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分析了应用亚甲基蓝分光光度(GB/T16489-1996)测定废水硫化物测试过程中不确定度影响因素,主要来源为硫化物标准溶液、标准曲线拟合、随机效应、分光光度计和取样体积这五部分。本测量合成相对标准不确定度0.025 9;其中由测定样品质量引入的不确定度为0.024 7;由样品体积引入的不确定度为0.007 7。本次废水中硫化物测量结果为:0.110±0.006 mg/L,k=2(包含概率约为95%)。 相似文献
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ABSTRACT Refrigerant pressure drop and temperature change in pipes are normally ignored in the thermodynamic analysis of traditional vehicle air conditioning system, this will result in serious errors. In this Paper, pressure drop and temperature difference are simulated in different pipes of electric vehicle (EV) heat pump system to analysis the effects of pipes in the actual EV heat pump system. The results indicate that the greater the mass flow, the faster pressure drop increases, the temperature difference decreases. Pressure drop of saturated liquid refrigerant is smaller than that of saturated gas refrigerant at the same saturation pressure and mass flow rate. The higher the refrigerant pressure (no phase change), the slower pressure drop decreases, the faster the temperature difference decreases. Pressure drop decreases with the increment of bending angle of the pipe. For EV heat pump system, suitable valves and less branches are helpful for energy saving of the system. Shortening the pipe between compressor and condenser can reduce temperature change obviously. Pressure drop per unit length in the pipe between evaporator and compressor is large especially in heating mode because of lower refrigerant density. It even reaches to over 100 times of that in the pipe between condenser and throttle valve in heating mode and has negative effects on the performance of the system. If the evaporator is closer to the compressor and the number of branches is less, then pressure drop will decrease a lot, which will be advantageous for energy saving of the heat pump system. 相似文献
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Ying Cui Feng Tan Yan Wang Suyu Ren Jingwen Chen 《Frontiers of Environmental Science & Engineering》2020,14(6):111
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Fang Shubo Cui Qu Dai Xiaoyan 《Environmental science and pollution research international》2020,27(9):8835-8845
Environmental Science and Pollution Research - This study proposed an in situ soil experimental system to quantify concentration and accumulation rates of polychlorinated biphenyl (PCB) congeners... 相似文献
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Steroid estrogens such as estrone (E1), 17β-estradiol (E2), estriol (E3), and 17α-ethynylestradiol (EE2) have been suspected to be the main contaminants, which can affect the endocrine system of animals. Many authors have investigated these chemicals in the domestic wastewater treatment plants (WTP). However, wastewater from industries producing steroid contraceptives has not got ample attention. From the environmental point of view, the four steroids are very significant because even very low concentrations (ng/L) can cause reproductive disturbances in human, livestock and wildlife. The main purpose of the present investigation was to develop an analytical method for the determination of the four steroid estrogens present in WTP of a pharmacy factory, mainly producing contraceptive medicine in Beijing, China. Analysis was performed by solid-phase extraction (SPE) system and liquid chromatography combined with tandem mass spectrometry (LC/MS/MS). The average recoveries from effluent samples ranged from 88% to 103% and the precision of the method ranged from 9% to 4%. Based on 0.5-L wastewater samples, the limit of quantification (LOQ) was determined at 0.7 ng/L for E1, 0.8 for E2, 0.9 ng/L for E3, and 0.5 ng/L for EE2 in influent, and 1.0 ng/L for E2 and EE2, and 2.0 ng/L for E1 and E3 in effluent. In the influent samples, average concentrations of 80, 85, 73 and 155 ng/L were determined for E1, E2, E3 and EE2, respectively, showing that they were removed in this WTP to the extent of 79, 73, 85 and 67%, respectively. 相似文献
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Dietary uptake is the major way that inorganic arsenic (iAs) enters into benthic fish; however, the metabolic process of dietborne iAs in fish muscle following chronic exposure remains unclear. This was a 40-day study on chronic dietborne iAs [arsenite (AsIII) and arsenate (AsV)] exposure in the benthic freshwater food fish, the crucian carp (Carassius auratus), which determined the temporal profiles of iAs metabolism and toxicokinetics during exposure. We found that an adaptive response occurred in the fish body after iAs dietary exposure, which was associated with decreased As accumulation and increased As transformation into a non-toxic As form (arsenobetaine). The bioavailability of dietary AsIII was lower than that of AsV, probably because AsIII has a lower ability to pass through fish tissues. Dietary AsV exhibited a high potential for transformation into AsIII species, which then accumulated in fish muscle. The largely produced AsIII considered more toxic at the earlier stage of AsV exposure should attract sufficient attention to human exposure assessment. Therefore, the pristine As species and exposure duration had significant effects on As bioaccumulation and biotransformation in fish. The behavior determined for dietborne arsenic in food fish is crucial for not only arsenic ecotoxicology but also food safety. 相似文献