全文获取类型
收费全文 | 13398篇 |
免费 | 100篇 |
国内免费 | 53篇 |
专业分类
安全科学 | 250篇 |
废物处理 | 915篇 |
环保管理 | 2004篇 |
综合类 | 1360篇 |
基础理论 | 4005篇 |
环境理论 | 3篇 |
污染及防治 | 2631篇 |
评价与监测 | 1299篇 |
社会与环境 | 1043篇 |
灾害及防治 | 41篇 |
出版年
2023年 | 28篇 |
2022年 | 41篇 |
2021年 | 46篇 |
2020年 | 57篇 |
2019年 | 71篇 |
2018年 | 1527篇 |
2017年 | 1465篇 |
2016年 | 1312篇 |
2015年 | 229篇 |
2014年 | 147篇 |
2013年 | 356篇 |
2012年 | 635篇 |
2011年 | 1531篇 |
2010年 | 860篇 |
2009年 | 769篇 |
2008年 | 1054篇 |
2007年 | 1405篇 |
2006年 | 206篇 |
2005年 | 194篇 |
2004年 | 186篇 |
2003年 | 198篇 |
2002年 | 230篇 |
2001年 | 110篇 |
2000年 | 79篇 |
1999年 | 65篇 |
1998年 | 57篇 |
1997年 | 64篇 |
1996年 | 50篇 |
1995年 | 54篇 |
1994年 | 56篇 |
1993年 | 46篇 |
1992年 | 39篇 |
1991年 | 31篇 |
1990年 | 29篇 |
1989年 | 27篇 |
1988年 | 23篇 |
1987年 | 17篇 |
1986年 | 17篇 |
1985年 | 23篇 |
1984年 | 29篇 |
1983年 | 36篇 |
1982年 | 22篇 |
1981年 | 32篇 |
1980年 | 19篇 |
1979年 | 18篇 |
1978年 | 13篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1969年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
861.
Ben-Shlomo R Shanas U 《Environmental science and pollution research international》2011,18(8):1264-1269
Purpose
We tested the genetic diversity in wild mice (Mus musculus domesticus) inhabiting the asbestos-polluted area as a model for the long-term mutagenic effect of asbestos. Hazardous effects of deposited asbestos persist in the environment because of low rate of fiber disintegration. The upper layers of the soil in the vicinity of a former asbestos factory are nearly “saturated” with asbestos fibers and dust. Natural populations of mice dwell in this area and are constantly exposed to asbestos fibers. 相似文献862.
Occurrence of perfluorinated organic acids in the North and Baltic seas. Part 1: distribution in sea water 总被引:1,自引:0,他引:1
Theobald N Caliebe C Gerwinski W Hühnerfuss H Lepom P 《Environmental science and pollution research international》2011,18(7):1057-1069
Purpose
Due to their high water solubilities and mobilities, persistent, polar perfluorinated compounds (PFCs) such as perfluorinated carboxylates and sulfonates are likely to end up in the oceans. In part 1 of this study, their distribution in North and Baltic Sea water is reported, being of special interest because these seas are surrounded by highly industrialized countries with high population densities. 相似文献863.
A modified version of the Multimedia Activity Model for Ionics MAMI, including two-layered atmosphere, air-water interface partitioning, intermittent rainfall and variable cloud coverage was developed to simulate the atmospheric fate of ten low volatility or ionizable organic chemicals. Probabilistic simulations describing the uncertainty of substance and environmental input properties were run to evaluate the impact of atmospheric parameters, ionization and air-water (or air-ice) interface enrichment.The rate of degradation and the concentration of OH radicals, the duration of dry and wet periods, and the parameters describing air-water partitioning (KAW and temperature) and ionization (pKa and pH) are the key parameters determining the potential for long range transport. Wet deposition is an important removal process, but its efficiency is limited, primarily by the duration of the dry period between precipitation events.Given the underlying model assumptions, the presence of clouds contributes to the higher persistence in the troposphere because of the capacity of cloud water to accumulate and transport non-volatile (e.g. 2,4-D) and surface-active chemicals (e.g. PFOA). This limits the efficiency of wet deposition from the troposphere enhancing long-range transport. 相似文献
864.
