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91.
Michaela Zeiner Iva Juranović Cindrić Ivanka Lovrenčić Mikelić Gordana Medunić Štefica Kampić Nenad Tomašić Gerhard Stingeder 《Environmental monitoring and assessment》2013,185(1):223-229
Concentrations of Ag, Al, Ba, Cd, Co, Cr, Cu, Fe, K, Mn, Na, Ni, Pb, Sr, and Zn—isolated by sequential extraction steps from apple orchard soil—were analyzed by inductively coupled plasma-atomic emission spectroscopy and compared to the total amount of metal in soil determined by XRF. The extractable amount of each metal was calculated by the extraction yields of the four steps. The LODs of the different elements in all extracts ware below 3 μg/L except for Ba (steps 1 and 2), Cu (step 1), Fe (all steps), K (steps 1–3), Mn (step 2), Na (steps 1–3), Ni (step 1), Pb (steps 1 and 4), and Zn (steps 1 and 2). The highest LOD (>10 μg/L) was found for Fe, K, and Na (step 1). The recovery of all metals after four sequential extraction steps was 90–112%. The repeatability (<1.1%), the intermediate precision (<5.3%), the day-to-day reproducibility (<6.2%), and the overall uncertainty of measurement (approximately 4–8.5%) for all analyzed metals supports the choice of the method used. 相似文献
92.
Jiří Pšeja Hana Charvátová Petr Hruzík Josef Hrnčiřík Jan Kupec 《Journal of Polymers and the Environment》2006,14(2):185-190
The presented work deals with blends composed of polyvinyl alcohol (PVA) and biopolymers (protein hydrolysate, starch, lignin). PVA does not belong to biologically inert plastics but its degradation rate (particularly under anaerobic conditions) is low. A potential solution to the issue problem lies in preparation of blends with readily degradable substrates. We studied degradation of blow-molded films made of commercial PVA and mentioned biopolymers in an aqueous anaerobic environment employing inoculation with digested activated sludge from the municipal wastewater treatment plant. Films prepared in the first experimental series were to be used for comparing biodegradation of blends modified with native or plasticized starch; in this case effect of plasticization was not proved. The degree of PVA degradation after modification with native or plasticized starch increases in a striking and practically same manner already at a starch level as low as approximately 5 wt.%. Films of the second experimental series were prepared as additionally modified with protein hydrolysate and lignin. Only lignin-modified samples exhibited a somewhat lower degree of biodegradation but regarding the measure of lignin present in blend this circumstance is not essential. Level of biodegradation with all discussed films differed only slightly—within range of experimental error. 相似文献
93.
Junga Petr Trávníček Petr Suchý Pavel Kotek Luboš Vítěz Tomáš 《Journal of Material Cycles and Waste Management》2023,25(1):288-301
Journal of Material Cycles and Waste Management - This work focuses on the issue of emergency prevention in the operation of municipal solid waste landfills. In this work, an emergency is... 相似文献
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Bikit I Slivka J Conkić Lj Krmar M Vesković M Zikić-Todorović N Varga E Curcić S Mrdja D 《Journal of environmental radioactivity》2005,78(1):11-19
The widespread public belief that during the bombardment of Vojvodina (Yugoslavia) this region was contaminated by depleted uranium has recently raised public concern with respect to the potential contamination of agricultural products due to soil radioactivity. Based on the gamma-spectrometric analysis of 50 soil samples taken from the region of Vojvodina we concluded that there is no increase of radioactivity that could endanger the food production. Taking into account the transfer factors of 137Cs to plants, the measured activity concentrations of this isotope should not endanger the health safety of the produced food. No traces of depleted uranium have been found. The natural radioactivity levels are compared with the results form other countries. 相似文献
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Mutavdzić D Brnardić I Kastelan-Macan M 《Journal of environmental science and health. Part. B》2006,41(7):1085-1101
The purpose of this investigation was to determine the influence of humic acids (HA) and Ca-montmorillonite (CaM) on the solid-phase extraction (SPE) efficiency of atrazine, alachlor and alpha-cypermethrin from water samples at various pH-values. The nature and intensity of binding of the studied pesticides to CaM were determined by X-ray diffraction analysis and termogravimetric analysis (TGA) test. The studied pesticides eluted from discs were analysed by thin-layer chromatography (TLC). The effects of CaM and humic acid were generally pH-dependent and acted independently in extraction efficiency influence. Lower recovery of pesticides was observed at higher pH values when CaM was > or =0.1 g and was attributed to greater dispersion of clay, increased surface area and subsequent adsorption. Concentrations of dissolved organic carbon (DOC) in humic acid had less effect on the extraction efficiency when water was at pH 8 compared to water at pH 2, which was probably due to greater nonpolar interactions of the pesticides to the charge-neutralized humic acid molecule. 相似文献
99.
Antić-Mladenović Svetlana Kresović Mirjana Čakmak Dragan Perović Veljko Saljnikov Elmira Ličina Vlado Rinklebe Jörg 《Environmental geochemistry and health》2019,41(1):249-266
Environmental Geochemistry and Health - Extreme flooding in May, 2014 affected the sub-catchments of six major rivers in Serbia. The goal of the study was to evaluate the contents of potentially... 相似文献
100.