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351.
352.
In the Willamette River, OR, main channel temperatures can be too warm for cold water fishes, causing fish to concentrate in secondary channel features that provide thermal refugia. However, temperature regimes vary among and within features. Improved understanding of physical processes controlling thermal regimes is needed. This study developed a dimensionless index for assessment of thermal refugia on the upper Willamette River. The novel hyporheic insolation (HIN) index uses minimal field measurements to predict thermal refugia resulting from buffering. Continuous water temperature measurements at one side channel, eight alcoves, and six beaver ponds provided data to ground truth calculated in predictions. Water temperature records were first used to characterize stratification at sites. Calculation of the Richardson number, an index of stability, showed two well-mixed sites and 13 stratified sites. At stratified sites, calculated in values characterized the ratio of cooling flux from hyporheic discharge to heat flux from incoming solar radiation. As in increased, measured temperatures at sites decreased. Despite overall scatter, a logarithmic fit to bin-averaged in values showed R2 = 0.91. Calculations suggest that secondary channel features characterized by stratification and cool hyporheic discharge can provide thermal refugia. Accordingly, the HIN index may serve as a practical tool grounded in physical processes governing temperature across a floodplain.  相似文献   
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354.
Chromium has become an important soil contaminant at many sites, and facilitating in situ reduction of toxic Cr(VI) to nontoxic Cr(III) is becoming an attractive remediation strategy. Acceleration of Cr(VI) reduction in soils by addition of organic carbon was tested in columns pretreated with solutions containing 1000 and 10 000 mg L(-1) Cr(VI) to evaluate potential in situ remediation of highly contaminated soils. Solutions containing 0,800, or 4000 mg L(-1) organic carbon in the form of tryptic soy broth or lactate were diffused into the Cr(VI)-contaminated soils. Changes in Cr oxidation state were monitored through periodic micro-XANES analyses of soil columns. Effective first-order reduction rate constants ranged from 1.4 x 10(-8) to 1.5 x 10(-7) s(-1), with higher values obtained for lower levels of initial Cr(VI) and higher levels of organic carbon. Comparisons with sterile soils showed that microbially dependent processes were largely responsible for Cr(VI) reduction, except in the soils initially exposed to 10 000 mg L(-1) Cr(VI) solutions that receive little (800 mg L(-1)) or no organic carbon. However, the microbial populations (< or = 2.1 x 10(5) g(-1)) in the viable soils are probably too low for direct enzymatic Cr(VI) reduction to be important. Thus, synergistic effects sustained in whole soil systems may have accounted for most of the observed reduction. These results show that acceleration of in situ Cr(VI) reduction with addition of organic carbon is possible in even heavily contaminated soils and suggest that microbially dependent reduction pathways can be dominant.  相似文献   
355.
Biogeochemical transformations of redox-sensitive chemicals in soils can be strongly transport-controlled and localized. This was tested through experiments on chromium diffusion and reduction in soil aggregates that were exposed to chromate solutions. Reduction of soluble Cr(VI) to insoluble Cr(II) occurred only within the surface layer of aggregates with higher available organic carbon and higher microbial respiration. Sharply terminated Cr diffusion fronts develop when the reduction rate increases rapidly with depth. The final state of such aggregates consists of a Cr-contaminated exterior, and an uncontaminated core, each having different microbial community compositions and activity. Microbial activity was significantly higher in the more reducing soils, while total microbial biomass was similar in all of the soils. The small fraction of Cr(VI) remaining unreduced resides along external surfaces of aggregates, leaving it potentially available to future transport down the soil profile. Using the Thiele modulus, Cr(VI) reduction in soil aggregates is shown to be diffusion rate- and reaction rate-limited in anaerobic and aerobic aggregates, respectively. Thus, spatially resolved chemical and microbiological measurements are necessary within anaerobic soil aggregates to characterize and predict the fate of Cr contamination. Typical methods of soil sampling and analyses that average over redox gradients within aggregates can erase important biogeochemical spatial relations necessary for understanding these environments.  相似文献   
356.
