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51.
Ouafa Benzina Dalel Daâssi Héla Zouari-Mechichi Fakher Frikha Steve Woodward Lassaad Belbahri Susana Rodriguez-Couto Tahar Mechichi 《Environmental science and pollution research international》2013,20(8):5177-5187
The aim of this work was to determine the optimal conditions for the decolorization and the detoxification of two effluents from a textile industry—effluent A (the reactive dye bath Bezactive) and effluent B (the direct dye bath Tubantin)—using a laccase mediator system. Response surface methodology (RSM) was applied to optimize textile effluents decolorization. A Box–Behnken design using RSM with the four variables pH, effluent concentration, 1-hydroxybenzotriazole (HBT) concentration, and enzyme (laccase) concentration was used to determine correlations between the effects of these variables on the decolorization of the two effluents. The optimum conditions for pH and concentrations of HBT, effluent and laccase were 5, 1 mM, 50 % and 0.6 U/ml, respectively, for maximum decolorization of effluent A (68 %). For effluent B, optima were 4, 1 mM, 75 %, and 0.6 U/ml, respectively, for maximum decolorization of approximately 88 %. Both effluents were treated at 30 °C for 20 h. A quadratic model was obtained for each decolorization through this design. The experimental and predicted values were in good agreement and both models were highly significant. In addition, the toxicity of the two effluents was determined before and after laccase treatment using Saccharomyces cerevisiae, Bacillus cereus, and germination of tomato seeds. 相似文献
52.
Marcela Rodrigues De Camargo Luís Fernando Barbisan Meire França Martinez Carla Adriene Da Silva Franchi João Lauro Viana De Camargo Ana Lúcia Tozzi Spinardi-Barbisan 《Journal of environmental science and health. Part. B》2013,48(7):607-613
The noxious effects of low or effective dose exposure to single or mixed pesticides on macrophage activity and the lymphohematopoietic organs were investigated. Male Wistar rats were orally exposed to dichlorvos, dicofol, endosulfan, dieldrin and permethrin, either as single or combined mixtures during a 28-day study containing eight groups: one group received a semipurified diet (non-treated); two groups received a semipurified diet containing low dose mixture (dieldrin 0.025 mg/kg, endosulfan, 0.6 mg/kg, dicofol 0.22 mg/kg, dichlorvos 0.23 mg/kg, permethrin 5 mg/kg) or an effective dose mixture (dichlorvos 2.3 mg/kg, dicofol 2.5 mg/kg, endosulfan 2.9 mg/kg, dieldrin 0.05 mg/kg and permethrin 25.0 mg/kg), respectively; the other five groups received a semipurified diet containing each single pesticide in effective doses. At sacrifice, the thymus, spleen, mesenteric lymph nodes, Payer's patches and bone marrow were removed for histological analysis. Peritoneal macrophages were obtained to determine the phagocytosis and spreading indexes and tumoral necrosis factor alpha (TNF-α), nitric oxide (NO) and H2O2 production. Exposure to pesticide mixtures did not alter the percentage of macrophage phagocytosis and spreading, TNF-α production or the NO and H2O2 release when compared to the non-treated group. Neither was there any apparent evidence that a pesticide mixture at low or effective doses altered the histological structure of the lymphohematopoietic organs. The findings indicate that short-term treatment with pesticide mixtures did not induce an apparent immunotoxic effect in male Wistar rats. 相似文献
53.
质量保证与质量拉制是水质自动监测中十分重要的技术工作和管理工作,包括人员素质、运行与管理机制、试剂与标准溶液的配制及文件记录等。在实际工作中,监测人员可根据仪器的运行状况,定期对仪器进行校准、标准溶液的棱查、比对实验验证及试剂有效性检查,用以检查仪器的基线飘移情况。如果分析中出现一个异常值,它的前后均为正常值,这种数值大多是由仪器的进样、仪器内部试剂传输等原因所致,如果发生原因不明的数据异常,就要及时检查系统的各个环节并采集实际水样进行人工分析,直至查清原因,剔除异常值,并在周报中加以说明,以确保上报数据的准确性、精密性和可比性。 相似文献
54.
José A. Murillo Pulgarín Luisa F. García Bermejo Armando Carrasquero Durán 《Environmental monitoring and assessment》2013,185(1):573-580
A flow injection analysis method based on ion chromatography and luminol chemiluminescence detection was used for the simultaneous determination of copper (II) and cobalt (II) trace levels in soils and sediments following microwave-assisted acid digestion. Detection was based on chemiluminescence (CL) of the luminol–perborate system in an alkaline medium, which is catalyzed by both transition metals. The concentration and pH of the eluent (oxalic acid) was found to affect CL intensities and retention times, both of which were inversely proportional to the oxalic acid concentration. The calibration curves for both metal ions were linear and allowed a limit of detection of 0.003 μg l?1 for cobalt (II) and 0.014 μg l?1 for cooper (II) to be calculated. The proposed method was successfully used to determine both metal ions in certified reference materials of stream and river sediments and soil samples. Based on the results, the determination is free of interferences from the usual concomitant ions. 相似文献
55.
