An assessment of the potential adverse properties of fluorescent tracer dyes used for groundwater tracing

The potential ecotoxicity of fluorescent dyes used in tracing, and their possible effects on human health, were evaluated by reviewing available toxicological information for 12 dyes — fluorescein, Lissamine Flavine FF, Rhodamine WT, Rhodamine B, Sulpho Rhodamine G, Sulpho Rhodamine B, eosin, pyranine, Phorwite BBH Pure, Tinopal 5BM GX, Tinopal CBS-X, and Diphenyl Brilliant Flavine 7GFF — and a dye-intermediate, amino G acid. This evaluation used available toxicological information, test data on analogous substances, and mathematical expressions for biological activity. Based on set criteria for human health and acute ecotoxicity, the evaluation indicated that these tracers have low to moderate levels of concern. The use of these tracers for the study of groundwater flow is appropriate if consideration is given to the overall human health and environmental effects. Their use in the environment requires tracer concentrations not exceeding 1–2 mg 1^–1 persisting for a period in excess of 24 h in the groundwater at the point of groundwater withdrawal or discharge. A simple calculated potential dose was used in a comparison of the estimated acute toxicity of Rhodamine WT in rats to the known acute oral toxic dose in humans for several known acutely toxic chemicals. This comparison showed that none of the fluorescent dyes evaluated would present an acutely toxic threat at or substantially above the recommended 2 mg 1^–1 concentration.The U.S. Governments right to retain a non-exclusive, royalty free licence in and to any copyright is acknowledged. Disclaimer: The views of this paper are solely those of the authors and do not necessarily reflect the views or policies of the U.S. Environmental Protection Agency.     

A 2.5‐million‐year perspective on coarse‐filter strategies for conserving nature's stage

Climate change will require novel conservation strategies. One such tactic is a coarse‐filter approach that focuses on conserving nature's stage (CNS) rather than the actors (individual species). However, there is a temporal mismatch between the long‐term goals of conservation and the short‐term nature of most ecological studies, which leaves many assumptions untested. Paleoecology provides a valuable perspective on coarse‐filter strategies by marshaling the natural experiments of the past to contextualize extinction risk due to the emerging impacts of climate change and anthropogenic threats. We reviewed examples from the paleoecological record that highlight the strengths, opportunities, and caveats of a CNS approach. We focused on the near‐time geological past of the Quaternary, during which species were subjected to widespread changes in climate and concomitant changes in the physical environment in general. Species experienced a range of individualistic responses to these changes, including community turnover and novel associations, extinction and speciation, range shifts, changes in local richness and evenness, and both equilibrium and disequilibrium responses. Due to the dynamic nature of species responses to Quaternary climate change, a coarse‐filter strategy may be appropriate for many taxa because it can accommodate dynamic processes. However, conservationists should also consider that the persistence of landforms varies across space and time, which could have potential long‐term consequences for geodiversity and thus biodiversity.     

Post-natal investigations: management and prognosis for fetuses with CNS anomalies identified in utero excluding neurosurgical problems

The suspicion of an abnormality of the central nervous (CNS) system raises difficult questions for the clinician and the family and will inevitably lead to considerable anxiety. These questions include what it means for the child's future, whether it can be treated and whether it will happen again in subsequent pregnancies. For many disorders accurate prenatal diagnosis remains elusive, as even with fetal magnetic resonance imaging (MRI), early recognition and characterisation are simply not possible because of the immature state of brain development at that stage of pregnancy. The natural history of many prenatally diagnosed CNS disorders remains to be elucidated which means that an accurate prognosis cannot be given in all cases. We review the current state of knowledge regarding the investigation, management and prognosis of the most common and important CNS malformations. We also discuss the post-natal management of these conditions both in the neonate and subsequent pregnancies for the families. Copyright © 2009 John Wiley & Sons, Ltd.     

