Application of slipstreamed air pollution control devices on waste-as-fuel processes

The recovery of energy from the combustion of municipal solid wastes is becoming an attractive alternative as landfill space becomes scarce and the availability of fossil fuels decreases. Particulate emissions from “waste-as-fuel” processes, however, may differ significantly in chemical and physical properties from particulate emissions produced by firing only coal. Such differences can affect the design and operation of air pollution control equipment. Presented in this paper are the results of a 2-month test program at Ames, Iowa, with a mobile electrostatic precipitator (ESP) and a mobile scrubber supplied by the U.S. Environmental Protection Agency (EPA), Industrial Environmental Research Laboratory (IERL), Research Triangle Park. PEDCo Environmental, Inc., and Acurex Corporation jointly conducted the test program to examine the effect of burning refuse-derived fuel (RDF) on particulate and heavy metal control efficiencies. The mobile ESP was used only as a primary control device, whereas the mobile scrubber was tested both upstream and downstream of the existing full-scale ESP. This paper also presents a status report on a PEDCo test program with a pilot fabric filter at Ames.     

High velocity fabric filtration for control of coal-fired boilers

As a follow-up to a pilot study, a full scale investigation of applying high velocity fabric filtration to coal-fired boiler fly ash control was conducted. Two filter systems were separately applied to two 60,000 lb/h coal-fired boilers. Performance evaluations conducted over the course of a year included total mass removal efficiency and fractional efficiencies. One filtration system employed Teflon felt as the filter media while the second system employed Gore-Tex, a Polytetrofluorethylene (PTFE) laminate on PTFE woven backing. During the course of the year, a limited number of glass felt and woven glass bags were introduced into the house containing Gore-Tex. As a separate option, the second system was outfitted entirely with woven glass bags. Preliminary results indicate acceptable performance at air-to-cloth ratio of 6 to 1. Future plans call for utilizing one of the baghouse systems for SO₂ removal.     

Mutagenic and carcinogenic potency of extracts of diesel and related environmental emissions: Study design, sample generation, collection, and preparation

A major diesel emissions research program has been initiated by the U.S. Environmental Protection Agency to assess the human health risk associated with increased use of diesel automobiles. This program is intended to establish the mutagenic and carcinogenic potency of complex organics associated with diesel particles as well as comparative particle-bound organics from other environmental emissions for which human epidemiological data are available. The mobile source samples selected for this study were collected from a heavy-duty diesel engine, a series of light-duty diesel passenger cars, and a gasoline catalyst automobile. The comparative source samples incorporated into the study were cigarette smoke condensate, coke oven emissions, roofing tar emissions, and benzo(a)pyrene. The samples were tested using three mutagenic assays and four carcinogenic assays as prescribed by a test matrix. This report describes the study design, particle generation, and sample collection and preparation. A brief summary of the bioassays is also included.     

Mutagenic and carcinogenic potency of extracts from diesel related environmental emissions: Simultaneous morphological transformation and mutagenesis in BALB/c 3t3 cells

Particulate extracts from six different environmental emission sources were assayed for genotoxic activity in mouse BALB/c 3T3 clone A31-1 cells. All compounds were tested simultaneously for both transforming and mutagenic (induction of ouabain-resistance) potential with and without exogenous metabolic activation in the form of a 9000 × g postmitochondrial hepatic supernatant fraction from Aroclor-1254 induced Fischer 344 rats. Dichloromethane particulate extracts from the exhaust of two light duty diesel engines (Oldsmobile and Nissan), one heavy duty diesel engine (Caterpillar) and one late model gasoline engine (Mustang II) were assayed in an identical manner to particulate extracts from the emissions of a roofing tar pot and a coke oven. No clear dose-dependent responses were observed, but several of the samples showed significant transforming and mutagenic activity. A qualitative ranking system showed the activity of these particulate extracts for either mutagenesis or transformation was: coke oven = Mustang II gasoline engine > Nissan diesel engine > roofing tar. Particulate extracts from the Oldsmobile diesel engine and the Caterpillar diesel engine showed essentially no activity.     

The additivity of multiple doses of a liver carcinogen in rats

The temporal pattern and dose-rate dependence of liver cancer in rats fed 2-fluorenylacetamide (2-FAA) was compared to analytical formulas derived from a specific model. The model was based on the idea that carcinogens have two distinct actions on cells: (1) transformation and (2) acceleration of progression. Transformed cells are by definition progressing toward cancer, but their rate of progression may depend on several factors, specifically, the amount of carcinogen. In the experiments the carcinogen was removed from the diet after various times and the rate of tumor progression was estimated from the time of tumor occurrence. The results were consistent with the idea that 2-FAA accelerated the progression of the cancers. The model provides a simple explanation of Druckrey's law in that the temporal occurrence of tumors induced by a carcinogen represents the acceleration of a naturally occurring disease progression.     

