Phytoplankton patterns along a series of small man-made reservoirs in Kenya

We studied nine small man-made reservoirs located in different climate regions of Kenya to get an insight into the relationship between phytoplankton community structure and its environment. The investigated ponds form three groups of three reservoirs each found in the rural areas of Machakos district, Mount Kenya region, and Lake Victoria area with varied climatic characteristics. The ponds were sampled in monthly intervals between May 2007 and June 2008 for physicochemical variables including water chemistry, phytoplankton community composition, zooplankton abundance, and bacterial numbers. All ponds were classified as hypertrophic. Seasonal changes were reflected in the phytoplankton pattern, as all ponds showed a community shift after the short dry season in February. Due to high nutrient loads and increased turbidity, Cyanobacteria, which were initially thought to be predominating in all investigated water bodies, were found to play only a minor role except for the Bomet reservoir in Lake Victoria region. Instead, Chloro- and Streptophyta, Dinophyta, and Euglenophyta were abundant in the pelagial. A principal component analysis explained around 85 % of the data variance with four principal components (PCs) interpreted as “location”, “ions”, “zooplankton”, and “particulate matter”. A clear separation of ponds with and without cattle access based on algal species community data was found indicating the need for a sustainable use and regular monitoring program as the local population is largely dependent on these sensitive small-scale ecosystems.     

The relationship between country and individual household wealth and climate change concern: the mediating role of control

The relationship between wealth and climate change concern has been a focus of several studies. In this article, we hypothesize that richer households (and countries) are less concerned about climate change because wealth provides a buffer against some of the related risks. This leads people in wealthier countries and households to perceive a greater sense of control over climate change impacts, which in turn results in lower levels of concern. We tested this hypothesis using a unique household survey encompassing 11 OECD countries and over 10,000 households and applying mixed multi-level regression models. Our results confirmed a statistically significant negative relationship between country and household wealth and individuals’ perceptions of the seriousness of climate change. This study contributes to current literature by showing that this relationship is mediated through sense of control, measured at the country level by the country’s readiness index and at the individual household level by the extent of adoption of energy efficiency improvements. These findings raise the question of how best to incentivize action on climate change amongst those with the ability—but not necessarily the motivation—to respond.

     

Modelling the connection between energy consumption and carbon emissions in North Africa: Evidence from panel models robust to cross-sectional dependence and slope heterogeneity

Environment, Development and Sustainability - This paper explored the link between energy consumption and carbon emissions in North Africa through an Environmental Kuznets Curve (EKC) framework....     

Development and testing a diagnostic capacity tool for improving socio-ecological system governance

The capacity to sustainably govern complex socio-ecological systems (SES) has been identified as a necessary but daunting task by SES scholars, resource stewards and stakeholders. This research sought to inform the question: What are determinant capacities and functional linkages that can be incorporated into diagnostic tools for analysts seeking to improve sustainable socio-economic system SES governance? Literature was used to identify and translate determinant capacities and functional linkages into a quantifiable metric of governance quality. The tool was developed from ecological, business, governance and decision science literature. This tool recognizes the dynamic and systemic linkages between the resources and the social systems that use and govern them for improving systems thinking and SES outcomes. The tool was tested to determine its ability to capture perceived characteristics of governance quality and problem management using Michigan’s cleanup and redevelopment program. The results of this research indicated that the exploratory tool was reliable and valid. This research contributes to the evolving body of SES frameworks, specifically the study of individual and organizational capacities for improved SES outcomes. The implications of this research suggest participatory network-based governance with higher levels of resource exchange, in the form of interdependency, trust, diplomacy and reciprocity, aligns with practitioners’ perceptions of improved program performance. Further, while some capacities and related findings of this research may be context specific, concepts associated with the development and testing of this diagnostic tool, such as the use of systems thinking, participatory network-based governance, and related competencies, may have more universal application.     

