虚拟振动试验与真实试验相关性分析

卫星虚拟振动试验是当今应用研究的前沿课题。以某中心承力筒为对象,由设计单位提供了承力筒的分析模型和承力筒试件,在相同的试验条件下分别独立地进行虚拟试验和真实试验,对比两者的试验数据,分析虚拟试验与真实试验结果的异同及其产生的原因,对建立的振动台分析模型和虚拟试验研究方法作出评价。     

柠条的营养成分动态变化分析

试验结果表明,柠条锦鸡儿叶片中的粗脂肪、粗蛋白、钙磷含量最高,其次为花,最差的是枝条,叶片中的粗纤维含量较低,是家畜优质的饲料。中间锦鸡儿种子中的粗蛋白、粗脂肪含量也很高。柠条的粗蛋白、吸附水以及磷的含量基本上以5月初为最高,从7月底到10月初呈下降趋势;粗纤维、粗灰分、钙、无氮浸出物含量从5月初到10月初逐渐增加。2年生柠条样品的粗脂肪含量10月初达到最高,而多年生柠条样品的粗脂肪含量则5月初为最高：随着生长年限的延长。粗蛋白、粗脂肪、先氮浸出物、吸附水、钙磷含量逐年下降,而粗纤维、粗灰分含量逐年增加。适口性下降。     

上推流厌氧反应器连续干发酵猪粪产沼气试验研究

为解决猪粪连续干发酵存在的氨抑制和出料难等难题,在温度(25±2)℃、有机负荷为干物质(TS)4.44 g.(L.d)-1的条件下,采用上推流式厌氧反应器(UPAR)对猪粪进行连续干式发酵试验,研究了猪粪干发酵过程的产气情况、氨抑制现象和出料流动性,并考察了上推流厌氧反应器进行猪粪干发酵的可行性.试验采用4种不同TS质量分数(20%、25%、30%、35%)的猪粪作为原料,经160 d的运行.结果表明,进料TS质量分数对发酵过程有很大的影响,4种不同进料TS质量分数稳定的池容产气率分别为2.40、1.73、0.89、0.62 L.(L.d)-1,进料TS质量分数为20%、25%和30%的产气效率明显优于进料TS=35%的产气效率.随着进料TS质量分数从20%增加到35%,氨氮质量浓度>2 300 mg.L-1会出现明显的产气抑制.在进料TS=35%时,氨氮质量浓度能达到3 800 mg.L-1,产气速率相对于进料TS=20%递减74.1%.当进料TS达到35%、出料TS质量分数达到17.1%、流速<0.002 m.s-1时,UPAR不能顺利出料.     

Redundancy analysis for characterizing the groundwater quality in coastal industrial areas

Groundwater quality in coastal area has been an issue of interest because of excessive groundwater extraction for human use, for example, industrialization, irrigation, which can lead to saltwater intrusion. The study develops an integrated data analysis procedure based on multivariate statistics principal component analysis (PCA), hierarchical cluster analysis (HCA) and redundancy analysis (RDA), to determine the effects of key environmental conditions on the formulation of groundwater pollutants. This proposed method was demonstrated by analyzing groundwater quality monitoring data collected between 2011 and 2014 from four coastal industrial areas in Changhua county of Taiwan, namely Chuansing, Xianxi, Lukang and Fangyuan industrial parks. First, different environmental conditions in each industrial region were explored by PCA. The spatial hierarchy and spatial distribution of pollutant categories were then identified using HCA with the kriging method. Finally, the effect of environmental conditions on constitutive pollutants were identified with RDA. The three environmental patterns identified from the analytical results in Chuansing, Lukang and Xianxi were the salination factor (including conductivity and general hardness (GH)), water level and redox condition (including dissolved oxygen and oxidation–reduction potential). Fangyuan industrial park had only two patterns, namely salination (including conductivity and GH) and oxygen content (including DO and depth). The pollutant category indicated high concentrations of all pollutants in Chuansing and Fangyuan, and higher concentration of SO₄^2?, TDS, Cl^? in Xianxi, and of NH₃-N, Mn, Fe and TOC in Lukang. According to RDA results, salination caused the high concentrations of NH₃N, Cl^?, TDS in Chuansing, and of Cl^?, TDS and SO₄^2? in Xianxi and Lukang. Additionally, salination caused high concentrations of Fe in both Lukang and Fangyuan industrial parks in combination with those three pollutants. The redox condition was linked to high content of NO₃^? in Chuansing and Lukang, and of TOC in Xianxi. In Fangyuan industrial park, NO₃^? was also linked to high oxygen concentration. In summary, the combination of PCA, HCA and RDA enables the analysis of monitoring data to support policy decision-making.     

