EPA SITE Demonstration of the BioTrol Soil Washing Process

A pilot-scale soil washing process, patented by BioTrol, Inc., was demonstrated on soil contaminated by wood treating waste, primarily pentachlorophenol (PCP) and creosote-derived polynuclear aromatic hydrocarbons (PAHs). Although soil washing was the main object of this demonstration, the treatment train that was evaluated included two other BioTrol technologies for treatment of waste streams from the soil washer. The three technologies were: ? The BioTrol Soil Washer (BSW)—a volume reduction process, which uses water to separate contaminated soil fractions from the bulk of the soil.

? The BioTrol Aqueous Treatment System (BATS)—a biological water treatment process.

? The Slurry Bioreactor (SBR)—a BioTrol biological slurry treatment process conducted in an EIMCO BIOLIFT^tm reactor.

The sandy soil at the site, consisting of less than 10 percent of fines, was well suited for treatment by soil washing. The soil washer was evaluated in two tests on soil samples containing 130 ppm and 680 ppm of PCP, respectively.

The BSW successfully separated the feed soil (dry weight basis) into 83 percent of washed soil, 10 percent of woody residues, and 7 percent of fines. The washed soil retained about 10 percent of the feed soil contamination while 90 percent of the feed soil contamination was contained within the woody residues, fines, and process water.

The soil washer achieved up to 89 percent removal of PCP and 88 percent of total PAHs, based on the difference between their levels in the as-is (wet) feed soil and the washed soil. PCP concentrations of 14 ppm and 87ppm in the washed soil were achieved from PCP concentrations of 130 ppm and 680ppm in the feed soil. Concentrations of total PAHs were reduced from 247 ppm to 42 ppm and 404 ppm to 48 ppm, respectively, in the two tests.

The BATS degraded up to 94 percent of PCP in the process water from soil washing. PAH removal could not be determined due to low influent concentrations.

The SBR achieved over 90 percent removals of PCP and 70 to 90 percent removals of PAHs from the slurry of contaminated fines from soil washing. However, steady state operation was not achieved during the single test and the results were variable.

Cost of a commercial-scale soil washing, assuming use of all three technologies, was estimated to be $168 per ton of soil treated. Incineration of woody material accounts for 76 percent of the cost.     

The Use of Health Risk Assessment to Estimate Desirable Sampling Detection Limits

Abstract

The inclusion of non-detected chemicals in a health risk assessment may lead, in some cases, to estimated risks that exceed regulatory thresholds, because one must use the detection limit or half of the detection limit. This study presents a methodology which will allow one to estimate appropriate detection limits by conducting a health risk assessment prior to the source sampling program. The advantages and shortcomings of various levels of detail in the risk assessment to determine those detection limits are discussed. The application of the methodology is demonstrated with a case study of the potential health effects of power plant stack emissions.     

Airborne Emissions of Mercury from Municipal Solid Waste. I: New Measurements from Six Operating Landfills in Florida

Abstract

Mercury-bearing material enters municipal landfills from a wide array of sources, including fluorescent lights, batteries, electrical switches, thermometers, and general waste; however, the fate of mercury (Hg) in landfills has not been widely studied. Using automated flux chambers and downwind atmospheric sampling, we quantified the primary pathways of Hg vapor releases to the atmosphere at six municipal landfill operations in Florida. These pathways included landfill gas (LFG) releases from active vent systems, passive emissions from landfill surface covers, and emissions from daily activities at each working face (WF). We spiked the WF at two sites with known Hg sources; these were readily detected downwind, and were used to test our emission modeling approaches. Gaseous elemental mercury (Hg⁰) was released to the atmosphere at readily detectable rates from all sources measured; rates ranged from ～1–10 ng m^?2 hr^?1 over aged landfill cover, from ～8–20 mg/hr from LFG flares (LFG included Hg⁰ at μg/m³ concentrations), and from ～200–400 mg/hr at the WF. These fluxes exceed our earlier published estimates. Attempts to identify specific Hg sources in excavated and sorted waste indicated few readily identifiable sources; because of effective mixing and diffusion of Hg⁰, the entire waste mass acts as a source. We estimate that atmospheric Hg releases from municipal landfill operations in the state of Florida are on the order of 10–50 kg/yr, substantially larger than our original estimates, but still a small fraction of current overall anthropogenic losses.     