Moving dirt: soil,lead, and the dynamic spatial politics of urban gardening

Urban gardens are often heralded as places for building social, physical, and environmental health. Yet they are also sites of significant conflict based on competing political, economic, and ecological projects. These projects range from radical re-envisionings of liberatory urban spaces, reformist aesthetic and sanitary improvement programmes, to underwriting the production of the neo-liberal city. These projects are based on divergent visions of the garden ground itself, in particular, whether this is soil (the fertile and living source for growing food and social values) or dirt (an inert and even problematic substrate to be removed or built upon for development purposes). These are not fixed or mutually exclusive categories, but are unstable as soil/dirt moves in discursive and material ways over time and space. Contaminants such as lead in the soil contribute to this instability, reframing fertile soil as dangerous dirt. To understand this discursive and material movement of soil/dirt over time and space, a dynamic spatial politics framework is needed that encompasses three scalar concepts: location, duration, and interconnection. This paper applies this dynamic spatial politics framework to interpret the 30-year conflict over the fate of an urban garden in Sacramento, California, that began as a countercultural space and was eventually transformed into a manicured amenity for a gentrifying neighbourhood, and the role of soil lead contamination in this narrative.     

Dealing With Uncertainty When Assessing Fish Passage Through Culvert Road Crossings

Assessing the passage of aquatic organisms through culvert road crossings has become increasingly common in efforts to restore stream habitat. Several federal and state agencies and local stakeholders have adopted assessment approaches based on literature-derived criteria for culvert impassability. However, criteria differ and are typically specific to larger-bodied fishes. In an analysis to prioritize culverts for remediation to benefit imperiled, small-bodied fishes in the Upper Coosa River system in the southeastern United States, we assessed the sensitivity of prioritization to the use of differing but plausible criteria for culvert impassability. Using measurements at 256 road crossings, we assessed culvert impassability using four alternative criteria sets represented in Bayesian belief networks. Two criteria sets scored culverts as either passable or impassable based on alternative thresholds of culvert characteristics (outlet elevation, baseflow water velocity). Two additional criteria sets incorporated uncertainty concerning ability of small-bodied fishes to pass through culverts and estimated a probability of culvert impassability. To prioritize culverts for remediation, we combined estimated culvert impassability with culvert position in the stream network relative to other barriers to compute prospective gain in connected stream habitat for the target fish species. Although four culverts ranked highly for remediation regardless of which criteria were used to assess impassability, other culverts differed widely in priority depending on criteria. Our results emphasize the value of explicitly incorporating uncertainty into criteria underlying remediation decisions. Comparing outcomes among alternative, plausible criteria may also help to identify research most needed to narrow management uncertainty.     

Biological monitoring of chlorpyrifos exposure to rice farmers in Vietnam

Chlorpyrifos is the most common organophosphate insecticide registered for use in Vietnam and is widely used in agriculture, particularly rice farming. However, chlorpyrifos exposure to and adverse effects on farmers has not been evaluated. In this study, biological monitoring of chlorpyrifos exposure in a group of rice farmers was conducted after a typical application event using back-pack spraying.Urine samples (24 h) were collected from the rice farmers before and post insecticide application. Samples were analysed for 3,5,6-trichloropyridinol (TCP), the major urinary metabolite of chlorpyrifos, using an enzymatic pre-treatment before extraction followed by HPLC-MS/MS. Absorbed Daily Dose (ADD) of chlorpyrifos for farmers were then estimated from urinary TCP levels, expressed as μg g⁻¹ creatinine. The analytical method for urinary TCP had a low detection limit (0.6 μg L⁻¹), acceptable recovery values (80-114%), and low relative percentage differences in duplicate and repeated samples.Post-application chlorpyrifos ADD of farmers varied from 0.4 to 94.2 μg kg⁻¹ (body weight) d⁻¹ with a mean of 19.4 μg kg⁻¹ d⁻¹ which was approximately 80-fold higher than the mean baseline exposure level (0.24 μg kg⁻¹ d⁻¹). Hazard Quotients (ratio of the mean ADD for rice farmers to acute oral reference dose) calculated using acute oral reference doses recommended by United States and Australian agencies varied from 2.1 (Australian NRA), 4.2 (US EPA) to 6.9 (ATSDR).Biological monitoring using HPLC-MS/MS analysis of urinary TCP (24 h) was found to be an effective method for measuring chlorpyrifos exposure among farmers. This case study found that Vietnamese rice farmers had relatively high exposures to chlorpyrifos after application, which were likely to have adverse health effects.     

