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111.
Liu X Sun L Yuan D Yin L Chen J Liu Y Liu C Liang Y Lin F 《Environmental science and pollution research international》2011,18(8):1324-1332
Background and purpose
More and more coal-fired power plants equipped with seawater flue gas desulfurization systems have been built in coastal areas. They release large amount of mercury (Hg)-containing waste seawater into the adjacent seas. However, very limited impact studies have been carried out. Our research targeted the distribution of Hg in the seawater, sediment, biota, and atmosphere, and its environmental transportation. 相似文献112.
Vijgen J Abhilash PC Li YF Lal R Forter M Torres J Singh N Yunus M Tian C Schäffer A Weber R 《Environmental science and pollution research international》2011,18(2):152-162
Purpose
Hexachlorocyclohexane (HCH) isomers (??-, ??- and ??- (Lindane)) were recently included as new persistent organic pollutants (POPs) in the Stockholm Convention, and therefore, the legacy of HCH and Lindane production became a contemporary topic of global relevance. This article wants to briefly summarise the outcomes of the Stockholm Convention process and make an estimation of the amount of HCH waste generated and dumped in the former Lindane/HCH-producing countries.Results
In a preliminary assessment, the countries and the respective amount of HCH residues stored and deposited from Lindane production are estimated. Between 4 and 7 million tonnes of wastes of toxic, persistent and bioaccumulative residues (largely consisting of alpha- (approx. 80%) and beta-HCH) are estimated to have been produced and discarded around the globe during 60 years of Lindane production. For approximately 1.9 million tonnes, information is available regarding deposition. Countries are: Austria, Brazil, China, Czech Republic, France, Germany, Hungary, India, Italy, Japan, Macedonia, Nigeria, Poland, Romania, Slovakia, South Africa, Spain, Switzerland, Turkey, The Netherlands, UK, USA, and former USSR. The paper highlights the environmental relevance of deposited HCH wastes and the related POPs?? contaminated sites and provides suggestions for further steps to address the challenge of the legacy of HCH/Lindane production.Conclusion
It can be expected that most locations where HCH waste was discarded/stockpiled are not secured and that critical environmental impacts are resulting from leaching and volatilisation. As parties to the Stockholm Convention are legally required to take action to stop further POPs pollution, identification and evaluation of such sites are necessary. 相似文献113.
Three methodologies to assess As bioaccessibility were evaluated using playground soil collected from 16 playgrounds in Madrid, Spain: two (Simplified Bioaccessibility Extraction Test: SBET, and hydrochloric acid-extraction: HCl) assess gastric-only bioaccessibility and the third (Physiologically Based Extraction Test: PBET) evaluates mouth-gastric-intestinal bioaccessibility. Aqua regia-extractable (pseudo total) As contents, which are routinely employed in risk assessments, were used as the reference to establish the following percentages of bioaccessibility: SBET - 63.1; HCl - 51.8; PBET - 41.6, the highest values associated with the gastric-only extractions. For Madrid playground soils - characterised by a very uniform, weakly alkaline pH, and low Fe oxide and organic matter contents - the statistical analysis of the results indicates that, in contrast with other studies, the highest percentage of As in the samples was bound to carbonates and/or present as calcium arsenate. As opposed to the As bound to Fe oxides, this As is readily released in the gastric environment as the carbonate matrix is decomposed and calcium arsenate is dissolved, but some of it is subsequently sequestered in unavailable forms as the pH is raised to 5.5 to mimic intestinal conditions. The HCl extraction can be used as a simple and reliable (i.e. low residual standard error) proxy for the more expensive, time consuming, and error-prone PBET methodology. The HCl method would essentially halve the estimate of carcinogenic risk for children playing in Madrid playground soils, providing a more representative value of associated risk than the pseudo-total concentrations used at present. 相似文献
114.