Models for preserving species diversity with backup coverage

The problem of selecting land for preservation of species has been a rich and active area of research over the past two decades. Typically, reserve selection models have tried to maximize species diversity by preserving areas that contain the greatest number of species. However, several studies have shown that seldom do these species-rich areas contain the rarest species most in need of protection. Most reserve selection models seek to maximize diversity by choosing parcels so that all species are covered by or represented in at least one parcel. This approach would usually be expected to result in coverage by a single parcel for the rarest species, especially for those that do not coincide with more abundant species. It is precisely these rare species, however, that would be lost or whose survivability would be most challenged, if the single parcels in which they are represented became unavailable due to some unforeseen event. In this paper, we introduce to reserve selection models the concept of secondary, or backup, coverage of species. Briefly stated, a species is said to have backup representation in the system of reserves if it is covered by, or represented in, two or more parcels. Having backup coverage guarantees that every species is still covered in the event that a natural or man-made catastrophe makes a given parcel uninhabitable. The results show that backup coverage can be obtained at little additional cost (as expressed by the number of parcels selected). Bi-objective formulations that trade-off primary with backup coverage show that backup coverage can be guaranteed for larger numbers of species with little reduction in primary coverage.     

Development of an Ecologic Marine Classification in the New Zealand Region

We describe here the development of an ecosystem classification designed to underpin the conservation management of marine environments in the New Zealand region. The classification was defined using multivariate classification using explicit environmental layers chosen for their role in driving spatial variation in biologic patterns: depth, mean annual solar radiation, winter sea surface temperature, annual amplitude of sea surface temperature, spatial gradient of sea surface temperature, summer sea surface temperature anomaly, mean wave-induced orbital velocity at the seabed, tidal current velocity, and seabed slope. All variables were derived as gridded data layers at a resolution of 1 km. Variables were selected by assessing their degree of correlation with biologic distributions using separate data sets for demersal fish, benthic invertebrates, and chlorophyll-a. We developed a tuning procedure based on the Mantel test to refine the classification's discrimination of variation in biologic character. This was achieved by increasing the weighting of variables that play a dominant role and/or by transforming variables where this increased their correlation with biologic differences. We assessed the classification's ability to discriminate biologic variation using analysis of similarity. This indicated that the discrimination of biologic differences generally increased with increasing classification detail and varied for different taxonomic groups. Advantages of using a numeric approach compared with geographic-based (regionalisation) approaches include better representation of spatial patterns of variation and the ability to apply the classification at widely varying levels of detail. We expect this classification to provide a useful framework for a range of management applications, including providing frameworks for environmental monitoring and reporting and identifying representative areas for conservation.     

Sorption of heavy metals in strongly weathered soils: an overview

Current knowledge of sorption processes in tropical soils is reviewed. Landscapes throughout the tropics are dominated by oxisols which occupy extensive areas of potentially highly productive soils. These soils are dominated by low-activity sesquioxide minerals and clays that have variable charge surfaces. The limited information on tropical soils available suggests that the composition of the ambient soil solution can influence sorption through changes in particle surface-charge density. Thus the observed decrease in sorption in the presence of divalent index cations may be related to the effect of ionic charge on the double-layer thickness which is manifested through a change in surface-charge characteristics. However, much work needs to be done to differentiate the effect of cation charge on surface-charge density from the competitive effect between the index cation and heavy-metal ions for the sorption sites. The effects of inorganic and organic ligands on adsorption of Cd by variable charge surfaces are also reviewed.     

A 396-YEAR RECONSTRUCTION OF PRECIPITATION IN SOUTHERN JORDAN1

ABSTRACT: Water resources are the lifeblood of the Near East region. Careful planning and management of water resources in dry land regions requires information on the likelihood of extreme events, especially prolonged drought. It is essential to understand the variability of climate on time scales of decades to centuries to assign reasonable probabilities to such events. Tree-ring analysis is one way to increase our knowledge of the climate variability beyond the short period covered by the instrumental data. In this paper, we reconstruct October-May precipitation from a Juniperus phoenicia tree-ring chronology in southern Jordan to gain a long-term (A.D. 1600–1995) perspective on runs of dry years and on time series fluctuations in precipitation averaged over several years. The reconstruction equation derived by regression of log-transformed precipitation on tree-ring indices explains 44 percent of the variance of observed precipitation. The longest reconstructed drought, as defined by consecutive years below a threshold of 217.4 mm, was four years, compared with three years for the 1946–95 instrumental data. A Monte Carlo analysis designed to account for uncertainty in the reconstruction indicates a lower than 50 percent chance that the region has experienced drought longer than five years in the past 400 years.