Concentrations of methylmercury in invertebrates from wetlands of the Prairie Pothole Region of North America

Prairie wetlands may be important sites of mercury (Hg) methylation resulting in elevated methylmercury (MeHg) concentrations in water, sediments and biota. Invertebrates are an important food resource and may act as an indicator of MeHg exposure to higher organisms. In 2007-2008, invertebrates were collected from wetland ponds in central Saskatchewan, categorized into functional feeding groups (FFGs) and analyzed for total Hg (THg) and MeHg. Methylmercury and THg concentrations in four FFGs ranged from 0.2-393.5 ng · g(-1) and 9.7-507.1 ng · g(-1), respectively. Methylmercury concentrations generally increased from gastropods with significantly lower average MeHg concentrations compared to other invertebrate taxa. Surrounding land use (agricultural, grassland and organic agricultural) may influence MeHg concentrations in invertebrates, with invertebrate MeHg concentrations being higher from organic ponds (457.5 ± 156.7 ng · g(-1)) compared to those from grassland ponds (74.8 ± 14.6 ng · g(-1)) and ponds on agricultural lands (32.8 ± 6.2 ng · g(-1)).     

Ozone oxidation and aerobic biodegradation with spent mushroom compost for detoxification and benzo(a)pyrene removal from contaminated soil

The combination of ozonation and spent mushroom compost (SMC)-mediated aerobic biological treatment was investigated in the removal of benzo(a)pyrene from contaminated soil. The performances of the process alone and combined were evaluated in terms of benzo(a)pyrene removal efficiency, mineralization efficiency (as total organic carbon removal), and soil residual toxicity (phytotoxicity to Lepidium Sativum and toxicity to Vibrio fischeri). In spite of the removal efficiency (35%) obtained by SMC-mediated biological process as a stand-alone treatment, the combined process showed a benzo(a)pyrene concentration reduction higher than 75%; the best removal (82%) was observed after 10 min pre-ozonation treatment. In particular, ozonation improved the biodegradability of the contaminant, as confirmed by the increase of CO(2) production (close to 70% compared to the control), mineralization (greater than 60%) and bacterial density (which increased by two orders of magnitude). Moreover, according to phytotoxicity tests on L. Sativum, the aerobic biological process of pre-ozonated soil decreased toxicity. According to the results achieved in the present study, ozonation pre-treatment showed an high potential to overcome the limitation of bioremediation of recalcitrant compound, but it should be carefully operated in order to maximize PAH removal efficiency as well as to minimize soil residual toxicity which can result from the formation of the oxidation intermediates.     

Development of cleaner-burning brick kilns in Ciudad Juarez, Chihuahua, Mexico

The following results provide a comparison between net airborne contamination produced by the traditional form of kiln used in Northern Mexico and by those modified according to a design by Dr. Robert Marquez. What has become known as the MK style kiln was intended to significantly reduce contaminant emissions. The concept involves covering the kiln with a dome and channeling the output of an active kiln through a second, identical loaded kiln for its additional filtration of the effluents. Kilns of a pair are connected via clay brick channels. The roles are reversed after the initial kiln is refilled. Significant reductions in the particulate and gaseous emissions were achieved in the prototype system, but a connectional problem with recent kiln pairs has also limited the degree of operational success. The problem did not mask the potential of the MK kiln, as will be shown. Additional anticipated benefits to the owners of MK kilns, such as reduced operating cycles and decreased quantities of fuel, also have been verified. Key measurements made during all of the burns were of aerosol densities and buoyancies in the flues, kiln temperatures, and, on a number of occasions, chemical analyses of both aerosol and gaseous effluents. Continuous time histories of aerosol densities for most burns (of a total of -40) provide a basis for examining features and the effects of differing styles of operation with respect to burn efficiency and net contaminant masses. Covering the active kiln with a dome produces a net reduction in dry aerosol effluent mass of a factor between 5 and 10, whereas the addition of a filter kiln produces a net reduction of about a factor of 2. The use of used motor oil as a fuel further reduced aerosol contamination by -1 order of magnitude.     