McGoldrick DJ Durham J Leknes H Kierkegaard A Gerhards R Powell DE McLachlan MS 《Chemosphere》2011,85(8):1241-1247
Cyclic volatile methyl siloxanes (cVMS) are high volume production chemicals used in a wide range of industrial and consumer products. Three cVMS compounds (D4, D5, and D6) have and are undergoing environmental risk evaluations in several countries and have been proposed for legal regulation in Canada. As interest in monitoring concentrations of these chemicals in the environment increase, there is a need to evaluate the analytical procedures for cVMS in biological matrices in order to assess the quality of data produced. The purpose of this study was to determine laboratory testing performance for measuring residues of D4, D5, and D6 in a standard set of fish homogenate samples and to estimate limits of determination for each substance. The samples sent to each laboratory consisted of homogenized whole body tissues of hatchery raised rainbow trout which were fed food fortified with D4, D5, and D6 (dosed) and trout that were fed standard food rations (control). The participants analyzed each sample using their analytical method of choice using their own standards and procedures for quantification and quality control. With a few exceptions, participating laboratories generated comparable results for D4, D5, and D6 in both the dosed and control samples having z-scores between 2 and −2. Method detection limits for the whole fish matrix were on average 2.4 ng g−1 ww for D4, 2.3 ng g−1 ww for D5, and 1.8 ng g−1 ww for D6. 相似文献
865.
Pujol Pereira EI Chung H Scow K Sadowsky MJ van Kessel C Six J 《Environmental pollution (Barking, Essex : 1987)》2011,159(2):401-407
We investigated the influence of elevated CO2 and O3 on soil N cycling within the soybean growing season and across soil environments (i.e., rhizosphere and bulk soil) at the Soybean Free Air Concentration Enrichment (SoyFACE) experiment in Illinois, USA. Elevated O3 decreased soil mineral N likely through a reduction in plant material input and increased denitrification, which was evidenced by the greater abundance of the denitrifier gene nosZ. Elevated CO2 did not alter the parameters evaluated and both elevated CO2 and O3 showed no interactive effects on nitrifier and denitrifier abundance, nor on total and mineral N concentrations. These results indicate that elevated CO2 may have limited effects on N transformations in soybean agroecosystems. However, elevated O3 can lead to a decrease in soil N availability in both bulk and rhizosphere soils, and this likely also affects ecosystem productivity by reducing the mineralization rates of plant-derived residues. 相似文献
866.
For urban community composting centers, the proper selection and use of bulking agent is a key element in not only the cost but also the quality of the finished compost. Besides wood chips (WC) widely used as BA, readily usable cereal residue pellets (CRP) can provide biodegradable carbon and sufficient free air space (FAS) to produce stabilizing temperatures. The objective of the present project was to test at a community center, the effectiveness of CRP in composting food waste (FW). Two recipes were used (CRP with and without WC) to measure: FAS; temperature regimes, and; losses in mass, water, carbon and nitrogen. Both recipes were composted during three consecutive years using a 2 m3 commercial in-vessel composter operated in downtown Montreal (Canada). For all recipes, FAS exceeded 30% for moisture content below 60%, despite yearly variations in FW and BA physical properties. When properly managed by the center operator, both FW and CRP compost mixtures with and without WC developed within 3 days thermophilic temperatures exceeding 50 °C. The loss of total mass, water, carbon and nitrogen was quite variable for both recipes, ranging from 36% to 54%, 42% to 55%, 48% to 65%, and 4% to 55%, respectively. The highest loss in dry mass, water and C was obtained with FW and CRP without WC aerated to maintain mesophilic rather than thermophilic conditions. Although variable, lower nitrogen losses were obtained with CRP and WC as BA, compared to CRP alone, as also observed during previous laboratory trials. Therefore and as BA, CRP can be used alone but nitrogen losses will be minimized by adding WC. Compost stabilization depends on operator vigilance in terms of aeration. The measured fresh compost density of 530-600 kg/m3 indicates that the 2 m3 in-vessel composter can treat 6.5 tons of FW/year if operated during 7 months. 相似文献
867.
Mehmet Berkun Egemen Aras Tugce Anılan 《Journal of Material Cycles and Waste Management》2011,13(4):305-313
As an economically developing country, Turkey has very well operated integrated solid waste management applications structured
on modern facilities, besides over 2,000 scattered open dump areas in the country. Integrated waste management applications
seem eligible for the metropolitan cities like Istanbul and Izmit (Kocaeli). Attempts have not been encouraging for the scattered
regional settlements using central storage sites due to financial shortages and received rejections from nearby settlements.
