Secondary organic aerosol production from aqueous photooxidation of glycolaldehyde: Laboratory experiments

Organic particulate matter (PM) formed in the atmosphere (secondary organic aerosol; SOA) is a substantial yet poorly understood contributor to atmospheric PM. Aqueous photooxidation in clouds, fogs and aerosols is a newly recognized SOA formation pathway. This study investigates the potential for aqueous glycolaldehyde oxidation to produce low volatility products that contribute SOA mass. To our knowledge, this is the first confirmation that aqueous oxidation of glycolaldehyde via the hydroxyl radical forms glyoxal and glycolic acid, as previously assumed. Subsequent reactions form formic acid, glyoxylic acid, and oxalic acid as expected. Unexpected products include malonic acid, succinic acid, and higher molecular weight compounds, including oligomers. Due to (1) the large source strength of glycolaldehyde from precursors such as isoprene and ethene, (2) its water solubility, and (3) the aqueous formation of low volatility products (organic acids and oligomers), we predict that aqueous photooxidation of glycolaldehyde and other aldehydes in cloud, fog, and aerosol water is an important source of SOA and that incorporation of this SOA formation pathway in chemical transport models will help explain the current under-prediction of organic PM concentrations.     

The making of fetal surgery

Fetal diagnosis prompts the question for fetal therapy in highly selected cases. Some conditions are suitable for in utero surgical intervention. This paper reviews historically important steps in the development of fetal surgery. The first invasive fetal intervention in 1963 was an intra-uterine blood transfusion. It took another 20 years to understand the pathophysiology of other candidate fetal conditions and to develop safe anaesthetic and surgical techniques before the team at the University of California at San Francisco performed its first urinary diversion through hysterotomy. This procedure would be abandoned as renal and pulmonary function could be just as effectively salvaged by ultrasound-guided insertion of a bladder shunt. Fetoscopy is another method for direct access to the feto-placental unit. It was historically used for fetal visualisation to guide biopsies or for vascular access but was also abandoned following the introduction of high-resolution ultrasound. Miniaturisation revived fetoscopy in the 1990s, since when it has been successfully used to operate on the placenta and umbilical cord. Today, it is also used in fetuses with congenital diaphragmatic hernia (CDH), in whom lung growth is triggered by percutaneous tracheal occlusion. It can also be used to diagnose and treat urinary obstruction. Many fetal interventions remain investigational but for a number of conditions randomised trials have established the role of in utero surgery, making fetal surgery a clinical reality in a number of fetal therapy programmes. The safety of fetal surgery is such that even non-lethal conditions, such as myelomeningocoele repair, are at this moment considered a potential indication. This, as well as fetal intervention for CDH, is currently being investigated in randomised trials. Copyright © 2010 John Wiley & Sons, Ltd.     

Transmission of employment shocks before and after the Oklahoma City tornado

This study examined the economic impact of the May 3, 1999 Oklahoma tornado outbreak on the labor markets of Oklahoma City (OK), Wichita (KS), and Kansas City (MO). In particular, this article examines the transmission of shocks to employment growth across these different labor markets. Using monthly employment data from January 1990 to December 2004, we provide empirical evidence on the cross-market relationships that existed before and after the Oklahoma City tornado. The results suggest that the impact of the wind event may have altered labor market dynamics in Oklahoma City, as well as Wichita and Kansas City.     

Steel consumption and economic activity in the UK: The integration and cointegration debate

This research examines whether a long-run stationary equilibrium relationship holds between economic activity and the consumption of crude steel within the UK. Using the theory of fractionally integrated and cointegrated processes, and allowing for the possibility that the equilibrium path changes abruptly at occasional points in time, it is possible to determine if steel consumption and economic activity follow a common stochastic trend or whether the two series randomly drift apart over time. Evidence is found to support such a long term relationship. This result is at odds with the conclusions drawn by previous researchers in the area. The reason for this difference may be due to these researchers concentrating only on I(0) and I(1) specifications, without consideration of fractional possibilities and also to a failure to account for structural breaks in the equilibrium relationship. Such conclusions are made within the framework of the ARFIMA methodology that yields reliable inferences on the degree of fractional integration and cointegration. Critical values for fractional contegration with an ARFIMA model in the presence of structural breaks are also derived in this paper.     

Relative proportions of polycyclic aromatic hydrocarbons differ between accumulation bioassays and chemical methods to predict bioavailability

Chemical methods to predict the bioavailable fraction of organic contaminants are usually validated in the literature by comparison with established bioassays. A soil spiked with polycyclic aromatic hydrocarbons (PAHs) was aged over six months and subjected to butanol, cyclodextrin and tenax extractions as well as an exhaustive extraction to determine total PAH concentrations at several time points. Earthworm (Eisenia fetida) and rye grass root (Lolium multiflorum) accumulation bioassays were conducted in parallel. Butanol extractions gave the best relationship with earthworm accumulation (r² ≤ 0.54, p ≤ 0.01); cyclodextrin, butanol and acetone-hexane extractions all gave good predictions of accumulation in rye grass roots (r² ≤ 0.86, p ≤ 0.01). However, the profile of the PAHs extracted by the different chemical methods was significantly different (p < 0.01) to that accumulated in the organisms. Biota accumulated a higher proportion of the heavier 4-ringed PAHs. It is concluded that bioaccumulation is a complex process that cannot be predicted by measuring the bioavailable fraction alone.     