Renewable energy is considered an indispensable basis of sustainable energy systems as electricity generation from renewable
sources results in low emissions of greenhouse gases compared to fossil fuel based electricity and contributes to sustainable
development. However, effective strategies and conducive institutional settings are needed for advancement of such clean electricity
systems. Although Thailand, as a nation, has a huge potential for renewable energy utilization, its total amount of electricity
generation from renewables is relatively small and could be enlarged substantially. Lack of policy mechanisms, institutional
development and financing exist as major barriers for Thailand in this regard. Investigation of the nation’s current energy
strategy implementation shows that relevant energy and development policies are at different stages of implementation and
institutional settings are continuously evolving. This paper argues that further significant efforts could be made towards
advancement of renewable electricity and thus achievement of energy sustainability in Thailand. Resource planning, effective
policy and institutions, focussed planning for energy sustainability and implementation of the Clean Development Mechanism
(CDM) under the Kyoto Protocol could facilitate further advancement of renewables for the nation. 相似文献
56.
IntroductionTheo chlorophenolisaverytoxicandpoorlybiodegradablepollutant,whichisusedasanintermediateinthemanufactureofhigherchlorophenolandphenolresinsandforextractingsulphurandnitrogencompoundsfromcoals.Itisalsousedinorganicsynthesis(dyesandpesticide) .Oxidationofo chlorophenolwastewaterincatalyticwetairoxidationisofpracticalinterestsinceawastewatercontainingo chlorophenolover 2 0 0ppmmaynotbetreatedeffectivelybydirectbiologicalmethods.Advancedoxidationprocesses(AOPs)havebeensuccessfullyuse… 相似文献
57.
Pérez IA Sánchez ML García MA Pardo N 《Environmental science and pollution research international》2011,19(7):3015-3027
Purpose
The impact of CO2 urban plume in a rural area was investigated by concentrations recorded near surface.Methods
CO2 dry concentrations at three levels near surface were recorded for about 8 months at a rural site. Daily cycles were obtained and directional analysis was made with percentiles. Several functions were used to fit background and plume concentrations and the goodness of fit was evaluated with different statistics, which were also compared.Results
Daily cycle showed a difference of around 2 ppm during the night between the lowest (1.8 m) and the highest (8.3 m) levels. Weighting functions of the directional analysis revealed the influence of the Valladolid urban plume. Two regions were established, with local factors prevailing below 3 m?s?1 and transport dominating above 6 m?s?1. The best fit was achieved with a quadratic function for the background and a cubic function for the plume due to the lack of symmetry observed. Gamma and Weibull distributions were also successfully used. Some statistics, such as the root mean square error (RMSE), stood out when evaluating the goodness of fit, whilst others were discarded due to their extremely low values and the lack of sensitivity against the functions used. Finally, a comprehensive metric merging several statistics was also tested with slight differences against RMSE. 相似文献58.
Benthic communities on soft bottoms off Barcelona, at and around two main pollution sources, the mouth of the Besòs River and the outlet of the submarine pipeline draining wastewater and organic sludges from the wastewater treatment plant of Sant Adrià del Besòs, have been studied. Samples were obtained with a Van Veen grab from 36 stations covering a 100 km2 grid, between 10 and 70 m in depth. The effect of both pollution sources is clearly seen both at the species (the following macrofauna groups have been studied: Polychaeta, Mollusca, Echinodermata and Crustacea Decapoda) and community levels. The distribution of species and individuals numbers, species diversity and a pollution index, and of some selected (indicator) polychaeta species, all clearly define the degree of environmental degradation and the extent of the areas under the influence of the organic pollution. 相似文献
59.
Temporal and spatial characteristics of the urban heat island during rapid urbanization in Shanghai, China 总被引:2,自引:0,他引:2
Kaixuan Zhang Rui Wang Chenchen Shen Liangjun Da 《Environmental monitoring and assessment》2010,169(1-4):101-112
Based on meteorological data from 1978 to 2007, we investigated the annual, seasonal, and fixed hourly variations of Shanghai urban heat island (UHI) in urban and suburban areas and spatial distribution of UHI. The results demonstrated a remarkable interannual increase of UHI intensity in Shanghai. The UHI was the strongest in autumn and the weakest in summer, as a consequence of the prevailing weather conditions. Similar to previous studies of other cities, the UHI in Shanghai was stronger in the nighttime than in the daytime. The SW–NE cross section followed the general cross section of the typical UHI described by Oke (1987) who defines its characteristic parts as “cliff”, “plateau”, and “peak”. Analysis of the association of UHI and urbanization indicated that the UHI increased with the expansion of population and rapid increase of gross domestic product. The continuous increase of power consumption and area of paved road and decrease of area of cropland caused the growth of UHI intensity. Green land had a positive effect on mitigation of heat island based on an inversed U-shaped curve with UHI intensity. 相似文献
60.
Da Chen Bixian Mai Jie Song Eddy Y. Zeng 《Environmental pollution (Barking, Essex : 1987)》2009,157(7):2023-2029
Little data are available on organochlorine contamination in Chinese terrestrial birds of prey. This study examined the presence of PCBs, DDTs and other organochlorine pesticides in various raptors from northern China. DDE exhibited the highest concentrations among targeted compounds. Greatest levels (23.5-1020 mg/kg lipid weight) were observed in Eurasian sparrowhawks. This may be due to their stopover in southeastern China, where high DDT and dicofol applications have been documented. Residential kestrels exhibited much lower DDE, but similar PCB and HCH concentrations. ΣTEQs and PCB-126/-77 concentration ratios exhibited significant positive correlations with ΣPCB concentrations, respectively. Similar results were also demonstrated by a meta-analysis of previously published data across avian species. Possible hepatic sequestration of coplanar PCB-77, -126, -169 and -118 was observed as liver TEQs increased in Eurasian sparrowhawks. These observations may indicate an induction of CYP1A enzymes, as a result of elevated contamination in some species. 相似文献