Evaluation of solid sorbents for sampling aliphatic and aromatic nitro compounds in work-room air

Amberlite XAD-2 and XAD-7 porous polymers were evaluated for the solid sampling of aliphatic and aromatic nitro compounds in work-room air. With the use of solvent desorption, XAD-2 gave 80–100% recovery of nitroaromatics, and XAD-7 85–100% recovery of nitroaliphatics. The compounds studied were nitromethane, nitroethane, 2-nitropropane, nitrobenzene, $\text{m}$-dinitrobenzene and 2,4,6-trinitrotoluene. All six compounds gave very poor recoveries from activated charcoal.     

Harmonized Nordic strategies for isocyanate monitoring in workroom atmospheres

The Nordic Network on Isocyanates (NORDNI) is financed by the Nordic Council of Ministers and is under the administration of Prof. Yngvar Thomassen and co-workers. National Institute of Occupational Health, Norway. The aim of NORDNI is to establish a broad network between the Nordic National Institutes of Occupational Health working within the field of isocyanate exposure and strategies for sampling and determination of isocyanates in workroom atmospheres. This viewpoint article summarizes the resolutions that were established at the 1st NORDNI consensus meeting arranged in Fr?ya, Norway, 31st August-2nd September, 2001. The consensus platform from the 1st NORDNI meeting was presented at the 4th International Symposium on Modern Principles of Air Monitoring, Lillehammer, Norway, 3-7 February, 2002.     

A gas-phase biosensor for environmental monitoring of formic acid: laboratory and field validation

In order to encourage more exposure measurements to be performed, a formic acid gas-phase biosensor has been developed for this purpose. In the present paper, an enzyme based biosensor has been validated with respect to analyte selectivity and on-site use. To ensure that the sampler developed measures the compound of interest the biosensor was exposed to three near structural homologues to formic acid, i.e. acetic acid, methanol and formaldehyde. These vapours were generated with and without formic acid and the only compound that was found to have an effect on the performance of the biosensor, albeit a small one, was acetic acid. The field test was performed in a factory using formic acid-containing glue for glulam products. In parallel to the measurements with the biosensor a well defined reference method was used for sampling and analysing formic acid. It was found that the biosensor worked satisfactorily in this environment when used in a stationary position. It was also shown that the biosensor could determine formic acid vapour concentrations down to 0.03 mg m(-3).     

A diffusive sampling device for the determination of formaldehyde in air using N-methyl-4-hydrazino-7-nitrobenzofurazan (MNBDH) as reagent

A new method utilizing the diffusive sampling of formaldehyde in air has been developed. Formaldehyde is sampled with the use of a glass fiber filter impregnated with N-methyl-4-hydrazino-7-nitrobenzofurazan (MNBDH) and phosphoric acid. The formaldehyde hydrazone formed is desorbed from the filter with acetonitrile and determined by high-performance liquid chromatography (HPLC) with UV/visible detection at 474 nm. The sampling rate was determined to be 24.7 mL min-1 with a relative standard deviation of 7% for 48 experiments. The measured sampling rates were not dependent on the formaldehyde concentration (0.1-1.0 mg m-3), sampling time (15-482 min) or relative humidity (20-85%). The detection limit was 70 micrograms m-3 for a 15 min sampling period and 2 micrograms m-3 for an 8 h sampling period.     

Naphthalene emissions from moth repellents or toilet deodorant blocks determined using head-space and small-chamber tests

The present study investigated the emissions of naphthalene and other compounds from several different moth repellents(MRs) and one toilet deodorant block(TDB)currently sold in Korea,using a headspace analysis.The emission factors and emission rates of naphthalene were studied using a small-scale environmental chamber.Paper-type products emitted a higher concentration of the total volatile organic compounds(VOCs)(normalized to the weight of test piece)than ball-type products,which in turn emitted higher ...     

From the Levant to Gibraltar: A Regional Perspective for Marine Conservation in the Mediterranean Sea

Marine protected areas (MPAs) are critical to the well-being of threatened ecosystems and thus can be highly beneficial to humans, especially to those residing nearby. We explore the qualities of 117 MPAs in the Mediterranean basin and develop a taxonomy of their characteristics. We relate the spatial distribution of the MPAs to the various characteristics of the taxonomy (size, distance from shore, protection levels, management regimes, etc.) and to areas of high human impact and influence levels. To do this we use information on biogeographic regions and information from two different human influence models; one model developed for the marine environment and one covering the littoral terrestrial environment. Our analysis provides insights to planners and managers working in a regional capacity and trying to build MPA networks. Generally, current MPAs have not been established in high impact areas despite their being close to shores containing intense human activity. Decision-makers wishing to design and establish new MPAs may seek out areas of high cumulative human impacts (near the marine-terrestrial interface) or avoid them depending on marine conservation objectives, including the desire to vary types of MPAs within a network. Limitations of our analysis and methodology indicate areas for further research.     

