organics on the degradation were investigated. The results illustrated that increasing the input power and the discharge frequency can improve the removal of MNZ. At low initial concentration, the removal of MNZ can reach up to 99.1%. Acidic and neutral conditions are more favorable for MNZ removal than alkaline condition in the early stage of degradation. However, the difference in MNZ removal between those in acidic or neutral media and that in alkaline one could be neglected with prolonging of the treatment time. Therefore, this method can be applied to MNZ degradation with a wide pH range. Coexisting organic matter in water can attenuate the removal to some extent. This study could provide valuable references for the degradation of nitroimidazole antibiotics by DBD.     

Exposure assessment,chemical characterization and source identification of PM2.5 for school children and industrial downwind residents in Guangzhou,China

To assess the exposure doses of PM_2.5 and to investigate its chemical components for the subpopulation (i.e., school children and industrial downwind residents), simultaneous sampling of indoor and outdoor PM_2.5 was conducted at an elementary school close to traffic arteries and a residence located in the downwind area of a steel plant in metropolitan Guangzhou in 2010. Chemical components, i.e., organic carbon, elemental carbon and 6 water soluble ions were analyzed in PM_2.5. A survey was also conducted to investigate the time-activity patterns of the school children and the industrial downwind residents. Indoor and outdoor PM_2.5 were 63.2 ± 20.1 and (76.7 ± 35.8) μg/m³ at the school, and 118.8 ± 44.7 and 125.7 ± 57.1 μg/m³ in the community, respectively. Indoor PM_2.5 was found to be highly related to outdoor sources, and stationary sources were the significant contributors to PM_2.5 at both sites. The daily average doses of PM_2.5 for the school children at the school (D _children) and the industrial downwind residents in the community (D _residents) were (7.6 ± 1.9) and (36.1 ± 36.8) μg/kg-day, respectively. The daily average doses of particulate organic mass and SO₄ ^2? were the two most abundant chemical components in PM_2.5. PM_2.5 exposure for the school children was contributed by indoor and outdoor environments by 48.8 and 51.2 %, respectively; for the industrial downwind residents, the contributions were 66.0 and 34.0 %, respectively. Age and body weight were significantly and negatively correlated with D _children, while age, body weight and education level were significantly and negatively correlated with D _residents; gender was not a significant factor at both cases.     

Initial mixing of inclined dense jet in perpendicular crossflow

A comprehensive experimental investigation for an inclined ( $60^{\circ }$ to vertical) dense jet in perpendicular crossflow—with a three-dimensional trajectory—is reported. The detailed tracer concentration field in the vertical cross-section of the bent-over jet is measured by the laser-induced fluorescence technique for a wide range of jet densimetric Froude number $Fr$ and ambient to jet velocity ratios $U_r$ . The jet trajectory and dilution determined from a large number of cross-sectional scalar fields are interpreted by the Lagrangian model over the entire range of jet-dominated to crossflow-dominated regimes. The mixing during the ascent phase of the dense jet resembles that of an advected jet or line puff and changes to a negatively buoyant thermal on descent. It is found that the mixing behavior is governed by a crossflow Froude number $\mathbf{F} = U_r Fr$ . For $\mathbf{F} < 0.8$ , the mixing is jet-dominated and governed by shear entrainment; significant detrainment occurs and the maximum height of rise $Z_{max}$ is under-predicted as in the case of a dense jet in stagnant fluid. While the jet trajectory in the horizontal momentum plane is well-predicted, the measurements indicate a greater rise and slower descent. For $\mathbf{F} \ge 0.8$ the dense jet becomes significantly bent-over during its ascent phase; the jet mixing is dominated by vortex entrainment. For $\mathbf{F} \ge 2$ , the detrainment ceases to have any effect on the jet behavior. The jet trajectory in both the horizontal momentum and buoyancy planes are well predicted by the model. Despite the under-prediction of terminal rise, the jet dilution at a large number of cross-sections covering the ascent and descent of the dense jet are well-predicted. Both the terminal rise and the initial dilution for the inclined jet in perpendicular crossflow are smaller than those of a corresponding vertical jet. Both the maximum terminal rise $Z_{max}$ and horizontal lateral penetration $Y_{max}$ follow a $\mathbf{F}^{-1/2}$ dependence in the crossflow-dominated regime. The initial dilution at terminal rise follows a $S \sim \mathbf{F}^{1/3}$ dependence.     

