Free-ranging dogs’ lifetime estimated by an approach for long-term survival data with dependent censoring

Environmental and Ecological Statistics - Populations of free-ranging dogs are still a matter of concern in developing countries. The presence of stray dogs is associated with environmental and...     

The regional impacts of small-scale gold mining in Amazonia

Gold mining is the major economic activity in the Upper Tapajós River Basin of the Brazilian Amazon. This article studies the structure, economy and impacts of gold mining operations in this region. Mining has significant environmental impacts in this region resulting in the removal of approximately 67 million m³ of sub-soil per year and accompanied by an annual release of some 12 tons of mercury to air, ground and rivers. In the early 1990s there were 245 mines in operation, employing some 30000 people and producing around 35t gold per year, valued at approximately $400 million yr^-1, the profits being about $110 million yr^-1. Miners spent most of their earnings on local goods and services, while mine owners and merchants in the gold towns invested in land (mainly for ranching), business ventures and money markets. Wealth gained from mining has served as an engine for development in other regions of the world and could, theoretically, achieve the same for Amazonia. However, before this could happen, the Government of Brazil would need to mark a strong presence in the area by providing technical assistance and developing and enforcing mining/environmental regulations. The likelihood of such a development materializing in the foreseeable future is small. In the meantime, gold mining acts, not as an 'engine for development', but as a destabilizing force — provoking environmental damage, social discord and public health hazards in the region.     

Bibliometric analysis of studies involving e-waste: a critical review

Environmental Science and Pollution Research - The correct destination of waste is an essential factor for sustainable development. Electronic waste, which is very toxic, is the type of waste with...     

Fishing sustainability via inclusion of man in predator-prey models: A case study in Lago Preto, Manacapuru, Amazonas

We modeled a fishery's system with two types of fishermen, commercial and subsistence fishermen, who exploit the fish stock at the Amazonian floodplain lakes. In the first model, we combined the Lotka-Volterra equations with Verhulst's Logistic model, by inserting hydrological cycle oscillations. The second model was based on the equations proposed by Berryman, which reflect the predator's functional response in relation to the prey's population behavior, taking into account the hydrological cycle. In both models, commercial fishermen and local direct consumers (called riverside dwellers - riverines - in the model), were considered the only predators acting upon fishing stocks. Primary data were collected in 48 riverside homes throughout 2006. The total number of interviewees corresponds to 69.6% of the universe of homes in the community defined as study area. The riverines were the predators that showed capacity to eliminate the opponent predators (commercial fishermen). The best scenery obtained regarding the number of prey, was the one that showed only commercial fishermen in the region. On the other hand, the simulations show that the coexistence is possible among predators, and between predators and their prey. The seasonal model with functional response provides a better response in relation to the system's current situation and to the established modeling conditions than the Lotka-Volterra seasonal model. The seasonal model with functional response also showed a better response pattern in all scenarios, with oscillations taking place more gradually, both for variations associated with the flooding pulse and for relations between predators and prey.     

Extent of sonochemical degradation and change of toxicity of a pharmaceutical precursor (triphenylphosphine oxide) in water as a function of treatment conditions

The degradation of triphenylphosphine oxide (TPPO) in water, a toxic compound typically found in effluents from the pharmaceutical industry, by means of ultrasonic irradiation at 20 kHz has been investigated with emphasis on the effect of various parameters on conversion and acute toxicity. Experiments were carried out at liquid volumes of 50 and 80 ml, electric power outputs of 125, 187.5 and 250 W, initial TPPO concentrations of 10, 100 and 350 mg/L and temperatures of 5, 20, 35, 50 and 70 degrees C. TPPO conversion was found to increase with increasing power output and decreasing initial concentration and temperature. Measurements of dissolved total carbon showed that liquid-phase degradation by-products were more stable to ultrasonic irradiation than TPPO. Addition of t-butanol as a radical scavenger at a concentration of 1000 mg/L nearly completely suppressed TPPO degradation. Conversely, addition of radical promoters (Fe(2+) ions or H(2)O(2)) had a positive effect on degradation. Acute toxicity to marine bacteria vibrio fischeri was measured before and after ultrasonic irradiation. At the conditions employed in this study, irradiated TPPO samples were always more toxic than TPPO itself with toxicity levels being a function of treatment conditions.     

A comparative study for results obtained using biomonitors and PM10 collectors in Sado Estuary

In 1996 a program was started, financed by the Environmental Ministry of Portugal and IAEA, aiming to study the inorganic atmospheric pollutant dispersion in Sado Estuary. Gent PM10 air samplers were used for air particulate matter sampling. Three sampling sites were chosen, forming a triangle around the fuel power station of Setúbal. Transplants of Parmelia sulcata Taylor were suspended in nylon bags within a rectangle 15 km wide and 25 km long on a 2.5 x 2.5 km grid. Two sets of four transplants were hung in each of the 47 locations, one set facing the wind and the other set opposing the wind. The transplants were suspended in December 1997 for a 1-year period; every 3 months, one transplant of each set was collected. Both lichen transplants and PM10 filters were analysed by INAA and PIXE. A comparative study of results obtained for the two sampling procedures is presented in this work.     

