Traffic and outdoor air pollution levels near highways in Baghdad,Iraq

In Iraq, the number of passenger cars, trucks and buses, local generators, and heavy construction equipment rose to a considerable extent since 2003, causing high environmental problems. Many types of pollutants were monitored and recorded for 24 h during March 2016. The study attempts to explore and establish a relationship between the volume of activity and the movement of motor vehicles of various compounds and contaminants resulting from their exhaust pipes, such as sulfur dioxide, particulate matters, oxides of nitrogen, VOCs, and unburned hydrocarbons. The study focused in and around Mohammad Al-Qasim highway adjacent to the University of Technology, Baghdad. The results showed the need for urgent treatments addressed by the environmental authorities in the city. The study results demonstrated that these contaminants are increased during periods of the beginning and end of working hours for government departments. Some types of sulfur compounds (H₂S and SO₂) concentrations were at serious health-threatening levels, which is a result of the high sulfur content in the Iraqi fuel. The concentrations of NOx and VOC were high, also, which could make the studied area vulnerable to the risk of smog formation. The Iraqi government should make greater efforts to protect the environment and human in this country from the transportation pollution risks.     

Energy–growth nexus revisited: an empirical application on transition countries

This study investigates the energy–growth nexus for transition countries analysing Granger causality between GDP growth per capita and energy use per capita. For this purpose, 17 countries located at Central and Eastern Europe and Caucasian region are chosen and a panel dataset consisting of these countries for the available period of 1990–2011 is studied. In the study, Granger causality is investigated using bootstrapped panel causality approach proposed by Konya (Econ Modell 23(6):978–992, 2006). The approach gives consistent results in case of cross-sectional dependency and heterogeneity of slope coefficients between countries. Causality is examined for two scenarios: one with a trend and one without a trend. The results reveal that, in general, there is no causality running between energy consumption and economic growth, yet there is causality running from energy consumption to economic growth for some countries and sign of the relationship is always negative. Therefore, increases in energy consumption harm economic growth.     

Sustainability indicators of water sharing compacts

There is an increasing crisis of fresh water availability throughout the world. Sharing the available water resources in a sustainable manner among numerous stakeholders in the backdrop of this crisis is more challenging. Very often water conflicts are triggered out in this challenging scenario. These conflicts are sometimes reconciled with compacts on sharing. Water sharing compacts on both surface and aquifer resources are very common. Whether these compacts are founded on postulates of sustainability is the important question we want to investigate. Conflicts resurface when the sustainability of a compact is at stake. In this paper, we are reviewing three compacts on surface water sharing to understand their sustainability perspectives and how it has helped addressing conflicts. An introduction to various legal instruments promulgated aiming water conflict abatement is given first. Different types of water sharing agreements being signed in the current water management practice are also looked into. Theoretical background of sustainability analysis, both quantitative and qualitative, applicable in the case of water sharing models is then discussed. This is followed by specific case study analysis of three interstate water sharing agreements executed in basins of different agro-climatic regions across the world. It includes the Colorado basin (USA), Murray Darling basin (Australia) and the Parambikulam Aliyar Project (PAP) basins (India). Interstate water sharing agreement of these basins is critically examined and compared to comment on its sustainability perspective. The Murray Darling basin and its compact appear to be better in its overall considerations of sustainability. Compared to Colorado and Murray Darling, PAP requires major revisions in its sustainability context. E flows and stochastic modeling are the thrust areas of PAP that require major revision.     

Resource Potentials and Limitations of A Nicaraguan Agricultural Region

Food production has to be increased in a sustainable way to meet the future global demand. A key position is attributed to developing countries. A deepened understanding of their agricultural regions with specific resource endowments and constraints is therefore crucial. In this study we propose a methodology based on material flux analysis (MFA) to assess the resource potentials and limitations of a Nicaraguan agricultural region. We focus on current regional and farm resource management and explore them under two scenarios. Indicators are nitrogen and the degrees of self-sufficiency (DSS) for energy, and the staples maize and beans. As data is scarce, most information is based on interviews with farmers of four categories and key persons, and on literature. The results show that nitrogen management does not differ considerably among categories. Nitrogen is mined mostly from staple plots. Self-sufficiency for beans is given in an average year. Yet, landless and small farmers neither produce enough maize for autoconsumption, nor are they self-sufficient for firewood. Energy supply is also the core problem of the region, since the DSS is 70%. Soil nitrogen stocks last at most for three more generations. Analyses with the scenario technique show that: (a) Unlimited population growth has serious consequences in the near future e.g. severe shortage of energy and food. (b) Alternative farming systems are possible, but they require reducing the population by a factor 2, and thus the creation of jobs in a Hinterland. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