波罗的海鳕鱼（Gadus morhua）中单氟和多氟烷基物质和总氟的时间变化趋势（1981-2013）

本文研究了1981~2013年间在波罗的海哥德兰东南部附近采集的鳕鱼（Gadus morhua）肝组织中28种单氟和多氟烷基物质（PFAS）的时间变化趋势。共检测到10种PFAS，其中∑28PFAS几何平均浓度范围为6.03~23.9 ng/g。全氟辛烷磺酸（PFOS）是PFAS的主要组成，且仍以每年3.4%的速度增长。大多数长链全氟烷基羧酸以每年3.9%~7.3%的速度增加，但全氟辛酸（PFOA）没有随着时间的推移而显著变化。全氟烃基酸前体——全氟辛烷磺酰胺（FOSA）和6:2氟端粒磺酸也被检出，其中前者以每年4.4%的速度下降，可能反映出其从2000年开始逐步淘汰。从2000年到2013年的交替时间趋势分析显示的趋势率略有不同。对于大多数化合物，其增长速度慢于其在整个时期的趋势。一个例外是全氟己烷磺酸盐（PFHxS），从2000年开始以3.7%的速度增长，而从1981年开始以每年3.0%的速度增长。对样品总氟（TF）含量的分析揭示了大量未经鉴定的氟，但其组成（有机或无机）仍不清楚。个体PFAS浓度（PFOS除外）与肝脏体细胞指数呈显著负相关。此外，体长与PFOA和PFNA呈负相关，而与全氟癸酸盐（PFDoDA）和FOSA呈正相关。对海洋鱼类中PFAS的内分泌、免疫和代谢影响的进一步研究对于评估这些物质的环境风险至关重要。     

Aerobic plate count,Salmonella and Campylobacter loads of whole bird carcass rinses from pre-chillers with different water management strategies in a commercial poultry processing plant

Abstract

Salmonella and Campylobacter are significant issues for poultry processors because of increasing regulatory standards as well as public health concerns. The goal of this study is to report the effects of two different pre-chiller systems that utilize different temperatures and water recirculation systems on whole bird carcass rinsates. Both pre-chiller tanks were contained within a single poultry processing facility and operated at different temperatures and water systems. The incidence of Campylobacter spp. and Salmonella spp., as well as the aerobic plate counts on whole bird carcass rinses are reported in this study from each pre-chiller system. The results from this study reveal that there are significant differences in how microbial populations and pathogens change over time in each pre-chiller system. Furthermore, we identify that these patterns are different per system. Such data are impactful as it indicates that measuring carcasses within a plant must consider both temperature and water recirculation as it may prevent comparability of different lines within a single processing facility.     

Spontaneous abortion in women occupationally exposed to inhalational anesthetics: a critical systematic review

Environmental Science and Pollution Research - Occupational exposure to inhalational anesthetics has been associated with health problems, including reproductive issues. Considering the scarcity...     

Modelling of the migration of trace elements along groundwater flowpaths by using a steady state approach application to the site at El Berrocal (Spain)

The applications of geochemical modelling to natural water systems mostly rely upon the equilibrium assumption. This is in principle justified for deep groundwater systems with long water residence times.In addition, trace element behaviour in these natural systems has been normally modelled by taking into account the precipitation and dissolution of individual trace element phases.Recent geochemical modelling work related to natural analogue systems would indicate that: (1) the equilibrium condition is restricted to a limited number of components in long water residence times and (2) the behaviour of trace metals is very much connected to the major component cycling in the system.There is a need to develop our geochemical modelling capabilities to take these two facts into account in order to be able to predict the behaviour of trace components (radionuclides) in a geological repository.In this work we report on the successful application of steady-state kinetics in conjunction with co-dissolution/co-precipitation approaches to model trace element geochemistry in the natural analogue system at El Berrocal. The evolution of major components of the system (Ca (II), Al (III), CO₃²⁻ and Si) as well the trace elements investigated (U, Ba and Mn) is well reproduced by using the coupling between steady-state kinetics and co-dissolution/co-precipitation approaches.     

Pilot‐scale field study for ammonia removal from lagoon biogas using an acid wet scrubber

The anaerobic activities in swine slurry storage and treatment generate biogas containing gaseous ammonia component which is a chemical agent that can cause adverse environmental impacts when released to the atmosphere. The aim of this pilot plant study was to remove ammonia from biogas generated in a covered lagoon, using a sulfuric acid wet scrubber. The data showed that, on average, the biogas contained 43.7 ppm of ammonia and its concentration was found to be exponentially related to the air temperature inside the lagoon. When the air temperature rose to 35°C and the biogas ammonia concentration reached 90 ppm, the mass transfer of ammonia/ammonium from the deeper liquid body to the interface between the air and liquid became a limiting factor. The biogas velocity was critical in affecting ammonia removal efficiency of the wet scrubber. A biogas flow velocity of 8 to 12 mm s^?1 was recommended to achieve a removal efficiency of greater than 60%. Stepwise regression revealed that the biogas velocity and air temperature, not the inlet ammonia concentration in biogas, affected the ammonia removal efficiency. Overall, when 73 g L^?1 (or 0.75 M) sulfuric acid solution was used as the scrubber solution, removal efficiencies varied from 0% to 100% with an average of 55% over a 40‐d measurement period. Mass balance calculation based on ammonium–nitrogen concentration in final scrubber liquid showed that about 21.3 g of ammonia was collected from a total volume of 1169 m³ of biogas, while the scrubber solution should still maintain its ammonia absorbing ability until its concentration reaches up to 1 M. These results showed promising use of sulfuric acid wet scrubber for ammonia removal in the digester biogas.