Small-scale compact solid waste management systems with materials recycling and composting can be more suitable alternatives
in the small-scale regional settlements. The major constituents of municipal solid waste are organic in nature and approximately
a quarter of municipal solid waste is recyclable. Although paper, including cardboard, is the main constituent, the composition
of recyclable waste varies strongly by the source or the type of collection point. Solid wastes need primary treatment in
order to be suitable for incineration and composting. Turkey needs to give more emphasis on the usage of modern solid waste
removal technologies to overcome the overgrowing solid waste disposal problems. 相似文献
868.
The circular economy has been developing rapidly in recent years in China. A legislative system has been created to provide
legal protection for the development of a circular economy, including a series of price and tax measures in the waste management
area. These measures form the basic foundation for promoting better waste management under the circular economic model. Many
challenges, however, remain. For instance, the legal system needs to incorporate more sophisticated science, and China lacks
key waste treatment technology that could support the further development of a circular economy. There is also a need to educate
the public about the concept of the circular economy and its benefits. Specific suggestions are made for the development and
implementation of the circular economic model. 相似文献
869.
Hisanori Watanabe Hidekichi Yoshino 《Journal of Material Cycles and Waste Management》2011,13(2):113-117
Since hydrogen is a renewable energy source, biohydrogen has been researched in recent years. However, data on hydrogen fermentation
by a leachate from a waste landfill as inoculum are scarce. We investigated hydrogen production using a leachate from an industrial
waste landfill in Kanagawa Prefecture. The results showed no methane gas production, and the leachate was a suitable inoculum
for hydrogen fermentation. The maximum H2 yield was 2.67 mol of H2 per mol of carbohydrate added, obtained at 30°C and an initial pH of 7. The acetate and butyrate production was significant
when the H2 yield was higher. Oxidation–reduction potential analysis of the culture suggested that hydrogen-producing bacteria in the
leachate were facultative anaerobic. Scanning electron microscope observations revealed that the hydrogen-producing bacteria
comprised bacilli about 2 μm in length. 相似文献
870.
Shinsuke Iijima Morito Nakamura Akira Yokoi Mitsuhiro Kubota Liwei Huang Hitoki Matsuda 《Journal of Material Cycles and Waste Management》2011,13(3):206-212
For an effective decomposition and removal of organic halogenated compounds, a packed-bed non-thermal plasma reactor with
in situ absorption of the resulting halogenated products by alkaline sorbent incorporated was proposed. In the plasma reactor,
α-Al2O3 particles of 1 and 3 mm (mean particle diameter) were packed as solid dielectric medium to enhance the plasma power density
in the reactor. Further, alkaline sorbent of Ca(OH)2 was doped onto the surface of α-Al2O3 particles, in order to remove halogenated products by in situ absorption with Ca(OH)2. A high-voltage and high-frequency pulsed power of −15 to 15 kV and 1 kHz was applied to the wire electrode of the plasma
reactor by means of a DC power source. In the present study, as the sample of an organic halogenated compound that is most
popularly used, we selected dichloromethane (CH2Cl2), and 500 ppm of the initial concentration of CH2Cl2 was fed into the reactor accompanied by air at a fixed flow rate of 500 × 10−6 m3 min−1 at room temperature. As a result, it was recognized that the amount of CH2Cl2 decomposed by non-thermal plasma in an α-Al2O3 particle bed increased with an increase in plasma input power. The ratio of decomposition of CH2Cl2 was almost 100% at 13 kV of electric power and 1 kHz frequency, and CO2, CH3Cl, COCl2, HCl, and Cl2 were observed as the major reaction products. On the other hand, when CH2Cl2 was introduced into the plasma reactor where α-Al2O3 particles doped with Ca(OH)2 were packed, the ratio of decomposition of CH2Cl2 became higher, compared to the case that α-Al2O3 particles were not doped with Ca(OH)2. Moreover, there were no halogenated by-product gases detected in the outlet gas from the reactor. As the solid reaction
products, CaClOH and Ca(ClO)2·4H2O were detected on Ca(OH)2 by X-ray diffraction. From these findings, it was recognized that CH2Cl2 was decomposed more effectively without producing unwanted harmful halogenated by-products in the proposed non-thermal plasma
reactor where α-Al2O3 particles doped with Ca(OH)2 sorbent were packed. 相似文献