Power,Fairness and Constrained Choice in Agricultural Markets: A Synthesizing Framework

The (un)fairness of agricultural markets is frequently invoked, especially by farmers. But fairness is difficult to define and measure. In this paper we link fairness and power with the concept of constrained choice to develop a framework for assessing fairness in agricultural markets. We use network exchange theory to define power from the dependencies that exist in agricultural networks. The structure of agricultural networks and the options that agricultural producers have to participate in agricultural networks affect the degree to which they are dependent on others within the network. Dependency, in turn, affects the choices that agricultural producers have. We consider both the number and nature of these choices. We argue that constraining or limiting choices—both in number and type—violates principles of justice. Importantly, network exchange theory provides a method for assessing constraints in choices and, hence, the fairness of agricultural markets. Such an assessment could potentially lead to new policies that safeguard the liberties of marketplace participants. We present a brief case to illustrate how this framework can inform on the fairness of agricultural markets and conclude with considerations of what this means for policy, particularly in the arena of anti-trust.     

The effects of 3,3′,4,4′-tetrabromobiphenyl on rats fed diets containing a constant level of copper and varying levels of molybdenum

Copper (Cu) metabolism is altered in rats fed diets high in molybdenum (Mo) and low in Cu. This 10-week study was carried out to examine the effects of supplemental Mo (7.5–240 μg/g diet) on male Sprague–Dawley rats fed diets adequate in Cu (5 μg/g diet) and to determine the susceptibility of Mo-treated animals to the environmental pollutant 3,3′,4,4′-tetrabromobiphenyl (TBB). After 7 weeks of dietary treatment, half of the rats in each group received a single IP injection of TBB (150 μM/kg bw), while the other half received the corn oil vehicle. Rats sacrificed at 10 weeks showed no effects of Mo on growth, feed efficiency, or selected organ or tissue weights. Dose-dependent effects on plasma Mo (0–5.1 μg/mL), plasma Cu (0.95–0.20 μg/mL), and bone Cu (3.4–10 μg/g) in control through the high dose were found. Cu sequestration in the bone of Mo-treated rats is a new finding. TBB treatment resulted in dramatic weight loss and loss of absolute organ mass. Relative organ weights were increased, except for the thymus. TBB altered the concentrations of certain amino acids. Compared to control rats, this polybrominated biphenyl congener significantly decreased plasma Cu and ceruloplasmin at higher concentrations of dietary Mo and promoted the process of plasma Cu decrease by Mo, suggesting a combined effect.     

Vulnerability of land systems to fire: Interactions among humans,climate, the atmosphere,and ecosystems

Fires are critical elements in the Earth System, linking climate, humans, and vegetation. With 200–500 Mha burnt annually, fire disturbs a greater area over a wider variety of biomes than any other natural disturbance. Fire ignition, propagation, and impacts depend on the interactions among climate, vegetation structure, and land use on local to regional scales. Therefore, fires and their effects on terrestrial ecosystems are highly sensitive to global change. Fires can cause dramatic changes in the structure and functioning of ecosystems. They have significant impacts on the atmosphere and biogeochemical cycles. By contributing significantly to greenhouse gas (e.g., with the release of 1.7–4.1 Pg of carbon per year) and aerosol emissions, and modifying surface properties, they affect not only vegetation but also climate. Fires also modify the provision of a variety of ecosystem services such as carbon sequestration, soil fertility, grazing value, biodiversity, and tourism, and can hence trigger land use change. Fires must therefore be included in global and regional assessments of vulnerability to global change. Fundamental understanding of vulnerability of land systems to fire is required to advise management and policy. Assessing regional vulnerabilities resulting from biophysical and human consequences of changed fire regimes under global change scenarios requires an integrated approach. Here we present a generic conceptual framework for such integrated, multidisciplinary studies. The framework is structured around three interacting (partially nested) subsystems whose contribute to vulnerability. The first subsystem describes the controls on fire regimes (exposure). A first feedback subsystem links fire regimes to atmospheric and climate dynamics within the Earth System (sensitivity), while the second feedback subsystem links changes in fire regimes to changes in the provision of ecological services and to their consequences for human systems (adaptability). We then briefly illustrate how the framework can be applied to two regional cases with contrasting ecological and human context: boreal forests of northern America and African savannahs.     

Judgments of photographs vs. field observations in studies of perception and judgment of the visual environment

The use of photographs as surrogates for field observations is common in studies of perception and judgment of the visual environment despite theoretically important differences between photographs and three-dimensional scenes. The few available empirical studies of the validity of photographs as representations of the visual environment have methodological weaknesses. We describe a method for investigating the representativeness of photographs that differs from previous approaches in three important respects. First, individual subjects rather than group averages are analyzed. Second, multiple judgments are obtained so that the relations among judgments of photographs can be compared with the environment. Third, a ‘lens model equation’ analysis is used to examine relations among systematic components of variation in judgments. An illustrative study of visual air quality judgments is presented. It was found that, in the case of judgments of visual air quality, photographs provide a good representation of the visual environment.