Membrane bioreactor biofouling is usually described as an extracellular matrix in which biopolymers, inorganic salts and active microbes co-exist. For that reason, biomineralization (BM) models can be useful to describe the spatial organization and environmental constraints within the referred scenario. BM arguments were utilized as background in order to (1) evaluate CaCO3 influence on flux decline; pore blocking and cake layer properties (resistance, permeability and compressibility) in a wide range of Chitosan/Bovine serum albumin (BSA) mixtures during step-pressure runs and, (2) perform membrane autopsies in order to explore the genesis of mineralized extracellular building blocks (MEBB) during cake layer build up. Using low molecular weight chitosan (LC) and BSA, 2 L of 5 LC/BSA mixtures (0.25-1.85 ratio) were pumped to an external ultra filtration (UF) membrane (23.5 cm2, hydrophobic, piezoelectric, 100 kDa as molecular weight cut-off). Eight different pressure steps (40 ± 7 to 540 ± 21 kPa) were applied. Each pressure step was held for 900 s. CaCO3 was added to LC/BSA mixtures at 0.5, 1.5 and 3 mM in order to create MEBB during the filtration tests. Membrane autopsies were performed after the filtration tests using thermo gravimetric, scanning microscopy and specific membrane mass (mg cm−2) analyses. Biopolymer-CaCO3 step-pressure filtration created compressible cake layers (with inner voids). The formation of an internal skeleton of MEBB may contribute to irreversible fouling consolidation. A hypothesis for MEBB genesis and development was set forth. 相似文献
115.
Minakshi?Sultania Deepak?SrivastavaEmail author 《Journal of Polymers and the Environment》2011,19(4):950-956
Diglycidyl ether of bisphenol—A (DGEBA)—based epoxy resin was blended in the ratio of 3:1 (weight basis) with cycloaliphatic
epoxy (CAE) resin. The prepared blend sample was further blended with different weight percentages of carboxyl-terminated
butadiene acrylonitrile copolymer (CTBN) ranging between 0 and 25 wt% with an interval of 5 wt% and cured with stiochiometric
amounts of 4, 4’- diamino diphenyl sulphone (DDS) cure agent. Structural changes during blending were studied by Fourier-transform
infra-red (FTIR) spectroscopic analysis. The kinetic parameters, viz., order of decomposition reaction (n), activation energy (E), pre-exponential factor (Z) and rate decomposition constant (k), for the decomposition of the samples were calculated by applying Coats-Redfern equation over thermogravimetric (TG) data.
The degradation of each sample followed second-order degradation kinetics, which was calculated by Coats-Redfern equation
using best-fit analysis. This was further confirmed by linear regression analysis. The validity of data was checked by t-test
statistical analysis. Further, the blend sample had higher initial degradation temperature and activation energy than its
respective pure epoxy resin indicating that the CTBN acted as thermal stabilizer for epoxy resin which improved the thermal
stability. 相似文献
116.
Timothy J. Pac James Baldock Brendan Brodie Jennifer Byrd Beatriz Gil Kevin A. Morris Denice Nelson Jaydeep Parikh Paulo Santos Miguel Singer Alan Thomas 《补救:环境净化治理成本、技术与工艺杂志》2019,29(2):75-91
This paper compiles a detailed set of in situ chemical oxidation (ISCO) lessons learned pertaining to design, execution, and safety based on global experiences over the last 20 years. While the benefits of a “correct” application are known (e.g., cost effectiveness, speed, permanence of treatment), history also provides examples of a variety of “incorrect” applications. These provide an opportunity to highlight recurring themes that resulted in failures. ISCO is, and will continue to provide, an important remedial tool for site remediation, particularly as a component of a multifaceted approach for addressing large and complex sites. Future success, however, requires an objective understanding of both the benefits and the limitations of the technology. The ability to learn from the mistakes of the past provides an opportunity to eliminate, or at least minimize, them in the future. Over the last 25 years of ISCO application, process understanding and knowledge have improved and evolved. This paper combines a thorough discussion of lessons learned through decades of ISCO implementation throughout all aspects of ISCO projects with an analysis of changes to the ISCO remediation market. By discussing the interplay of these two themes and providing recommendations from collective lessons learned, we hope to improve the future of safe, cost‐effective, and successful applications of ISCO. 相似文献
117.
