Impact of a massive crude oil spill on the invertebrate fauna of a Missouri Ozark stream

The benthic macroinvertebrate fauna of Asher Creek, a 4th order stream with a base flow of 0.03 m(3)/s, was monitored on 11 occasions for 532 days following a 1.5 million liter domestic crude oil spill. Aquatic insects, crustaceans, segmented worms, roundworms, flatworms, snails, freshwater mussels and other benthic organisms in the oil impacted area were reduced to less than 0.1% of expected numbers at the first sampling period 25 days after the spill. Species diversity indices and the number of mayfly and stonefly taxa were less than the minimum values established for unpolluted Missouri streams for 11 months. The initial post-spill community was dominated by Chironomidae (midges), Simuliidae (blackflies) and Oligochaeta (segmented worms). Some species of Plecoptera (stoneflies), Ephemeroptera (mayflies) and Trichoptera (caddisflies) were absent from the fauna for as long as 9 months. The functional feeding groups of scrapers, filterers, gatherers, and predators initially decreased in relative abundance. Predators later increased in response to a rapidly expanding prey base. Shredders did not change in relative abundance throughout the recovery period. Oil was visually present in the stream riffle substrate for 453 days following the spill. Dissolved oxygen, pH and conductivity were not affected. The visible appearance of oil in the stream substrate was a simple predictor of the status of the benthic invertebrate community. Areas protected with surface skimming siphon dams were less severely impacted and recovered more rapidly than areas where the stream substrate was inundated with oil. The most apparent factors controlling the recovery were the total volume of water passing through the contaminated area and the occurrence of scouring flood.     

Hydroxyurea explosion: a thermoanalytical and calorimetric study

An accident occurred during a production process of hydroxyurea. Several thermoanalytical techniques were used in order to understand the reason for the accident, even utilising a simulation program. Thermogravimetric analysis and Fourier transform infra-red spectroscopy were performed to identify the decomposition products according to European Directive 96/82/EC, the so-called Seveso II.     

工伤保险与安全管理

从我国安全管理实际出发,分析了借助于工伤保险的经济杠杆作用实现国家对企业安全管理制约机制的必要性,并对建立制约机制有关的指标体系及综合评估模型,以及该机制实现等问题进行了深入探讨.     

A laboratory experiment testing the antecedents of leader cognitions

A laboratory experiment was conducted to test relationships between leadership style, feedback on subordinate performance within the context of either the vision or goals of the organization, and leader cognitions representing a modified version of Wofford and Goodwin's (1994) cognitive processing model of leadership. The results indicated that: (1) positive feedback leads to the access of transformational cognitions, whereas negative feedback leads to the access of transactional cognitions; (2) negative feedback about subordinate performance causes transformational leaders to access transactional cognitions in response to subordinates; (3) the relationship between transformational leadership behavior and transformational cognitions is strengthened when feedback received about subordinates is vision‐related compared to feedback that is goal‐related; and (4) the relationship between transactional leadership behavior and transactional cognitions is strengthened when feedback received is goal‐related compared to feedback that is vision‐related. Limitations and future research directions are discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

Leadership self‐efficacy and managers' motivation for leading change

This study develops and tests a leadership model that focuses on managers' motivation for attempting the leadership of change. The construct of leadership self‐efficacy (LSE) is defined, and a measure comprising three dimensions (direction‐setting, gaining followers' commitment, and overcoming obstacles to change) is developed. Based on Bandura's (1986) social cognitive theory, the primary hypothesis is that high LSE managers will be seen by direct reports as engaging in more leadership attempts. Relationships are also proposed between LSE and several factors that are expected to influence this confidence judgment. Managers' organizational commitment and crisis perceptions are modelled as potential moderators of the relationship between LSE and leadership attempts. The model was tested through surveys distributed to managers (n = 150) and their direct reports (n = 415) in a real estate management company and an industrial chemicals firm. Positive relationships (p < 0.05) were found between the first two dimensions of LSE and managers' leadership attempts. An interaction effect involving organizational commitment was discovered for the LSE/overcoming obstacles dimension (p < 0.05). Several positive relationships were found between LSE dimensions and proposed antecedents, including self‐esteem (p < 0.05), subordinates' performance abilities (p < 0.05), and managers' job autonomy (p < 0.05). Copyright © 2002 John Wiley & Sons, Ltd.     

Isometric Pull and Push Strengths of Paraplegics in the Workspace: 2. Statistical Analysis of Spatial Factors

The effect of reach levels, horizontal angles, and vertical angles on isometric pull and push strengths of male and female was determined. Highly significant increases in men’s push strength were found between extreme to maximum reaches, and from extreme to normal reaches. However, for women’s push strength, a significant increase was found only between extreme to maximum reach. Significant or highly significant increases were found in men’s and women’s pull strength between the horizontal angle (θ) sagittal through the active shoulder (90°) and other angles (0, 45, and 135°). However, for men’s push strength, highly significant increases were found between the horizontal angle 45° from the frontal plane, and other angles. For women’s push strength, significant or highly significant increases were found between the horizontal angles 0° and angles of 90 and 135°. For men’s and women’s pull strength, significant or highly significant increases were found between the vertical angle (?), 90°, and other angles (–20, 0, and 45°). Similar increases were found for women’s push strength between the 45° angle and other angles. In the design of a workstation for paraplegics that requires pull and push forces, consideration must be given to the spatial factors.     

Experimental investigation of spark ignition energy in kerosene,hexane, and hydrogen

Quantifying the risk of accidental ignition of flammable mixtures is extremely important in industry and aviation safety. The concept of a minimum ignition energy (MIE), obtained using a capacitive spark discharge ignition source, has traditionally formed the basis for determining the hazard posed by fuels. While extensive tabulations of historical MIE data exist, there has been little work done on ignition of realistic industrial and aviation fuels, such as gasoline or kerosene. In the current work, spark ignition tests are performed in a gaseous kerosene–air mixture with a liquid fuel temperature of 60 °C and a fixed spark gap of 3.3 mm. The required ignition energy was examined, and a range of spark energies over which there is a probability of ignition is identified and compared with previous test results in Jet A (aviation kerosene). The kerosene results are also compared with ignition test results obtained in previous work for traditional hydrogen-based surrogate mixtures used in safety testing as well as two hexane–air mixtures. Additionally, the statistical nature of spark ignition is discussed.     

An approach for domino effect reduction based on optimal layouts

An approach to reduce the probability of producing a domino effect in process industry is developed in this work. It is assumed that optimal layouts should include appropriate analysis to reduce risk during the process design stage. The model developed for this approach combines the estimation of probability of damage due to overpressure, proposed by Mingguang and Juncheng (2008), and escalation threshold values defined by Cozzani, Gubinelli, and Salzano (2006). These equations are combined with other typical layout constraints as well as bounding the probability constraint, which has resulted in a highly non-linear MINLP problem. Solving a case study used by other authors provides evidence for reliability of the developed approach. In this way, layouts are designed to reduce the escalation probability yielding safe distributions.