Near‐Surface Disposal Performance Assessment: Modeling Monthly Precipitation and Temperature in Various Climate Environments

A more stable and extensive analysis of climate is necessary to simulate long‐term impacts associated with climate change. The exponential dispersion model (EDM) family of distributions, a popular choice when characterizing precipitation levels and temperature in different climate environments, is being considered for its applicability to near‐surface disposal performance assessments. In this study, the EDM family is examined to determine if there is a preferred distributional form within the family for these parameters using data from two sites whose climate environments are quite different. One site is in a semiarid environment and the other is in a humid environment. In addition, the merits of selecting a different distributional form to represent each calendar month of precipitation and temperature data are explored. Results show that the gamma distribution was most often determined to be the best fit to recorded precipitation data. When considering temperature, however, the Weibull distribution proved to be a better fit. These results suggest that greater precision may be possible when temperature and precipitation serve as inputs to modeling activities, if these parameters are allowed to be represented by different distributions and derived by calendar month. Ultimately, the approach provides a more far‐reaching examination of historical records and provides an increase in confidence, when used in the evaluation of long‐term climate impacts associated with near‐surface disposal facilities. © 2013 Wiley Periodicals, Inc.     

The Perceived Implications of an Outsourcing Model on Governance within British Columbia Provincial Parks in Canada: A Quantitative Study

Good governance is of paramount importance to the success of parks and protected areas. This research utilized a questionnaire for 10 principles of governance to evaluate the outsourcing model used by British Columbia Provincial Parks, where profit-making corporations provide all front country visitor services. A total of 246 respondents representing five stakeholder groups evaluated the model according to each principle, using an online survey. Principal component analysis resulted in two of the 10 principles (equity and effectiveness) each being split into two categories, leading to 12 governance principles. Five of the 12 criteria received scores towards good governance: effectiveness outcome; equity general; strategic vision; responsiveness; and effectiveness process. One criterion, public participation, was on the neutral point. Six criteria received scores below neutral, more towards weak governance: transparency; rule of law; accountability; efficiency; consensus orientation; and, equity finance. The five stakeholder groups differed significantly on 10 of the 12 principles (P < .05). The 2 exceptions were for efficiency and effectiveness process. Seven of the 12 criteria followed a pattern wherein government employees and contractors reported positive scores, visitors and representatives of NGOs reported more negative scores, and nearby residents reported mid-range scores. Three criteria had government employees and contractors reporting the most positive scores, residents and visitors the most negative scores, and NGO respondents reporting mid-range scores. This research found evidence that perceptions of governance related to this outsourcing model differed significantly amongst various constituent groups.     

Collective guilt mediates the effect of beliefs about global warming on willingness to engage in mitigation behavior

The present research examines whether collective guilt for an ingroup's collective greenhouse gas emissions mediates the effects of beliefs about the causes and effects of global warming on willingness to engage in mitigation behavior. In Study 1, we manipulate the causes and effects of global warming and then measure collective guilt. Results demonstrate that collective guilt for Americans' greenhouse gas emissions is stronger when participants believe that global warming is caused by humans and will have minor effects. Study 2 employs the same manipulations and then measures collective guilt and collective anxiety, as well as willingness to conserve energy and pay green taxes. This study replicates the effect from Study 1 and rules out collective anxiety as a plausible alternative mediator. Collective guilt for Americans' greenhouse emissions was the only reliable mediator of the effect of beliefs about global warming on willingness to engage in mitigation behaviors. The importance of collective guilt as a tool for promoting global warming mitigation is discussed.     

Compliance with and ecosystem function of biodiversity offsets in North American and European freshwaters

Land-use change via human development is a major driver of biodiversity loss. To reduce these impacts, billions of dollars are spent on biodiversity offsets. However, studies evaluating offset project effectiveness that examine components such as the overall compliance and function of projects remain rare. We reviewed 577 offsetting projects in freshwater ecosystems that included the metrics project size, type of aquatic system (e.g., wetland and creek), offsetting measure (e.g., enhancement, restoration, and creation), and an assessment of the projects’ compliance and functional success. Project information was obtained from scientific and government databases and gray literature. Despite considerable investment in offsetting projects, crucial problems persisted. Although compliance and function were related to each other, a high level of compliance did not guarantee a high degree of function. However, large projects relative to area had better function than small projects. Function improved when projects targeted productivity or specific ecosystem features and when multiple complementary management targets were in place. Restorative measures were more likely to achieve targets than creating entirely new ecosystems. Altogether the relationships we found highlight specific ecological processes that may help improve offsetting outcomes.