A Methodology for Evaluating and Ranking Water Quantity Indicators in Support of Ecosystem-Based Management

Ecosystem-based Management (EBM) is an approach that includes different management priorities and requires a balance between anthropogenic and ecological resource demands. Indicators can be used to monitor ecosystem status and trends, and assess whether projects and/or programs are leading to the achievement of management goals. As such, the careful selection of a suite of indicators is a crucial exercise. In this paper we describe an indicator evaluation and selection process designed to support the EBM approach in Puget Sound. The first step in this process was the development of a general framework for selecting indicators. The framework, designed to transparently include both scientific and policy considerations into the selection and evaluation process, was developed and then utilized in the organization and determination of a preliminary set of indicators. Next, the indicators were assessed against a set of nineteen distinct criteria that describe the model characteristics of an indicator. A literature review was performed for each indicator to determine the extent to which it satisfied each of the evaluation criteria. The result of each literature review was summarized in a numerical matrix, allowing comparison, and demonstrating the extent of scientific reliability. Finally, an approach for ranking indicators was developed to explore the effects of intended purpose on indicator selection. We identified several sets of scientifically valid and policy-relevant indicators that included metrics such as annual-7 day low flow and water system reliability, which are supportive of the EBM approach in the Puget Sound.     

What Is the Potential Measurement Error in Occupational Exposure Studies?

ABSTRACT

This paper demonstrates statistical methods that estimate measurement error from available industrial hygiene data. Errors in measuring a continuous exposure variable may arise when all individuals in a work area are assigned the same exposure. An example is when the mean of exposure measurements obtained on a sample of individuals is assigned to all workers with similar jobs. This may lead to inaccurate point and interval estimates in exposure-response modeling. A method of simulating the distribution of true (i.e., unobserved) individual exposures is described in order to estimate the mean and variance of measurement error. The minimum variance unbiased estimator approximates the mean of lognormally distributed exposure measurements. The distribution of true individual exposures is approximated by the distribution of simulated estimates of mean exposure. The methodology is illustrated by exposure data from work areas manufacturing refractory ceramic fiber (RCF) and RCF products. Results show that exposure is slightly underestimated in work areas with between 25 and 113 exposure measurements; measurement error variance averages about 1.3% of the total variance.     

Applying parcel-specific land-use data for improved monitoring of semi-natural grassland in Denmark

A major obstacle to the conservation and management of semi-natural grassland (SNG) is the general lack of consistent and precise maps showing the extent and quality of this habitat type. SNG is related to, and influenced by, agricultural land use. Both intensive land use as well as a lack of extensive land use can reduce the extent and quality of SNG. For Denmark, this paper demonstrates how parcel-specific land-use data can be applied to detect localities with spatial convergences and conflicts between SNG and agricultural land use. Based on their respective influence on SNG, land use is aggregated into five major classes and spatially overlaid with existing nationally registered SNG. Results show that almost 11 % of all SNG is mapped either on cropped land or on rotational grassland, indicating a conflict between mapped SNG and land use. Thirty percent of SNG is mapped outside any agricultural land use, pointing to a lack of management. Fifty nine percent of SNG is mapped either on land receiving payments for grazing/mowing or on other land under extensive management, indicating a convergence between SNG and land use. Finally, 30 % of land receiving payments for grazing/mowing and 62 % of other land under extensive management does not contain any semi-natural habitat. Potential, as yet unmapped, SNG might exist in these localities. Based on these results it is argued that the application of parcel-specific land-use data could significantly improve monitoring of SNG.     

Earth stewardship: Shaping a sustainable future through interacting policy and norm shifts

Transformation toward a sustainable future requires an earth stewardship approach to shift society from its current goal of increasing material wealth to a vision of sustaining built, natural, human, and social capital—equitably distributed across society, within and among nations. Widespread concern about earth’s current trajectory and support for actions that would foster more sustainable pathways suggests potential social tipping points in public demand for an earth stewardship vision. Here, we draw on empirical studies and theory to show that movement toward a stewardship vision can be facilitated by changes in either policy incentives or social norms. Our novel contribution is to point out that both norms and incentives must change and can do so interactively. This can be facilitated through leverage points and complementarities across policy areas, based on values, system design, and agency. Potential catalysts include novel democratic institutions and engagement of non-governmental actors, such as businesses, civic leaders, and social movements as agents for redistribution of power. Because no single intervention will transform the world, a key challenge is to align actions to be synergistic, persistent, and scalable.