Bioaccumulation of butyltins and liver damage in the demersal fish Cathorops spixii (Siluriformes,Ariidae)

The toxicity of butyltin compounds (BTs), mainly tributyltin (TBT), has been reported in different organisms. However, such an analysis in fish after field exposure with reference to the related biomarkers has not been commonly observed in the literature. This study presents the uptake of BTs in the liver of a neotropical marine catfish Cathorops spixii in Paranagua Bay, an important estuarine system located in southern Brazil. Two different areas, close to and distant from the harbor, were used for chemical analysis evaluation of hepatotoxicity through genetic, enzymatic, and histopathological biomarkers. The presence of polycyclic aromatic hydrocarbons in bile was also considered as a biomarker. The results showed a significant relationship between TBT levels and the inhibition of biotransformation enzymes and high occurrence of melanomacrophages in fish collected close to the harbor site. These effects were linked to the absence of TBT metabolites in the liver. In the second site, the presence of DBT was associated with an increase in EROD and GST activity. The larger amount of DNA damage as well as the highest oxidative stress was noted in fish from the less TBT-polluted area, where DBT and bile PAHs occurred. These findings showed different impact levels due to or increased by the chronic exposure of biota to BTs.     

Developing slow-release persulfate candles to treat BTEX contaminated groundwater

The development of slow-release chemical oxidants for sub-surface remediation is a relatively new technology. Our objective was to develop slow-release persulfate-paraffin candles to treat BTEX-contaminated groundwater. Laboratory-scale candles were prepared by heating and mixing Na₂S₂O₈ with paraffin in a 2.25 to 1 ratio (w/w), and then pouring the heated mixture into circular molds that were 2.38 cm long and either 0.71 or 1.27 cm in diameter. Activator candles were prepared with FeSO₄ or zerovalent iron (ZVI) and wax. By treating benzoic acid and BTEX compounds with slow-release persulfate and ZVI candles, we observed rapid transformation of all contaminants. By using ¹⁴C-labeled benzoic acid and benzene, we also confirmed mineralization (conversion to CO2) upon exposure to the candles. As the candles aged and were repeatedly exposed to fresh solutions, contaminant transformation rates slowed and removal rates became more linear (zero-order); this change in transformation kinetics mimicked the observed dissolution rates of the candles. By stacking persulfate and ZVI candles on top of each other in a saturated sand tank (14 × 14 × 2.5 cm) and spatially sampling around the candles with time, the dissolution patterns of the candles and zone of influence were determined. Results showed that as the candles dissolved and persulfate and iron diffused out into the sand matrix, benzoic acid or benzene concentrations (C_o = 1 mM) decreased by >90% within 7 d. These results support the use of slow-release persulfate and ZVI candles as a means of treating BTEX compounds in contaminated groundwater.     

Kinetics of the oxidation of sucralose and related carbohydrates by ferrate(VI)

The kinetics of the oxidation of sucralose, an emerging contaminant, and related monosaccharides and disaccharides by ferrate(VI) (Fe(VI)) were studied as a function of pH (6.5-10.1) at 25°C. Reducing sugars (glucose, fructose, and maltose) reacted faster with Fe(VI) than did the non-reducing sugar sucrose or its chlorinated derivative, sucralose. Second-order rate constants of the reactions of Fe(VI) with sucralose and disaccharides decreased with an increase in pH. The pH dependence was modeled by considering the reactivity of species of Fe(VI), (HFeO(4)(-) and FeO(4)(2-)) with the studied substrates. Second-order rate constants for the reaction of Fe(VI) with monosaccharides displayed an unusual variation with pH and were explained by considering the involvement of hydroxide in catalyzing the ring opening of the cyclic form of the carbohydrate at increased pH. The rate constants for the reactions of carbohydrates with Fe(VI) were compared with those for other oxidant species used in water treatment and were briefly discussed.