Quantifying dry NH3 deposition to an ombrotrophic bog from an automated NH3 field release system

Providing an accurate estimate of the dry component of N deposition to low N background, semi-natural habitats, such as bogs and upland moors dominated by Calluna vulgaris is difficult, but essential to relate nitrogen deposition to effects in these communities. To quantify the effects of NH₃ inputs to moorland vegetation growing on a bog at a field scale, a field release NH₃ fumigation system was established at Whim Moss (Scottish Borders) in 2002. Gaseous NH₃ from a line source was released along of a 60 m transect, when meteorological conditions (wind speed >2.5 m s^–1 and wind direction in the sector 180–215°) were met, thereby providing a profile of decreasing NH₃ concentration with distance from the source. In a complementary study, using a NH₃ flux chamber system, the relationships between NH₃ concentrations and cuticular resistances were quantified for a range of NH₃ concentrations and micrometeorological conditions for moorland vegetation. Cuticular resistances increased with NH₃ concentration from 11 s m^–1 at 3.0 g m^–3 to 30 s m^–1 at 30 g m^–3. The NH₃ concentration data and the concentration-dependent canopy resistance are used to calculate NH₃ deposition taking into account leaf surface wetness. The implications of using an NH₃ concentration-dependent cuticular resistance and the importance for refining critical loads are discussed.     

Planning for ex situ conservation in the face of uncertainty

Ex situ conservation strategies for threatened species often require long‐term commitment and financial investment to achieve management objectives. We present a framework that considers the decision to adopt ex situ management for a target species as the end point of several linked decisions. We used a decision tree to intuitively represent the logical sequence of decision making. The first decision is to identify the specific management actions most likely to achieve the fundamental objectives of the recovery plan, with or without the use of ex‐situ populations. Once this decision has been made, one decides whether to establish an ex situ population, accounting for the probability of success in the initial phase of the recovery plan, for example, the probability of successful breeding in captivity. Approaching these decisions in the reverse order (attempting to establish an ex situ population before its purpose is clearly defined) can lead to a poor allocation of resources, because it may restrict the range of available decisions in the second stage. We applied our decision framework to the recovery program for the threatened spotted tree frog (Litoria spenceri) of southeastern Australia. Across a range of possible management actions, only those including ex situ management were expected to provide >50% probability of the species’ persistence, but these actions cost more than use of in situ alternatives only. The expected benefits of ex situ actions were predicted to be offset by additional uncertainty and stochasticity associated with establishing and maintaining ex situ populations. Naïvely implementing ex situ conservation strategies can lead to inefficient management. Our framework may help managers explicitly evaluate objectives, management options, and the probability of success prior to establishing a captive colony of any given species.     

Taproot™ technology: Tree coring for fast,noninvasive plume delineations

In efforts to evaluate the use of plants as a forensic tool for delineating contaminated soil and groundwater, a laboratory experiment and a field sampling effort were undertaken. Site assessments are often costly and inaccurate, requiring multiple mobilizations to hone in on source areas and getting accurate estimates of contaminant extent and distribution. As these extensive site delineations take place, valuable time and resources are lost. The findings of this study show that plants can be used as a tool to evaluate a variety of subsurface contaminants, either in the vadose zone or in the saturated zone. In the first field application of Taproot? Technology, a large, heavily forested site was sampled in one day and the contamination on‐site was more accurately delineated than had been generated at the site in over a decade, with more than 26 wells installed. New source zones were detected on the site, and the presence of new waste depositions was uncovered for the first time showing the great value of tree coring as a contaminant detection tool. © 2009 Wiley Periodicals, Inc.     

State and potential management to improve water quality in an agricultural catchment relative to a natural baseline

Land use change and the expansion of dairying are perceived as the cause of poor water quality in the 1881 km² Pomahaka catchment in Otago, New Zealand. A study was conducted to determine the long-term trend at four sites, and current state in 13 sub-catchments, of water quality. Drains in 2 dairy-farmed sub-catchments were also sampled to determine their potential as a point source of stream contamination. Data highlighted an overall increase in the concentration of phosphorus (P) fractions at long-term sites. Loads of contaminants (nitrogen (N) and P fractions, sediment and Escherichia coli) were greatest in those sub-catchments with the most dairying. Baseline (without human influence) contaminant concentrations suggested that there was considerable scope for decreasing losses. At most sites, baseline concentrations were <20% of current median concentrations. Contaminant losses via drainage were recorded despite there being no rainfall that day and attributed to applying too much effluent onto wet soil. Modelling of P concentrations in one dairy-farmed sub-catchment suggested that up to 58% of P losses came from point sources, like bad effluent practice and stock access to streams. A statistical test to detect “contaminated” drainage was developed from historical data. If this test had been applied to remove contaminated drainage from samples of the two dairy-farmed sub-catchments, median contaminant concentrations and loads would have decreased by up to 58% (greater decreases were found for E. coli, ammoniacal-N and total P than other contaminants). This suggests that better uptake of strategies to mitigate contamination, such as deferred effluent irrigation (and low rate application), could decrease drainage losses from dairy-farmed land and thereby improve water quality in the Pomahaka catchment.     

Gastric bioaccessibility and human health risks associated with soil metal exposure via ingestion at an E-waste recycling site in Kumasi,Ghana

Environmental Geochemistry and Health - Over 1000 people make a living by processing electronic and electrical waste (E-waste) and scrap metals for the recovery of valuable metals and integrated...     