Oscar Pindado Rosa Ma Pérez Susana García Miguel Sánchez Pilar Galán Marta Fernández 《Atmospheric environment (Oxford, England : 1994)》2009,43(17):2796-2803
The results from a year-long study of the organic composition of PM2.5 aerosol collected in a rural area influenced by a highway of Spain are reported. The lack of prior information related to the organic composition of PM2.5 aerosol in Spain, concretely in rural areas, led definition of the goals of this study. As a result, this work has been able to characterize the main organic components of atmospheric aerosols, including several compounds of SOA, and has conducted a multivariate analysis in order to assign sources of particulate matter. A total of 89 samples were taken between April 2004 and April 2005 using a high-volume sampler. Features and abundance of n-alkanes, polycyclic aromatic hydrocarbons (PAHs), alcohols and acids were separately determined using gas chromatography/mass spectrometry and high performance liquid chromatography analysis. The Σn-alkane and ΣPAHs ranged from 3 to 81 ng m?3 and 0.1 to 6 ng m?3 respectively, with higher concentrations during colder months. Ambient concentrations of Σalcohols and Σacids ranged from 21 to 184 ng m?3 and 39 to 733 ng m?3, respectively. Also, several components of secondary organic aerosol have been quantified, confirming the biogenic contribution to ambient aerosol. In addition, factor analysis was used to reveal origin of organic compounds associated to particulate matter. Eight factors were extracted accounting more than 83% of the variability in the original data. These factors were assigned to a typical high pollution episode by anthropogenic particles, crustal material, plant waxes, fossil fuel combustion, temperature, microbiological emissions, SOA and dispersion of pollutants by wind action. Finally, a cluster analysis was used to compare the organic composition between the four seasons. 相似文献
118.
119.
Miguel Delibes-Mateos Miguel ángel Farfán Jesús Olivero Ana Luz Márquez Juan Mario Vargas 《Environmental management》2009,43(6):1256-1268
Agricultural change has transformed large areas of traditional farming landscapes, leading to important changes in the species
community assemblages in most European countries. We suspect that the drastic changes in land-use that have occurred in Andalusia
(southern Spain) over recent decades, may have affected the distribution and abundance of game species in this region. This
article compares the distribution of the main game species in Andalusia during the 1960s and 1990s, using data from maps available
from the Mainland Spanish Fish, Game and National Parks Service and from recent datasets on hunting yield distributions, respectively.
Big-game and small-game species were significantly segregated in southern Spain during the 1990s, as two clearly independent
chorotypes (groups of species whose abundances are similarly distributed) were obtained from the classification analysis.
In contrast, big-game and small-game species were not significantly segregated several decades ago, when there was only one
chorotype consisting of small-game species and wild boar. The other three ungulates did not constitute a significant chorotype,
as they showed positive correlations with some species in the group mentioned above. These changes seem to be a consequence
of the transformations that have occurred in the Iberian Mediterranean landscape over the last few decades. The abandoning
of traditional activities, and the consequent formation of dense scrubland and woodland, has led to an expansion of big-game
species, and a decrease of small-game species in mountain areas. Moreover, agricultural intensification has apparently depleted
small-game species populations in some agricultural areas. On the other hand, the increasingly intensive hunting management
could be artificially boosting this segregation between small-game and big-game species. Our results suggest that the conservation
and regeneration of traditional agricultural landscapes (like those predominating in the 1960s) should be a priority for the
conservation of small-game species. 相似文献
120.
Castello L Viana JP Watkins G Pinedo-Vasquez M Luzadis VA 《Environmental management》2009,43(2):197-209
Fishers and small-scale fisheries worldwide have been marginalized historically. Now it is clear that integrating fishers
in management processes is key to resource conservation, but it is less clear how to do it. Here, based on a literature review and new information, we present and analyze a case in which the participation
of fishers in the management process was crucial in recovering an overexploited small-scale fishery for the pirarucu (Arapaima spp.) in the Amazon Basin, Brazil. In 8 years of experimental management, from 1999 to 2006, the population of pirarucu increased
9-fold (from about 2200 to 20,650 individuals), harvest quotas increased 10-fold (from 120 to 1249 individuals), and fishers’
participation in the management process increased and they benefited from increased monetary returns. Additionally, the number
of communities conducting the management scheme increased from 4 in 1999 to 108 in 2006, following the demands of fishers
and regional government agencies. Based on our analysis, we suggest that the participation of fishers in the management of
other small-scale fisheries in the world can be improved by focusing on (1) applying the knowledge and skills of fishers in
resource monitoring and management, (2) bridging knowledge systems among all involved stakeholders, (3) collaborating with
fishers that are interested in, and capable of conducting, resource conservation schemes, and (4) conducting management under
conditions of uncertainty. 相似文献