Plutonium in sheep faeces as an indicator of deposition on vegetation

In order to study the deposition on vegetation of plutonium arising from the testing of nuclear weapons and discharges from nuclear facilities, sheep faeces were collected from the South-west and North of England. The plutonium content of faeces has been shown to be a reproducible and sensitive indicator of deposition on herbage and, with this technique, plutonium discharged from the Sellafield Works of British Nuclear Fuels LImited can be detected 60 km from the site. On moorland pastures the concentration of ^239+240Pu in faeces, expressed as activity per gram of ash, is roughly equal numerically to the deposit of plutonium on 1 m² of vegetation.Some of the plutonium ingested by a grazing sheep is absorbed and the highest concentrations are found in liver. The liver of a sheep grazing on pasture where the ^239+240Pu concentration in faeces was about 2 pCi (74 mBq) g⁻¹ of ash, was found to contain <1% of the Generalised Derived Limit for mutton and offal, and the meat <0·001%.     

An elemental rationing technique for assessing concentration data from a complex water system

Water samples have been collected at the surface and bottom layers at 51 locations throughout Chesapeake Bay. The suspended particulate and dissolved fractions of these samples have been analyzed for Cd, Ce, Co, Cu, Fe, Mn, Mo, Ni, Pb, Sc, Sn, Th, U, and Zn using neutron activation analysis and atomic absorption spectrometry. Special chemical procedures were used to preconcentrate the elements of interest in the dissolved samples and separate them from the salt water matrix. The elemental concentrations observed in the dissolved samples were evaluated by direct comparison to those found in coastal seawater; however, the elemental concentrations in the particulate samples (mass per volume of water) were strongly influenced by the total amount of particulate material suspended in the water at time of collection. A double normalization procedure was used to calculate crustal enrichment factors for each sample, and these enrichment factors provided both a means to observe sample-to-sample variations, and also allowed a crude comparison with the natural levels occurring in the earth's crust.     

Threshold and dose response estimation using the “filter model”

The “filter model” has been developed to explain the biologic effects of radiation and chemicals. We have examined nearly 300 sets of dose response data, of which 50 are presented here. Responses (induced by radiation and chemicals) which have been examined include in vitro survival studies on animal and plant tissues, induction of cellular aberrations and time to tumor or death. Similar data from in vivo studies has also been examined. All of the data appear to fit the model R = a lnD + b(lnD)² + c, where R is the response, a and b are parameters fitted by regression to a particular set of data, and c is the response at zero (or lowest) dose. By writing this model in exponential form, it can be seen that the response R results from multistage filtering (by net amounts a and b) of the initial dose, D. The threshold is obtained from this model as the point, $\text{D}\text{?}{}_{\mathrm{T}}$, at which the second derivative becomes zero. This is given by $\text{D}\text{?}{}_{\mathrm{T}}\text{=}\text{exp}\text{(1 ?}\text{a}\text{2b}\text{)}$ when a and b are oppositelt signed.     

Fertility and air pollution: Some empirical findings

This paper attempts to explain regional differences in fertility rates in the standard metropolitan statistical areas of the United States through socioeconomic factors and air pollution. An important feature of this study is that it uses the most recent data pertaining to a homogeneous sample of observations within a country rather than using data for different countries. Statistical results suggest that given other factors, fertility and the level of air pollution have an inverse relationship. This quantitative effect is statistically significant but the absolute impact is rather low. Our results also suggest that an increase in the level of income, relative education of females, temperature, and the availability of physicians would in the long run reduce fertility rates in the urban areas of the United States.     

Health effects of oxidants

Oxidants of significance to human health include ozone, nitrogen dioxide, and peroxyacetylnitrate. All of these compounds are involved in complex photochemical reactions which makes quantification and prediction of their individual health effects difficult. Ozone causes trauma to lung tissues and interferes with enzyme systems in the lungs and other tissues causing a broad range of symptoms. Measurable health impacts can occur at concentrations as low as 390 μg/m³. Acute effects of ozone exposure are reversible at normal urban concentrations (80–120 μg/m³). A special problem of concern, however, is increased susceptibility to infectious diseases contracted through the lungs. Nitrogen dioxide also causes trauma to lung tissues and interferes with enzyme systems. Measurable impacts can occur at concentrations as low as 100 μg/m³, but recovery is rapid and it is not known whether repeated exposures at this level have cumulative effects or predispose the lungs to permanent damage. Chronic exposure of laboratory animals to higher nitrogen dioxide levels can cause emphysema-like conditions and reduction in resistance to respiratory infection. Epidemiological studies of children in houses with gas stoves confirm the finding of reduced resistance to respiratory infection. The U.S. EPA estimates that health effects may occur in young children exposed to concentrations in excess of 280 to 560 μg/m³ one-hour average. These concentrations occur routinely in houses having gas stoves. Peroxyacetylnitrate is a powerful eye irritant in photochemical smog. Other health effects are similar to those of ozone, but less important because of the relatively low concentrations of this pollutant compared to other oxidants.