Distribution of polycyclic aromatic hydrocarbons (PAHs) and sterols in termite nest, soil, and sediment from Great Kwa River, SE Nigeria

Costal sediment samples from Great Kwa River as well as adjoining termite nest and soil samples were analyzed for quantitative determination of polycyclic aromatic hydrocarbons (PAHs) and sterols using gas chromatography–mass spectrometry (GC–MS) in order to access the possibility of transport of biologically produced PAHs/sterols from termite nest to the sediments. The total PAH concentrations (sum of parent and alkyl) for the sediments ranged between 131.96 and 139.35 ng/g dry weight (dw) while those for the nest and soil samples were in the range 9.51–9.71 and 71.85–77.26 ng/g dw, respectively. These levels of PAHs in sediments were relatively low compared to other urban/industrial Asian and American countries. No evidence of the usual biologically produced PAHs was found, thus reducing the likelihood of transport of these compounds from the nest to the sediments. The absence of parent and alkyl PAHs in central compartment of the nest may reflect the selective fern leaves feeding pattern of the dominant termite species prevalent in the vicinity of the study site. Utilization of six selected PAH ratios such as Fla/(Fla + Pyr) (0.4–0.5), Ant/(Ant + Phe) (0.25–0.90), BaA/(BaA + Chrys) (0.45–0.61), MP/P (0.05–6.81), 1,7/(1,7?+?2,6)-DMP (0.61–0.95), and LPAH/HPAH ( 2.80–3.80) allows discrimination of PAH sources for the samples to be made with a mixed source dominance observed. Examination of sterol distributions in the samples shows relatively high abundance of cholest-5-en-3β-ol in central compartment of the nest, considered here as a consequence of metabolic conversion of phyto-/fungi sterols in the tissues of the termite species. The relatively reduced levels of stanol compounds in central compartment of the nest may be associated with their utilization by the termites for growth and development.     

The Monitoring of UK Sewage Sludge Disposal Sites

In recent years there has been an increase in the intensity and frequency of environmental monitoring surveys at UK sewage sludge disposal sites. These have been carried out by the regulatory authorities and by the licensees. in order to ensure maximum efficiency, a coordinated and harmonised programme of monitoring has been developed. the programme concentrates on sediment chemical and biological quality but also includes assessments of water and fish quality

In England and Wales the Ministry of Agriculture, Fisheries and Food is the regulatory authority and the Water Authorities are the licensees. the Ministry's first priority is the collection of samples for temporal trend analysis but in addition, infrequent surveys are made to check the status of the disposal site and surrounding areas. in the periods between status surveys, regular spatial surveys designed to define the area of impact are carried out by the Water Authorities.     

Evolution of the landscape as a response of a demographic change. A case study in the Duero riverside,Spain

The Arribes del Duero area, in western Spain, at the border with Portugal, is suffering a drastic change in the landscape, as a response of the diminution of population. Traditional tasks related to agriculture have been abandoned, and heavy sheep farming on the area is provoking the impoverishment of soils. The effect derived from these actions is the disintegration of the terraces, which are one of the major attractions for tourists visiting the region. We propose that incentives for local people could help to develop those traditional labours to recover the landscape, together with the promotion of immigration of families with school-age children, could bring back the economy to the area.     

Collaborative Modeling to Evaluate Water Management Scenarios in the Rio Grande Basin

This article describes the collaborative modeling process and the resulting water resources planning model developed to evaluate water management scenarios in the transboundary Rio Grande basin. The Rio Grande is a severely water stressed basin that faces numerous management challenges as it crosses numerous jurisdictional boundaries. A collaborative process was undertaken to identify and model water management scenarios to improve water supply for stakeholders, the environment, and international obligations of water delivery from Mexico to the United States. A transparent and open process of data collection, model building, and scenario development was completed by a project steering committee composed of university, nongovernmental, and governmental experts from both countries. The outcome of the process was a planning model described in this article, with data and operations that were agreed on by water planning officials in each country. Water management scenarios were created from stakeholder input and were modeled and evaluated for effectiveness with the planning model.     

The accumulation of person-environment congruences and well-being

The impact of the additivity of three aspects of person-environment congruence — vocational, avocational and skill utilization — to well-being was assessed by four measures: occupational satisfaction, work satisfaction, somatic complaints and anxiety. Subjects were 74 female teachers. Findings showed: (a) the three congruence aspects were not interrelated; (b) all congruence aspects were correlated with all well-being measures in the expected direction; and (c) combinations of the three congruence aspects had an additive effect: the higher the number of congruence aspects the higher the well-being. The implications of congruence additivity to stress research and to vocational counselling was discussed.     

Collection efficiency of electrostatic precipitators by numerical simulation

A numerical simulation code has been developed to analyze the coupled electro-aerodynamic phenomena within an electrostatic precipitator operated in both the positive and negative corona modes. The space charge and current densities, as well as the static and space charge components of the electric field, are first obtained using the known cross-sections for ionization and negative ion formation. Data includes the effects of fluid flow. The above quantities (except the static field) are then corrected in a subsequent iteration for the presence of dust particles of known size distribution, charges predominantly by the field charging mechanism. The precipitator collection efficiency is calculated from the trajectories of the charged dust particles. For theory comparison, the collection efficiencies of model precipitators were measured by light-scattering techniques using oil drops as test particles. The variation of efficiency with wire-to-wire spacing will be discussed as a case study.     

Methodological aspects of a national population-based study of persistent organochlorine compounds in serum

Key methodological aspects are presented for a study of concentrations of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychlorinated biphenyls (PCBs), and organochlorine pesticides in the serum of a sample of the New Zealand population aged 15 years and older. The study took advantage of the sampling frame and sample collection and interview processes of the National Nutrition Study (NNS). An additional blood sample for this organochlorines study was collected by the NNS and questions added to the NNS questionnaire. Serum was obtained from the blood and, based on responses to questions in the questionnaire, samples with possible occupational exposure to organochlorines were excluded. Remaining samples providing at least 2 ml of serum were pooled within 80 strata defined according to geographic area, age group, sex and ethnicity. A minimum number of five individual serum samples was required for pooling within a stratum. Within strata with sufficient samples, two or three pooled samples were created for variance calculation. Eligible for inclusion in the study were 2497 individual serum samples. Sixty strata had sufficient serum samples for pooling and chemical analysis. This was the first study of organochlorine compounds with a national population-based sample. Two factors that made the study feasible deserve emphasis. First, being able to "piggy-back" on another study. Second, pooling of samples to reduce analytic expenses. It is hoped that the methods used in this study will form the basis for other studies investigating organochlorine concentrations in national populations.