The effects assessment of firm environmental strategy and customer environmental conscious on green product development

The purpose of this study is to examine why both parties (industry and consumer market) have mutual interests in protecting the environment but they still are hesitant to act green. The study used two-stage sampling from consumer market to depict ideal green product characteristics and reliable toy companies, and visit these companies for the second sample collection to examine whether the organizational eco-innovation strategy with customer value has a positive effect on green product development. In other words, the customer's benefit is an important factor for new product development strategy for green toys. This research shows that the willingness to buy green toys increases if most people in society buy green toys. This represents that customers are environmentally conscious and care about protecting the environment, or buying green toys is the result of a new economic trend and childhood education. The willingness to buy green toys increases if customers think that green products implies an enhancement on new product development to toy manufacturers. Further, if manufacturers are able to manage the difficulty of cooperation with all parties in the supply chain and difficulties related to production, they are willing to adopt customers' perceived value on green toys for their new product development strategy. It is rare to find academic research discussing the perspectives of both consumers and manufacturers in the same study because the research topic is very broad and many conditions must be considered. This research aims to find the effect of consumer-perceived value and company eco-innovation on green product development.     

Chlorine residuals and haloacetic acid reduction in rapid sand filtration

It is quite rare to find biodegradation in rapid sand filtration for drinking water treatment. This might be due to frequent backwashes and low substrate levels. High chlorine concentrations may inhibit biofilm development, especially for plants with pre-chlorination. However, in tropical or subtropical regions, bioactivity on the sand surface may be quite significant due to high biofilm development—a result of year-round high temperature. The objective of this study is to explore the correlation between biodegradation and chlorine concentration in rapid sand filters, especially for the water treatment plants that practise pre-chlorination. In this study, haloacetic acid (HAA) biodegradation was found in conventional rapid sand filters practising pre-chlorination. Laboratory column studies and field investigations were conducted to explore the association between the biodegradation of HAAs and chlorine concentrations. The results showed that chlorine residual was an important factor that alters bioactivity development. A model based on filter influent and effluent chlorine was developed for determining threshold chlorine for biodegradation. From the model, a temperature independent chlorine concentration threshold (Cl_threshold) for biodegradation was estimated at 0.46-0.5 mg L⁻¹. The results imply that conventional filters with adequate control could be conducive to bioactivity, resulting in lower HAA concentrations. Optimizing biodegradable disinfection by-product removal in conventional rapid sand filter could be achieved with minor variation and a lower-than-Cl_threshold influent chlorine concentration. Bacteria isolation was also carried out, successfully identifying several HAA degraders. These degraders are very commonly seen in drinking water systems and can be speculated as the main contributor of HAA loss.     

High-throughput screening of dioxins in sediment and soil using selective pressurized liquid extraction with immunochemical detection

A high-throughput screening method using selective pressurized liquid extraction (SPLE) and enzyme-linked immunosorbent assay (ELISA) for monitoring dioxins in sediment and soil is described. SPLE conditions were developed by extracting sediment or soil together with alumina, 10% AgNO₃ in silica, and sulfuric acid impregnated silica (acid silica) using dichloromethane (DCM) as the solvent at 100 °C and 2000 psi. Post-extraction cleanups were not required for ELISA. Two reference sediments (National Institute of Standards and Technology SRM 1944 and Wellington Laboratories WMS01) were analyzed by the SPLE–ELISA method. The ELISA utilized a polyclonal antibody and 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) as the calibrant. Recoveries of ELISA-derived TCDD equivalents (EQ) relative to the expected gas chromatography/high resolution mass spectrometry (GC/HRMS) derived dioxin toxic equivalent (TEQ) values were 116 ± 11% for SRM 1944 and 102 ± 13% for WMS01. ELISA TCDD EQs were consistent with the dioxin TEQs as measured by GC/HRMS for 25 soil/sediment samples from seven different contaminated sites. The ELISA had an approximate method detection limit of 10 pg g⁻¹ with a precision of 2.6–29% based on the relative percentage difference (%RPD) for duplicate samples. Estimated sample throughput for the SPLE–ELISA was three times or more than that of the GC/HRMS method employing PLE with a multi-column cleanup.     

河南省环境管制与工业污染物排放量的灰色关联度研究

选取万元GDP能耗作为参考序列,将工业发展过程中的5种主要污染物作为比较序列,运用灰色关联分析方法定量研究了河南省18个城市的环境管制和不同污染物之间的灰色关联程度,并提出了一些富有针对性的政策建议：加强监管,切实查找固体废弃物的产生来源,努力提高废弃物综合利用水平。     

A sulfur removal and disposal process through H2S adsorption and regeneration: Ammonia leaching regeneration

An iron oxide solid sponge H₂S adsorbent works by reacting H₂S and turning ferric oxide into ferric sulfide. The ferric sulfide will be converted back into ferric oxide and elemental sulfur when contacting oxygen or air. This study investigates the leaching of elemental sulfur from the solid sponge using anhydrous liquid ammonia as solvent. The leaching treatment expectedly results in effective regeneration of the adsorbent, which is able to lead to a sulfur removal and recovery process suitable for handling the small and mid-sized sulfur production cases, i.e., those less than 10 ton/day sulfur. The leaching does not significantly impair the physical properties, including the adsorbent pellet strength. The adsorption–regeneration (or leaching) cycle could be repeated at least three times. The cumulative sulfur loading can achieve as high as 50% (w/w), three times greater than that in the one-time use. The wash-off in leaching and the spent adsorbent can be made into slurry that is to be injected into underground formations such as depleted oil wells. It is anticipated that this underground injection is safer and more efficient than acid gas injection.