Removal of toxic metals from solution by leaf, stem and root phytomass of Quercus ilex L. (holly oak)

Increased consciousness for safeguarding the aqueous environment has prompted a search for alternative technologies for the removal of toxic metal ions from aqueous solutions. In this regard, a wide variety of biomass is being considered as adsorbents of heavy metals for treatment of industrial and domestic wastewaters as well as natural waters, including drinking water. In the present investigation, the potential of Quercus ilex phytomass from stem, leaf and root as an adsorbent of chromium (Cr), nickel (Ni), copper (Cu), cadmium (Cd) and lead (Pb) at ambient temperature was investigated. The metal uptake capacity of the root for different metals was found to be in the order: Ni>Cd>Pb>Cu>Cr; stem Ni>Pb>Cu>Cd>Cr; and leaf Ni>Cd>Cu>Pb>Cr. The highest amount adsorbed was Ni (root>leaf>stem). Data from this laboratory demonstrated that Ni is sequestered mostly in the roots, where concentrations can be as high as 428.4 ng/g dry wt., when 1-year-old seedlings were treated with Ni (2000 mg/l) in pot culture experiments, compared to 7.63 ng/g dry wt., control (garden and greenhouse soil) topsoil where Ni was present in trace amounts. This proves that the root biomass of Q. ilex has the capacity for complexing Ni. Cr exhibited the least adsorption values for all the three types of phytomass compared to other metals. The trend of adsorption of the phytomass was similar for Ni and Cd, i.e. root>leaf>stem. Desorption with 10 mM Na(4) EDTA was effective (55-90%) and, hence, there exists the possibility of recycling the phytomass. The biosorption results of recycled phytomass suggest that the selected adsorbents are re-usable. The advantages and potential of the Q. ilex phytomass as a biofilter of toxic trace metals, the scope and need for enhancing the efficiency of the Q. ilex phytomass as an adsorbent of metals are presented.     

Gravimetric and Chemical Features of Airborne PM10 AND PM2.5 in Mainland Portugal

This paper describes concentration amounts of arsenic (As), particulate mercury (Hg), nickel (Ni) and lead (Pb) in PM₁₀ and PM_2.5, collected since 1993 by the Technological and Nuclear Institute (ITN) at different locations in mainland Portugal, featuring urban, industrial and rural environments, and a control as well. Most results were obtained in the vicinity of coal- and oil-fired power plants. Airborne mass concentrations were determined by gravimetry. As and Hg concentrations were obtained through instrumental neutron activation analysis (INAA), and Ni and Pb concentrations through proton-induced X-ray emission (PIXE). Comparison with the EU (European Union) and the US EPA (United States Environmental Protection Agency) directives for Ambient Air has been carried out, even though the sampling protocols herein – set within the framework of ITN's R&D projects and/or monitoring contracts – were not consistent with the former regulations. Taking this into account, 1) the EU daily limit for PM₁₀ was exceeded a few times in all sites except the control, even if the number of times was still inferior to the allowed one; 2) the EU annual mean for PM₁₀ was exceeded at one site; 3) the EPA daily limit for PM_2.5 was exceeded one time at three sites; 4) the EPA annual mean for PM_2.5 was exceeded at most sites; 5) the inner-Lisboa site approached or exceeded the legislated PMs; 6) Pb levels stayed far below the EU limit value; and 7) concentrations of As, Ni and Hg were also far less than the reference values adopted by EU. In every location, Ni appeared more concentrated in PM_2.5 than in coarser particles, and its levels were not that different from site to site, excluding the control. The highest As and Hg concentrations were found in the neighbourhood of the coal-fired, utility power plants. The results may be viewed as a “worst-case scenario” of atmospheric pollution, since they have been obtained in busy urban-industrial areas and/or near major power-generation and waste-incineration facilities.     

Ant–plant–herbivore interactions in the neotropical cerrado savanna

The Brazilian cerrado savanna covers nearly 2 million km² and has a high incidence on foliage of various liquid food sources such as extrafloral nectar and insect exudates. These liquid rewards generate intense ant activity on cerrado foliage, making ant–plant–herbivore interactions especially prevalent in this biome. We present data on the distribution and abundance of extrafloral nectaries in the woody flora of cerrado communities and in the flora of other habitats worldwide, and stress the relevance of liquid food sources (including hemipteran honeydew) for the ant fauna. Consumption by ants of plant and insect exudates significantly affects the activity of the associated herbivores of cerrado plant species, with varying impacts on the reproductive output of the plants. Experiments with an ant–plant–butterfly system unequivocally demonstrate that the behavior of both immature and adult lepidopterans is closely related to the use of a risky host plant, where intensive visitation by ants can have a severe impact on caterpillar survival. We discuss recent evidence suggesting that the occurrence of liquid rewards on leaves plays a key role in mediating the foraging ecology of foliage-dwelling ants, and that facultative ant–plant mutualisms are important in structuring the community of canopy arthropods. Ant-mediated effects on cerrado herbivore communities can be revealed by experiments performed on wide spatial scales, including many environmental factors such as soil fertility and vegetation structure. We also present some research questions that could be rewarding to investigate in this major neotropical savanna.