Fate of ah receptor agonists during biological treatment of an industrial sludge containing explosives and pharmaceutical residues

GOAL, SCOPE AND BACKGROUND: Sweden is meeting prohibition for deposition of organic waste from 2005. Since 1 million tons of sludge is produced every year in Sweden and the capacity for incineration does not fill the demands, other methods of sludge management have to be introduced to a higher degree. Two biological treatment alternatives are anaerobic digestion and composting. Different oxygen concentrations result in different microbial degradation pathways and, consequently, in a different quality of the digestion or composting residue, It is therefore necessary to study sludge treatment during different oxygen regimes in order to follow both degradation of compounds and change in toxicity. In this study, an industrial sludge containing explosives and pharmaceutical residues was treated with anaerobic digestion or composting, and the change in toxicity was studied. Nitroaromatic compounds, which are the main ingredients of both pharmaceutical and explosives, are well known to cause cytotoxicity and genotoxicity. However, little data are available concerning sludge with nitroaromatics and any associated dioxin-like activity. Therefore, we studied the sludge before and after the treatments in order to detect any changes in levels of Ah receptor (AhR) agonists using two bioassays for dioxin-like compounds. METHODS: An industrial sludge was treated with anaerobic digestion or composting in small reactors in a semi-continuous manner. The same volume as the feeding volume was taken out daily and stored at -20 degrees C. Sample preparation for the bioassays was done by extraction using organic solvents, followed by clean up with silica gel or sulphuric acid, yielding two fractions. The fractions were dissolved in DMSO and tested in the bioassays. The dioxin-like activity was measured using the DR-CALUX assay with transfected H4IIE rat hepatoma pGudluc cells and an EROD induction assay with RTL-W1 rainbow trout liver cells. RESULTS AND DISCUSSION: The bioassays showed that the sludge contained AhR agonists at levels of TCDD equivalents (TEQs) higher than other sludge types in Sweden. In addition, the TEQ values for the acid resistant fractions increased considerably after anaerobic digestion, resulting in an apparent formation of acid resistant TEQs in the anaerobic reactors. Similar results have been reported from studies of fermented household waste. There was a large difference in effects between the two bioassays, with higher TEQ levels in the RTL-W1 EROD assay than in the DR-CALUX assay. This is possibly due to a more rapid metabolism in rat hepatocytes than in trout hepatocytes or to differences in sensitivities for the AhR agonists in the sludge. It was also demonstrated by GC/FID analysis that the sludge contained high concentrations of nitroaromatics. It is suggested that nitroaromatic metabolites, such as aromatic amines and nitroanilines, are possible candidates for the observed bioassay effects. It was also found that the AhR agonists in the sludge samples were volatile. CONCLUSIONS: The sludge contained fairly high concentrations of volatile AhR agonists. The increase of acid resistant AhR agonist after anaerobic digestion warrants further investigations of the chemical and toxic properties of these compounds and of the mechanisms behind this observation. RECOMMENDATION AND OUTLOOK: This study has pointed out the benefits of using different types of mechanism-specific bioassays when evaluating the change in toxicity by sludge treatment, in which measurement of dioxin-like activity can be a valuable tool. In order to study the recalcitrant properties of the compounds in the sludge using the DR-CALUX assay, the exposure time can be varied between 6 and 24 hours. The properties of the acid-resistant AhR agonists formed in the anaerobic treatment have to be investigated in order to choose the most appropriate method for sludge management.     