Assessing Watershed-Scale, Long-Term Hydrologic Impacts of Land-Use Change Using a GIS-NPS Model

Land-use change, dominated by an increase in urban/impervious areas, has a significant impact on water resources. This includes impacts on nonpoint source (NPS) pollution, which is the leading cause of degraded water quality in the United States. Traditional hydrologic models focus on estimating peak discharges and NPS pollution from high-magnitude, episodic storms and successfully address short-term, local-scale surface water management issues. However, runoff from small, low-frequency storms dominates long-term hydrologic impacts, and existing hydrologic models are usually of limited use in assessing the long-term impacts of land-use change. A long-term hydrologic impact assessment (L-THIA) model has been developed using the curve number (CN) method. Long-term climatic records are used in combination with soils and land-use information to calculate average annual runoff and NPS pollution at a watershed scale. The model is linked to a geographic information system (GIS) for convenient generation and management of model input and output data, and advanced visualization of model results. The L-THIA/NPS GIS model was applied to the Little Eagle Creek (LEC) watershed near Indianapolis, Indiana, USA. Historical land-use scenarios for 1973, 1984, and 1991 were analyzed to track land-use change in the watershed and to assess impacts on annual average runoff and NPS pollution from the watershed and its five subbasins. For the entire watershed between 1973 and 1991, an 18% increase in urban or impervious areas resulted in an estimated 80% increase in annual average runoff volume and estimated increases of more than 50% in annual average loads for lead, copper, and zinc. Estimated nutrient (nitrogen and phosphorus) loads decreased by 15% mainly because of loss of agricultural areas. The L-THIA/NPS GIS model is a powerful tool for identifying environmentally sensitive areas in terms of NPS pollution potential and for evaluating alternative land use scenarios for NPS pollution management.     

轻型柴油车排放特性与机动车比功率分布的实例研究

引入机动车比功率概念研究了驾驶条件(DrivingCondition)对机动车排放的影响及二者间的关系.利用美国Sensors公司生产的SEMTECH-D车载排放测试仪在上海选取2辆轻型柴油客货两用车开展了实际道路排放测试.测试道路包括城市快速道、主干道和次干道,2辆轻型车测试的道路全长分别为31·8和39·7km.通过计算逐秒的比功率值,研究了实际行驶中机动车比功率(VSP)与机动车油耗、空燃比和污染物排放的关系.回归分析结果表明,比功率比加速度能够更好地反映与NOx排放之间的关系,不同道路上机动车的CO、TC、NOx排放速率和油耗的比功率区间(VSPbin)分布具有较好的一致性.实测研究中VSPbin分布于-20~20kW·t-1的范围内,其中超过50%的数据分布在-3~1kW·t-1之间.高排放集中在分布频率较低的高VSP区间.应用污染物排放与VSP分布的关系式和VSPbins的频率分布可以估算机动车污染物排放总量.排放速率计算式具有一定的不确定性,还有待将来进一步修正.     

The Effects of Small Dam Removal on the Distribution of Sedimentary Contaminants

With increasing concern over degradation of aquatic resources, issues of liability, and maintenance costs, removal of small dams has become increasing popular. Although the benefits of removal seem to outweigh the drawbacks, there is a relative paucity of studies documenting the extent and magnitude of biological and chemical changes associated with dam removal, especially those evaluating potential changes in contaminant inventories. In August and November of 2000, a run-of-the-river dam on Manatawny Creek (southeast Pennsylvania) was removed in a two-stage process. To assess the effects of dam removal on the contaminant redistribution within the creek, sedimentary concentrations of polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), and trace metals (Cd, Cr, Cu, Ni, Pb, Zn) were evaluated prior to and several months after removal. Pre- and post-removal analyses revealed elevated and spatially variable concentrations of total PAHs (ranging from approximately 200 to 81,000 ng(g dry weight) and low to moderate concentrations of trace metals and PCBs. The concentrations of these sedimentary contaminants pre- versus post-removal were not significantly different. Additionally, though the impoundment received storm water run-off and associated contaminants from the adjacent city of Pottstown, the total inventory of fine-grain sediments in the impoundment prior to removal was very low. The removal of the low-level Manatawny Creek dam did not significantly redistribute contaminants downstream. However, each dam removal should be assessed on a case by case basis where the potential of sedimentary contaminant redistribution upon dam removal exists.     

Opportunities for redistributed manufacturing and digital intelligence as enablers of a circular economy

The linear production of consumer goods is characterised by mass manufacture by multinational enterprises and globally dispersed supply chains. The current centralised model has created a distance between the manufacturer and end user, limiting the opportunity for intelligent circular approaches for production and consumption. Through a mixed method approach, opportunities of circularity are explored for the consumer goods sector. The study presents four lenses to analyse three enterprises through a multi-case study approach to explore the potential of digital intelligence and redistributed manufacturing (RDM) as enablers of circular business models. In addition, the study examines whether Discrete Event Simulation can be used to evaluate the circular scenarios identified through quantifying flows of material that determine traditional economic value (cost/tonne). The mixed method approach demonstrates that, a qualitative systemic analysis can reveal opportunities for circularity, gained through implementing ‘digital intelligence’ and distributed models of production and consumption. Furthermore, simulations can provide a quantified evaluation on the effects of introducing circular activities across a supply chain.