邻苯二甲酸二丁酯对蚕豆胚根细胞微核形成的影响及毒理机制

研究常用增塑剂邻苯二甲酸二丁酯(di-n-butyl phthalate,DBP)对农作物生长的影响,为农用地膜及其残留物的环境安全性评估提供实验依据。以蚕豆为试材,DBP处理浓度为0(CK)、9 mmol·L-1、18 mmol·L-1、27 mmol·L-1和36 mmol·L-1,培养24 h、48 h和72 h后,观测根尖细胞染色体结构变化,测试胚根抗氧化酶活性。结果显示:DBP暴露的蚕豆胚根生长速率减缓;随着DBP暴露时间延长,根尖正在进行分裂的细胞被阻断在有丝分裂前期的比例增加,微核率升高,出现多种类型的染色体畸变;DBP暴露的胚根超氧化物歧化酶(superoxide dismutase,SOD)活性提高5.41%~29.68%,过氧化物酶(peroxidase,POD)活性随DBP浓度增加而递减,过氧化氢酶(catalase,CAT)活性显著降低14.00%~43.08%。结果表明,DBP对蚕豆胚根具有遗传毒性,且能够破坏纺锤丝的结构。     

Effects of ellagic acid on arylamine N‐acetyltransferase activity in human colon tumor cells

The inhibition of arylamine N‐acetyltransferase (NAT) activity by ellagic acid was determined in a human colon tumor (adenocarcinoma) cell line. Two assay systems were performed, one with cellular cytosols (9000g supernatant), the other with intact colon tumor cell suspensions. The NAT activity in a human colon tumor cell line was inhibited by ellagic acid in a dose‐dependent manner in both types of examined systems: i.e. the greater the concentration of ellagic acid in the reaction, the greater the inhibition of NAT activities in both systems. The data also indicated that ellagic acid decreased the apparent K _m and V _max of NAT enzymes from human colon tumor cells in both the systems examined. This report is the first demonstration which showed ellagic acid affect human colon tumor cell NAT activity.     

镉胁迫对脊尾白虾的毒性效应研究

为揭示重金属镉对脊尾白虾的毒性效应,采用急性毒性实验方法,研究了不同浓度镉(Cd~(2+))对脊尾白虾(Exopalaemon carinicauda)血清氧化应激相关生理指标的活性以及肌肉组织中腺苷酸转移酶基因(ANT)和热激蛋白70基因(HSC70)表达水平的影响。共设置4个Cd2+浓度胁迫(0、0.0002、0.001、0.005 mmol·L~(-1)),分别在0、3、6、9、12、24、36、48、72和96 h共10个时间点对相关指标进行测定。结果显示:不同浓度镉胁迫下,脊尾白虾血清中H_2O_2含量、MDA含量和GSH含量均表现为先升高后降低的趋势,H2O2含量在胁迫3 h时即出现明显的升高,而MDA和GSH则均在9 h时出现升高趋势,表现为一定的滞后性。H2O2含量在0.005 mmol·L~(-1)胁迫3 h时出现峰值,MDA含量在0.005 mmol·L~(-1)胁迫9 h时出现峰值,GSH含量在0.001mmol·L~(-1)胁迫48 h时出现峰值,且均与对照组存在显著性差异(P0.05)。HSC70基因的表达量在不同浓度胁迫下均表现为先升高后降低的趋势,且均在24 h时达到峰值,具体表达量水平的顺序为:0.0002 mmol·L~(-1)0.001 mmol·L~(-1)0.005 mmol·L~(-1)。ANT基因的表达量在不同浓度下则均表现为明显的下调趋势。由此可见,急性Cd~(2+)胁迫不仅影响脊尾白虾的氧化应激相关生理指标,还影响机体内组成型HSC70及与能量传递有关的ANT基因的表达水平。     

深部煤层对CO2地质处置机制及应用前景

CO2是重要的温室气体之一,CO2的有效处置对减缓全球变暖具有重大意义。由于煤介质具有特殊的双重孔隙结构、吸附性强等物性特征,对CO2具有很强的吸附能力,且大于煤介质吸附CH4的能力,因此,可将CO2注入深部不可开采煤层储存,在长久处置CO2的同时亦可促进深部煤层气的开采。在我国,深部不可开采煤层处置CO2显示了巨大的潜力,可以处置26-46年的CO2排放量,尤其在华北煤炭能源基地具有良好的应用前景。