Healing the wounds in the landscape—reclaiming gravel roads in conservation areas

Reclaiming abandoned and unmaintained roads, built originally for forestry and mineral extraction, is an important part of ecological restoration, because the roads running through natural habitats cause fragmentation. The roads can be reclaimed in a passive way by blocking access to the road, but successful seedling recruitment may require additional management due to the physical constraints present at the road. We established a full factorial study to compare the effects of three road reclaiming measures, namely ripping, creation of safe sites by adding mulch and pine seed addition, on soil processes, recovery of understorey vegetation and seedling recruitment in three conservation areas in eastern Finland. We surveyed soil organic matter, frequency and cover of plant functional types, litter and mineral soil, and number of tree seedlings. The soil organic matter was, on average, 1.3-fold in the 50-cm-deep ripping treatment relative to unripped and 20-cm-deep ripping treatments. The germination and survival of deciduous seedlings and grass establishment were promoted by adding mulch. The addition of pine seeds counteracted the seed limitation and enhanced the regeneration of trees. The treatment combination consisting of ripping, adding mulch and pine seed addition enhanced the vegetation succession and tree-seedling recruitment most: the cover of grasses, herbs and ericaceous dwarf shrubs was 1.3–7.6-fold and the number of coniferous tree seedlings was 3.4–7.1-fold relative to the other treatment combinations. Differences between short-term (1–3 years) and longer-term (6 years) results indicate the need for a sufficient observation period in road reclamation studies.     

Estuarine circulation in the Taranto Seas

The Taranto basin is a shallow water marine system in the South of Italy characterized by the presence of a lagoon environment together with a semi-enclosed bay connected to the Ionian Sea. This marine system experienced over the last few decades strong biochemical pollution and environmental degradation, and it is considered a hotspot study site for economic, ecological and scientific reasons. The aim of this study was to examine, on an annual temporal scale and with high spatial resolution, the main hydrodynamical processes and transport scales of the system by means of a 3D finite element numerical model application, adopting the most realistic forcing available. The model allowed us to assess the role played by baroclinic terms in the basin circulation, describing its estuarine nature. In particular, the main features of water circulation, salinity and temperature distribution, water renewal time and bottom stress were investigated. Our results allowed us to equate this system dynamic to that of a weakly stratified estuary, identifying the main driving sources of this mechanism. The vertical stratification over the whole year was proved to be stable, leading to a dual circulation flowing out on the surface, mainly through Porta Napoli channel, and inflowing on the bottom mainly through Navigabile channel. This process was responsible also for the renewal time faster on the bottom of the Mar Piccolo basin than the surface. Due to the great importance of the Taranto basin for what concerns sediment pollution, also the effect of currents in terms of bottom stress was investigated, leading to the conclusion that only in the inlets area the values of bottom stress can be high enough to cause erosion.     

The application of regenerable sorbents for mercury capture in gas phase

Mercury is a well-known toxic element, and flue gas streams emitted from coal-fired utilities are one of the largest anthropogenic sources of this element. This study briefly reviews the proposed technologies for reducing mercury emissions from coal combustion, focusing on an emerging process which involves the use of regenerable sorbents and especially those loaded with noble metals. Among the mercury species formed during coal combustion, elemental mercury is the most difficult to remove from the flue gases due to its low reactivity and insolubility in water. The widespread interest in using regenerable sorbents with metals is due to their ability to retain elemental mercury. With this technology, not only can efficiencies of 100 % be reached in the retention of elemental mercury but also a way to avoid the generation of new wastes loaded with mercury. This study considers the main aspects that must be taken into account when developing effective regenerable sorbents for mercury capture, with special attention to sorbents containing noble metals. The characteristics of this process are compared with those of other processes in a more advanced state of development.     

Enhanced science–stakeholder communication to improve ecosystem model performances for climate change impact assessments

In recent years, climate impact assessments of relevance to the agricultural and forestry sectors have received considerable attention. Current ecosystem models commonly capture the effect of a warmer climate on biomass production, but they rarely sufficiently capture potential losses caused by pests, pathogens and extreme weather events. In addition, alternative management regimes may not be integrated in the models. A way to improve the quality of climate impact assessments is to increase the science–stakeholder collaboration, and in a two-way dialog link empirical experience and impact modelling with policy and strategies for sustainable management. In this paper we give a brief overview of different ecosystem modelling methods, discuss how to include ecological and management aspects, and highlight the importance of science–stakeholder communication. By this, we hope to stimulate a discussion among the science–stakeholder communities on how to quantify the potential for climate change adaptation by improving the realism in the models.