There has and continues to be concern about the effects of elevated nitrogen (N) deposition on natural ecosystems. In this paper, research on natural ecosystems, including wetlands, heathlands, grasslands, steppe, naturally regenerated forests and deserts, is evaluated to determine what is known about nitrogen cycling in these ecosystems, the effects of elevated nitrogen on them and to identify research gaps. Aquatic ecosystems are not included in this review, except as they are part of the larger ecosystem. Research needs fall into several categories: (1) improved understanding and quantification of the N cycle, particularly relatively unstudied processes such as dry deposition, N fixation and decomposition/mineralization; (2) carbon cycling as affected by increased N deposition; (3) effects on arid ecosystems and other "neglected" ecosystems; (4) effects on complex ecosystems and interactions with other pollutants; (5) indicators and assessment tools for natural ecosystems.  相似文献   
357.
PROBLEM: By numerous accounts, alcohol abuse is considered the number one drug problem facing young people today. Alcohol consumption and its negative consequences, especially those due to drinking and driving, continue to have devastating effects on the college student population. METHOD: This field study examined the blood alcohol concentration (BAC) levels of male and female designated drivers (DD), non-DD, and their respective passengers as they were leaving drinking establishments in a university town. Also investigated were the effects of group size and gender on DD use. RESULTS: A 2 Gender x 2 Driver type (DD vs. non-DD) analysis of variance (ANOVA) for BAC indicated significant main effects for Gender and Driver type, with higher BAC for men and non-DD (p's<.001). A significant Gender x Driver type interaction (p<.05) was primarily due to female DD having lower BAC than male DD. In addition, larger groups were more likely to have a DD. IMPACT ON INDUSTRY: Results indicate that the success of DD programs may be influenced by group size and a DD's gender. While larger groups are more likely to have a DD, students riding home with a male DD may still be at risk for the negative consequences of drunk driving.  相似文献   
358.
Signs of desertification in Africa in the 1970s and 1980s were closely linked to rainfall fluctuations. There may now be an upward trend in the Sahel, but climate change models do not yet provide reliable predictions of rainfall. As family farms become smaller under conditions of population growth, some people move to new areas or new occupations (urban population is growing much faster than rural) and farmers attempt to raise the value of output (crops or livestock) per hectare. Long–term data for selected countries and areas provide some evidence of positive trends. Case studies show that adaptive strategies of small farmers include techniques to improve fertility, conserve water, manage trees, increase livestock, and take advantage of changing markets. However, their investments in improving land and productivity are constrained by poverty. Governments can best help by improving market access and opportunities for non–farm activities. The region's climate is characterized by variable rainfall, which means that droughts will continue to occur unpredictably.  相似文献   
359.
Many government agencies and other organizations hold large tracts of surplus land. Some are investigating ways to lower expenses by selling the land or transferring management responsibility. There is no generally recognized process used to decide what land can be decommissioned and what future use would be best. This paper provides guidance for land‐use decisions in the form of a checklist. The checklist questions address both the socio‐economic resources and current land use in the region, and the ecological resources and suitability of the tract itself. The answers will clarify regional public needs and the economic and ecological values of the land.  相似文献   
360.
Previous research has shown that dispositional negative affect (NA) is associated with lower levels of job satisfaction. Little research has been conducted, however, on other organizational implications of negative affect or on the potential effects of dispositional positive affect (PA). The present studies examined the relationship of both positive and negative affectivity to organizational commitment, turnover intentions, global job satisfaction and performance. In the first study both NA and PA were associated with organizational commitment and turnover intentions. Additionally, commitment mediated the relationship between dispositional affectivity and turnover. Finally, PA and tenure interacted to predict job performance, such that PA and job performance were positively related, but only for high tenure employees. In Study 2 the findings were generally similar, but not identical. Both NA and PA were related to global job satisfaction and turnover intentions. However, only PA was related to affective organizational commitment. Moreover, both job satisfaction and affective commitment mediated the relationship between dispositional affectivity and turnover intentions. Finally, unlike Study 1, PA was not related to job performance. Rather, NA and tenure interacted such that when individuals were lower in tenure, NA was negatively related to performance.  相似文献   
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